Angewandte Chemie International Edition: Vol 38, No 13-14

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Angewandte Chemie International Edition: Volume 38, Issue 13-14

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Discovery of Some of the Biological Effects of Nitric Oxide and Its Role in Cell Signaling (Nobel Lecture)

Endothelium-Derived Relaxing Factor: Discovery, Early Studies, and Identifcation as Nitric Oxide (Nobel Lecture)

Nitric Oxide: A Unique Endogenous Signaling Molecule in Vascular Biology (Nobel Lecture)

Quantum Chemical Models (Nobel Lecture)

Polymer-Supported Synthesis of Non-Oligomeric Natural Products

Li4SeO5, the First Orthoselenate, Crystallizes as an Order Variant of a Theoretically Predicted A[5]B[5] Structure Type

Helical Crystallization of Proteins on Carbon Nanotubes: A First Step towards the Development of New Biosensors

Template Assembly of Metal Aggregates by Imino-Carboxylate Ligands

Dendritically Cross-Linking Chiral Ligands: High Stability of a Polystyrene-Bound Ti-TADDOLate Catalyst with Diffusion Control

Chelated Bisphosphites with a Calix[4]arene Backbone: New Ligands for Rhodium-Catalyzed Low-Pressure Hydroformylation with Controlled Regioselectivity

Organic Transformations at a Group 4 Metallocene Framework: Formation of a Rigid ansa-Metallocene by Mannich-type Carbon–Carbon Coupling

Intramolecular NMe2H Elimination and Fulvene Coupling Leading to Novel Allyl-Bridged Zirconocene and Hafnocene Complexes

A Convenient and Versatile Route to Hydroquinolines by Inter- and Intramolecular Aza-Diels–Alder Pathways

re- and si-Face-Selective Nitroaldol Reactions Catalyzed by a Rigid Chiral Quaternary Ammonium Salt: A Highly Stereoselective Synthesis of the HIV Protease Inhibitor Amprenavir (Vertex 478)

A Three-Dimensional Coordination Polymer with an Expanded NbO Structure

Templated Synthesis of Vanadium Borophosphate Cluster Anions

Expanded Radialenes: Modular Synthesis and Characterization of Cross-Conjugated Enyne Macrocycles

A New Radical Vinylation Reaction of Iodides and Dithiocarbonates

Metal-Mediated, Completely Diastereofacial Conjugate Addition of Trialkylstannylmetal Reagents to γ-Alkoxy-α,β-Unsaturated Esters

Peptide Mini-Vectors for Gene Delivery

Metathesis of Alkanes: Evidence for Degenerate Metathesis of Ethane over a Silica-Supported Tantalum Hydride Prepared by Surface Organometallic Chemistry

A Giant Carceplex Permanently Entraps Three Organic Molecules

Porphomethenes and Porphodimethenes Synthesized by the Two- and Four-Electron Oxidation of the meso-Octaethylporphyrinogen

Novel and Efficient Isomerization of Allylic Alcohols Promoted by a Tetrapropylammonium Perruthenate Catalyst

Nanospheres from Polymerized Lipofullerenes

Surface Modification of Porous Silicon by Electrochemical Reduction of Organo Halides

S-Cylindrophanes: From Metal Tweezers to Metal Sandwiches

N-Oxidation of Epothilone A–C and O-Acyl Rearrangement to C-19- and C-21-Substituted Epothilones

Molecular Beside Ionic: Crystal Structures of a 1/1 and a 1/4 Adduct of Pyridine and Formic Acid

New Advances in the Biosynthesis of Glycopeptide Antibiotics of the Vancomycin Type from Amycolatopsis mediterranei

A Highly Luminescent Tetranuclear Silver(I) Cluster and Its Ligation-Induced Core Rearrangement

A Polymer Guest Transforms Clathrate Cages into Channels: The Single-Crystal X-Ray Structure of Tetra-n-butylammonium Polyacrylate Hydrate, nBu4NPA⋅40 H2O

A Formal Asymmetric Synthesis of (+)-Anatoxin-a Using an Enantioselective Deprotonation Strategy on an Eight-Membered Ring

2,2′-commo-Bis[2-ruthena-nido-1-(η5-pentamethylcyclopentadienyl)ruthenahexaborane(12)]: An Unusual Ruthenaborane Related to Ruthenocene and Exhibiting a Linear Triruthenium Fragment

Liquid Crystals Based on Hypervalent Sulfur Fluorides: Pentafluorosulfuranyl as Polar Terminal Group

Identification of Sequence-Selective Receptors for Peptides with a Carboxylic Acid Terminus

ITQ-7: A New Pure Silica Polymorph with a Three-Dimensional System of Large Pore Channels

Interaction of a PDZ Protein Domain with a Synthetic Library of All Human Protein C Termini

N5+: A Novel Homoleptic Polynitrogen Ion as a High Energy Density Material

Chalcogenatetrasilacyclopentenes: Five-Membered Rings with Endocyclic Si−Si Double Bonds

Regio- and Enantioselective Cyclization of Epoxy Alcohols Catalyzed by a [CoIII(salen)] Complex

Insight into the Mechanism of the Saegusa Oxidation: Isolation of a Novel Palladium(0)–Tetraolefin Complex

The Origin of the Distorted Close-Packed Elemental Structure of Indium

Design and Development of the First Peptide-Chelating Bisphosphane Bioconjugate from a Novel Functionalized Phosphorus(III) Hydride Synthon

Modeling a Nitrogenase Key Reaction: The N2-Dependent HD Formation by D2/H+ Exchange

Highly Selective Three-Component Coupling of Ethyl Propiolate, Alkenes, and Diphenyl Diselenide under Visible-Light Irradiation

The First Determination of Eu−H Distances by Neutron Diffraction on the Novel Hydrides EuMg2H6 and EuMgH4

Design, Synthesis, and Evaluation of Novel Modular Bisubstrate Analogue Inhibitors of Farnesyltransferase

Rb10Mo36S38: A Novel Reduced Molybdenum Sulfide Containing the Highest Nuclearity Metal Transition Cluster in a Solid-State Compound

Non-Oxide Sol–Gel Chemistry: Preparation from Tris(dialkylamino)silazanes of a Carbon-Free, Porous, Silicon Diimide Gel

Solid Xenon: A Medium for Unusual Photoreactions

Organic Quantum-Confined Structures through Molecular Layer Epitaxy

Highly Efficient, Enantioselective Total Synthesis of the Active Anti-Influenza A Virus Indole Alkaloid Hirsutine and Related Compounds by Domino Reactions

Stabilization of Organosilicenium Ions by means of Intramolecular Coordination of O, S, or P Ligands

Synthesis and Structural Characterization of Graphite-Like [(Me3Sn)3O]Cl

Markovnikov Hydroboration of Perfluoroalkylethylenes

Ta4BTe8: Tantalum Telluride Cluster Chains with Encapsulated Boron Atoms

Template-Mediated Synthesis of a Polymeric Receptor Specific to Amino Acid Sequences

A New Platinum Anticancer Drug Forms a Highly Stereoselective Adduct with Duplex DNA

Demetalation of Tricarbonyl(cyclopentadienone)iron Complexes Initiated by a Ligand Exchange Reaction with NaOH—X-Ray Analysis of a Complex with Nearly Square-Planar Coordinated Sodium

A Molybdenum–Iron–Sulfur Cluster Containing Structural Elements Relevant to the P-Cluster of Nitrogenase

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Special Issue: Membrantechnik

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Li₄SeO₅, the First Orthoselenate, Crystallizes as an Order Variant of a Theoretically Predicted A^[5]B^[5] Structure Type

Intramolecular NMe₂H Elimination and Fulvene Coupling Leading to Novel Allyl-Bridged Zirconocene and Hafnocene Complexes

A Polymer Guest Transforms Clathrate Cages into Channels: The Single-Crystal X-Ray Structure of Tetra-n-butylammonium Polyacrylate Hydrate, nBu₄NPA⋅40 H₂O

2,2′-commo-Bis[2-ruthena-nido-1-(η⁵-pentamethylcyclopentadienyl)ruthenahexaborane(12)]: An Unusual Ruthenaborane Related to Ruthenocene and Exhibiting a Linear Triruthenium Fragment

N₅⁺: A Novel Homoleptic Polynitrogen Ion as a High Energy Density Material

Regio- and Enantioselective Cyclization of Epoxy Alcohols Catalyzed by a [Co^III(salen)] Complex

Modeling a Nitrogenase Key Reaction: The N₂-Dependent HD Formation by D₂/H⁺ Exchange

The First Determination of Eu−H Distances by Neutron Diffraction on the Novel Hydrides EuMg₂H₆ and EuMgH₄

Rb₁₀Mo₃₆S₃₈: A Novel Reduced Molybdenum Sulfide Containing the Highest Nuclearity Metal Transition Cluster in a Solid-State Compound

Synthesis and Structural Characterization of Graphite-Like [(Me₃Sn)₃O]Cl

Ta₄BTe₈: Tantalum Telluride Cluster Chains with Encapsulated Boron Atoms