Communication
A Three-Dimensional Coordination Polymer with an Expanded NbO Structure
First published: 08 July 1999
Citations: 42
Abstract
The connection of square-planar [Ni(CN)4]2− ions with Ph3Sn+ ions results in 1, a noninterpenetrated three-dimensional coordination polymer with an expanded NbO structure. The (Ph3Sn)2Ni(CN)4 framework (shown schematically without phenyl groups and solvent molecules) displays a large central cavity that is occupied by Ph3SnOH, acetonitrile, and water molecules.
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