KAIST Special Issue

20 July 2024
21 July 2025
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Guest Editors: Prof. Il-Doo Kim, Korea Advanced Institute of Science & Technology
Prof. Seungbum Hong, Korea Advanced Institute of Science & Technology
Prof. Dong-Hwa Seo, Korea Advanced Institute of Science & Technology

Articles

Open Access

A review of recent developments in the design of electrolytes and solid electrolyte interphase for lithium metal batteries

  • First Published: 23 October 2024
A review of recent developments in the design of electrolytes and solid electrolyte interphase for lithium metal batteries

With various types of lithium salt, solvents, and additives, the structure and components of solid electrolyte interphase (SEI) can be designed. The comprehensive properties of SEI such as high mechanical stability, electronic insultation, and high ionic conductivity are closely related to uniform lithium deposition and side reaction prevention resulting in high Coulombic efficiency.

Open Access

Addressing electrode passivation in lithium–sulfur batteries by site-selective morphology-controlled Li2S formation

  • First Published: 22 August 2024
Addressing electrode passivation in lithium–sulfur batteries by site-selective morphology-controlled Li2S formation

Site-selective morphology-controlled Li2S formation enabled by electrode and electrolyte design.

Open Access

Advanced approach for active and durable proton exchange membrane fuel cells: Coupling synergistic effects of MNC nanocomposites

  • First Published: 09 October 2024
Advanced approach for active and durable proton exchange membrane fuel cells: Coupling synergistic effects of M<span class='icomoon'></span>N<span class='icomoon'></span>C nanocomposites

This review discusses the structure–performance relationships of MNC nanocomposite electrocatalysts for the acidic oxygen reduction reaction (ORR) in proton exchange membrane fuel cells, highlighting the synergistic intrinsic activity/durability enhancements caused by the combination of single atoms, clusters, and nanoparticles with MNC catalysts. Examples of in situ/operando analysis are presented, providing insights into the underlying mechanisms/phenomena. ORRs, proton exchange membrane fuel cells, atomically dispersed catalysts, nanocomposites, coupling synergistic effects.

Open Access

Recommended practice for measurement and evaluation of oxygen evolution reaction electrocatalysis

  • First Published: 17 September 2024
Recommended practice for measurement and evaluation of oxygen evolution reaction electrocatalysis

Careful consideration of the methodology employed for measuring the oxygen evolution reaction is paramount. Moreover, accurate determinations of various catalyst performances are crucial for assessing electrochemical efficiency and driving development forward.

Open Access

Electrospun Carbon Nanofibers for Clean Energy Applications: A Comprehensive Review

  • First Published: 06 February 2025
Electrospun Carbon Nanofibers for Clean Energy Applications: A Comprehensive Review

This review provides perspectives on design principles of electrospun carbon nanofibers (CNFs) with structural modifications and surface activity tuning for energy storage and conversion applications. Variety of approaches can be applied on both before and after carbonization stage to induce structural and surface property changes. Overall, this review guides researchers in developing CNFs for sustainable energy solutions.

Open Access

Efficient and spectrally stable pure blue light-emitting diodes enabled by phosphonate passivated CsPbBr3 nanoplatelets with conjugated polyelectrolyte-based energy transfer layer

  • First Published: 29 September 2024
Efficient and spectrally stable pure blue light-emitting diodes enabled by phosphonate passivated CsPbBr3 nanoplatelets with conjugated polyelectrolyte-based energy transfer layer

Short-chain octyl-phosphonate capped CsPbBr3 nanoplatelets were successfully synthesized using a room temperature method. The introduction of a conjugated polyelectrolyte material as a hole transport layer facilitated energy transfer to the nanoplatelets. The resulting LEDs emit pure blue light and maintain this emission without any spectral peak shift, even under conditions where the device undergoes degradation due to joule heating.

Open Access

Enhancing performance of two-step fabricated perovskite solar cells with sulfonium triflate-based additive

  • First Published: 31 March 2024
Enhancing performance of two-step fabricated perovskite solar cells with sulfonium triflate-based additive

A bulky sulfonium-based additive is incorporated into the array of the PbI2 structure, facilitating the FAI reaction in two-step deposition and inducing an alternation of growth in the perovskite film that has large grains with fewer defects. As a result of the additive effect, we achieved a PCE of 23.88%.

Open Access

Exploring Gas/Solid Interface Reactions of Solid Oxide Cell Electrodes via Model Thin-Film Systems

  • First Published: 20 March 2025
Exploring Gas/Solid Interface Reactions of Solid Oxide Cell Electrodes via Model Thin-Film Systems

Thin-film-based model systems provide unique insights due to their ability to emulate the complex phenomena at SOC electrode interfaces under controlled conditions. This review highlights the fundamental research, utilizing thin films to dissect interface dynamics in SOCs, advocating for their crucial role in advancing SOC technology and understanding.

Open Access

Impact of conducting agents on sulfide and halide electrolytes in disordered rocksalt cathode-based all-solid-state batteries

  • First Published: 12 November 2024
Impact of conducting agents on sulfide and halide electrolytes in disordered rocksalt cathode-based all-solid-state batteries

This research investigates the integration of Mn-based disordered rock-salt cathodes in all-solid-state battery systems operating from 1.5 to 4.8 V. We discuss the effects of high carbon contents required for the DRX cathodes on electrochemical performance, comparing halide and sulfide solid electrolytes. It provides new insights into the interplay among solid electrolytes, cathodes, and conductive additives.

Open Access

In-situ photo-polymerized elastomeric composite electrolytes containing Li6.4La3Zr1.4Ta0.6O12 particles for stable operation in lithium metal batteries

  • First Published: 13 November 2024
In-situ photo-polymerized elastomeric composite electrolytes containing Li6.4La3Zr1.4Ta0.6O12 particles for stable operation in lithium metal batteries

The in-situ photo-polymerized composite polymer electrolyte (CPE) exhibits high ionic conductivity, excellent elasticity, and superior adhesion properties with uniform dispersion of LLZTO nanoparticles. This CPE achieves excellent cycling performance of Li/NCM811 full cell, maintaining a capacity retention of 95% after 200 cycles with a specific capacity of 166.7 mAh g−1 under 0.5C.

Open Access

Multiscale Materials Imaging and Spectroscopy for Battery Materials

  • First Published: 06 May 2025
Multiscale Materials Imaging and Spectroscopy for Battery Materials

Key physical and chemical phenomena in battery materials are illustrated across multiple length scales, from atomic to device level. Corresponding characterization techniques are aligned with each regime, showing how structural, thermal, and interfacial changes affect performance. This multiscale framework underscores the importance of integrated imaging for next-generation battery diagnostics and design.

Open Access

Unlocking fast-charging capabilities of lithium-ion batteries through liquid electrolyte engineering

  • First Published: 20 June 2024
Unlocking fast-charging capabilities of lithium-ion batteries through liquid electrolyte engineering

The fast-charging performance of lithium-ion batteries can be achieved by electrolytes that provide well-connected ion channels with homogeneous Li+ flux and solvents with moderate solvating power to facilitate desolvation. Furthermore, an ionically conductive solid electrolyte interphase (SEI) plays a crucial role in reducing the desolvation energy barrier and forming a stable SEI with a long lifespan, particularly at high charge rates.