• Issue

    Journal of Applied Polymer Science: Volume 139, Issue 43

    November 15, 2022

COVER IMAGE

Free Access

Cover Image, Volume 139, Issue 43

  • First Published: 08 October 2022
Cover Image, Volume 139, Issue 43

The cover image by Dr. Noorullah Baig shows how metal-organic copolymers containing iron(II) clathrochelated with various arylamines were synthesized via a palladium-catalyzed Sonogashira crosscoupling reaction. The copolymers reveal ultrafast dye adsorption efficiencies up to 100% and exhibit maximum adsorption capacity (qm) for Methylene Blue and Congo Red of 146.63 mg g−1 and 787.40 mg g−1, respectively. The metal-organic polymers demonstrate several advantages, namely, their versatile synthesis, low cost, superior thermal stability, excellent adsorption capacity, and high surface area, which qualify them as prominent adsorbents for water purification applications. DOI: 10.1002/app.52966. [Correction added on October 21, 2022, after first online publication: Cover image has been corrected.]

ISSUE INFORMATION

Free Access

Editorial Board, Aims & Scope, Table of Contents

  • First Published: 08 October 2022

RESEARCH ARTICLES

Removal of anionic and cationic dyes using porous copolymer networks made from a Sonogashira cross-coupling reaction of diethynyl iron (II) clathrochelate with various arylamines

  • First Published: 03 August 2022
Removal of anionic and cationic dyes using porous copolymer networks made from a Sonogashira cross-coupling reaction of diethynyl iron (II) clathrochelate with various arylamines

The synthesis of four copolymer networks based on iron(II) clathrochelate derivative and several arylamines is described. Target copolymers reveal microporous properties with surface areas up to 411 m2g−1. They demonstrate efficient adsorption of various organic dyes from aqueous media making them promising candidates for environmental remediation.

Preparation and evaluation of organosilica nanocapsules encapsulating DCOIT by using the response surface optimization

  • First Published: 08 August 2022
Preparation and evaluation of organosilica nanocapsules encapsulating DCOIT by using the response surface optimization

Organosilicon nanocapsules encapsulating the antifouling agent DCOIT were prepared based on the self-catalytic sol–gel reaction between methyl trimethoxysilane (MTMS) and 3-aminopropyl trimethoxysilane (APS). With the encapsulation efficiency as the evaluation index, the response surface method was used to optimize the preparation process. The results indicate that the obtained nanocapsules would have great potential for application in antifouling coatings, which are sufficient to cope with the challenges brought by marine environments.

Hydrophobic chitosan/salicylic acid blends film with excellent tensile properties for degradable food packaging plastic materials

  • First Published: 26 August 2022
Hydrophobic chitosan/salicylic acid blends film with excellent tensile properties for degradable food packaging plastic materials

Due to the first synthesis of degradable CS/SA plastic materials in organic systems, the crosslinked CS-SA blends have better hydrophobicity, mechanical strength, permeability, stability, and antibacterial properties, extending the storage time of grapes to more than 14 days, and greatly meet the needs of food plastic packaging.

Self-assembled nanoprodrugs from reducible dextran-diethyldithiocarbamate conjugates for robust tumor-targeted chemotherapy

  • First Published: 24 August 2022
Self-assembled nanoprodrugs from reducible dextran-diethyldithiocarbamate conjugates for robust tumor-targeted chemotherapy

A reduction-sensitive folate-dextran-diethyldithiocarbamate (DDTC) prodrug conjugate can self-assemble into nanoprodrugs for tumor cell targeting and robust tumor chemotherapy.

Hydrophobic and lipophilic cellulose nanocrystal aerogel prepared by methyltrichlorosilane via vapor-phase reaction

  • First Published: 25 August 2022
Hydrophobic and lipophilic cellulose nanocrystal aerogel prepared by methyltrichlorosilane via vapor-phase reaction

Vapour-phase reaction of CNC aerogel with MTS followed by its adsorption of paraffin and the desorption

Open Access

Acrylate-free tough 3D printable thiol-ene thermosets and composites for biomedical applications

  • First Published: 20 August 2022
Acrylate-free tough 3D printable thiol-ene thermosets and composites for biomedical applications

Thiol-ene thermoset and composite resins developed for hard tissue repair are adapted for SLA 3D printing through the addition of either diluents, free radical inhibitors, or micro- and nano-sized hydroxyapatite. The resulting printed materials display excellent biological profiles, while their mechanical properties exceed the thiol-ene printed systems in the literature.

Surface modification of cellulose nanofibers by oxidative polymerization of tannic acid/ethanediamine and their polyvinylalcohol composites

  • First Published: 25 August 2022
Surface modification of cellulose nanofibers by oxidative polymerization of tannic acid/ethanediamine and their polyvinylalcohol composites

A facile and green method for surface functionalization of cellulose nanofiber (CNF) by mussel-like oxidative polymerization of tannic acid and ethanediamine is reported. The modified CNF was then used as filler for constructing multifunctional polyvinylalcohol composites with comprehensively improved properties.

Characteristic comparison of lignocellulose nanofibrils from wheat straw having different mechanical pretreatments

  • First Published: 24 August 2022
Characteristic comparison of lignocellulose nanofibrils from wheat straw having different mechanical pretreatments

Herein, the morphology, physicochemical structure, chemical composition, and thermostability of Wheat straw (WS) and lignocellulose nanofibrils (LCNFs) were systematically investigated, aiming to reveal the impact of screw extrusion and ball milling during the process of LCNF preparation. This work could not only offer theoretical guidance on the preparation of LCNFs by mechanical pretreatments but also expand the high-value application of agricultural residues in polymer composites.

Fast fabrication of a light-scattering polycarbonate with high transmittance, high haze, and excellent flame-retardant performance

  • First Published: 24 August 2022
Fast fabrication of a light-scattering polycarbonate with high transmittance, high haze, and excellent flame-retardant performance

This paper provides a simple, economical, and environmentally benign fabrication process for light-scattering PC with excellent flame-retardant performance. During processing, the strong hydrogen bond interaction between PSi and SAN enabled the in-situ formation of flame-retardant scatterers SAN-PSi, which allowed us to prepare light-scattering PC with excellent flame-retardant performance in the one-step melt blending process.

Effects of acrylate monomers with different alkyl chain structure on the electro-optical properties and microstructure of polymer dispersed liquid crystals

  • First Published: 24 August 2022
Effects of acrylate monomers with different alkyl chain structure on the electro-optical properties and microstructure of polymer dispersed liquid crystals

Acrylate monomers with different alkyl chain structure were applied to prepare polymer dispersed liquid crystals films and the electro-optical performance and microstructure were compared. By balancing the alkyl chain length, branched chains and isomeric structure, low driving voltage and high contrast ratio can be achieved. The transparent and opaque states can work effectively to show or block the background picture.

Preparation of bis-epoxy end capped macromonomers through anionic or RAFT polymerization

  • First Published: 25 August 2022
Preparation of bis-epoxy end capped macromonomers through anionic or RAFT polymerization

A novel bis-epoxy end functionalized polyisoprene (BETPI) macromonomers are prepared by living anionic polymerization and high-pressure RAFT polymerization. The BETPI with 600–1000 Da of molecular weight and over 75% of epoxy end capping rate, which can be further utilized as highly reactive liquid macromonomers in rubber coupling agents, vitrimer materials, and other fields.

Renewable low viscosity polyester-polyols for biodegradable thermoplastic polyurethanes

  • First Published: 06 September 2022
Renewable low viscosity polyester-polyols for biodegradable thermoplastic polyurethanes

In the present work, we carried out the synthesis of renewable low viscosity polyester-polyols for thermoplastic polyurethane applications. Our proposed low viscosity polyester-polyols were found to be attractive candidates for industrial large-scale applications, enabling the synthesis of thermoplastic polyurethanes at a lower temperatures. These TPUs showed good mechanical properties and excellent biodegradation under compost conditions.

Influence of glycidyl methacrylate grafted poly (butylene succinate) (PBS-g-GMA) on flame retardancy and mechanical properties of water hyacinth fiber/ammonium polyphosphate/poly (butylene succinate) composites

  • First Published: 24 August 2022
Influence of glycidyl methacrylate grafted poly (butylene succinate) (PBS-g-GMA) on flame retardancy and mechanical properties of water hyacinth fiber/ammonium polyphosphate/poly (butylene succinate) composites

Environmentally friendly intumescent flame retardant (IFR) based poly (butylene succinate) (PBS) composites are prepared using water hyacinth fiber (WHF) and ammonium polyphosphate (APP) as IFR, with glycidyl methacrylate grafted poly (butylene succinate) (PBS-g-GMA) as a compatibilizer. The enhanced mechanical properties and flame retardancy of WHF/APP/PBS composites will promote the development of biodegradable flame-retardant polymer composites for engineering applications.

Supercritical CO2 foaming of open-cell polypropylene/ethylene propylene diene monomer composite foams with oriented cellular structures for water treatment

  • First Published: 23 August 2022
Supercritical CO2 foaming of open-cell polypropylene/ethylene propylene diene monomer composite foams with oriented cellular structures for water treatment

Open-cell PP/EPDM composite foams with oriented cellular structures and excellent selective filtration properties were fabricated via supercritical CO2 extrusion foaming.