• Issue

    Journal of Applied Polymer Science: Volume 140, Issue 10

    March 10, 2023

COVER IMAGE

Free Access

Cover Image, Volume 140, Issue 10

  • First Published: 01 February 2023
Cover Image, Volume 140, Issue 10

The cover image by Juraij Kandiyil, Suni Vasudevan, and Sujith Athiyanathil shows the antifouling and selective methylene blue adsorption properties of polyurethane/montmorillonite-based electrospun composite membranes (PU/MMT). The optimized membrane showed water permeation with a high water flux of 4029 Lm−2hr−1, significant oil rejection, a better flux recovery ratio, and a maximum MB adsorption capacity (qm) of 112.35 mg/g. The developed, antifouling electrospun composite membrane opens a new avenue for the water treatment process. DOI: 10.1002/app.53464

ISSUE INFORMATION

Free Access

Editorial Board, Aims & Scope, Table of Contents

  • First Published: 01 February 2023

RESEARCH ARTICLES

Efficient selective methylene blue adsorption by polyurethane/montmorillonite-based antifouling electrospun composite membranes

  • First Published: 01 December 2022
Efficient selective methylene blue adsorption by polyurethane/montmorillonite-based antifouling electrospun composite membranes

Selective methylene blue adsorption and antifouling performance of polyurethane/montmorillonite-based electrospun composite membrane.

Rapid gelation of dual physical network hydrogel with ultra-stretchable, antifreezing, moisturing for stable and sensitive response

  • First Published: 09 January 2023
Rapid gelation of dual physical network hydrogel with ultra-stretchable, antifreezing, moisturing for stable and sensitive response

Dual physical network hydrogels were prepared rapidly at room temperature without the use of chemical cross-linking agents. The hydrogel is ultra-stretchable, tough, antifatigue, antifreezing and moisturing. Graphene was dispersed well in this hydrogel. The sensor with good adhesion and sensitivity ensures stable, reliable monitoring. Moreover, this sensor can monitor human size movement flexibly under extreme conditions.

Insight into the structure and mechanical performance of high content lignin reinforced poly (vinyl alcohol) gel-spun fibers via the regulation of esterified hydrophilic lignin composition for better sustainability

  • First Published: 04 January 2023
Insight into the structure and mechanical performance of high content lignin reinforced poly (vinyl alcohol) gel-spun fibers via the regulation of esterified hydrophilic lignin composition for better sustainability

Lignin is a cost-effective renewable reinforcement material for composite fibers. This work investigates the possibility of employing bio-based high content lignin mixture by the regulation of ML composition for the reinforcement of high-performance poly (vinyl alcohol) fibers to achieve better sustainability with no sacrifice of fiber properties.

The improved low-field electro-actuation of dielectric elastomer composites regulated by entirely-inorganic BaTiO3@TiO2 core-shell construction

  • First Published: 04 January 2023
The improved low-field electro-actuation of dielectric elastomer composites regulated by entirely-inorganic BaTiO3@TiO2 core-shell construction

The BaTiO3@TiO2 core-shell construction endows DE composites with an enlarged heterogeneous interface and enhanced interfacial polarization synchronously, which is also benefit to maintain the flexibility of DE materials. The buffer effect offered by TiO2 shell is helpful to alleviate the local electric field concentration at the fillers-matrix interface in DE when being withstood the exponentially-growing electric field. Specifically, the maximum electro-actuated strain of 21% under a low electric field (40 V·μm−1) is obtained from the DE composite filled with 4 wt% BaTiO3@TiO2, which is 290% higher than that of pristine PDMS (5.38% at 40 V·μm−1).

Valorization of hemp fibers into biocomposites via one-step pectin-based green fabrication process

  • First Published: 03 January 2023
Valorization of hemp fibers into biocomposites via one-step pectin-based green fabrication process

A one-step water-based fabrication methodology to valorize hemp fibers into biocomposite materials was reported using pectin as a crosslinker. The compressive strength of these hemp fiber composites was pH-dependent and followed a V-shape trend, confirming the formation of ester bonds between pectin and lignin of hemp fibers via transesterification.

Effect of glass fiber loading and reprocessing cycles on the mechanical, thermal, and morphological properties of isotactic polypropylene composites

  • First Published: 02 January 2023
Effect of glass fiber loading and reprocessing cycles on the mechanical, thermal, and morphological properties of isotactic polypropylene composites

Illustration of the recycling process for glass fiber and Isotactic polypropylene composites for ten reprocessing cycles and the study of their mechanical, thermal, and morphological properties.

Experimental and modeling studies of IPDI-based polyurea elastomers – The role of hard segment fraction

  • First Published: 04 January 2023
Experimental and modeling studies of IPDI-based polyurea elastomers – The role of hard segment fraction

Polyurea (PUa) adhesives have unique properties due to their nanophase-separated morphology. Here, multiple experimental techniques (TEM and DSC) are used to elucidate the hard phase domain structure as a function of the formulation. A new micromechanical model is then proposed to describe linear viscoelasticity of the material and successfully validated based on DMA measurements.

Open Access

Extrusion 3D printing of a multiphase collagen-based material: An optimized strategy to obtain biomimetic scaffolds with high shape fidelity

  • First Published: 09 January 2023
Extrusion 3D printing of a multiphase collagen-based material: An optimized strategy to obtain biomimetic scaffolds with high shape fidelity

A multiphase biomaterial ink combining type-I-collagen with nano-sized mesoporous bioactive glasses and nanohydroxyapatite was successfully designed to mimic the natural composition of bone. Based on rheological data and computational-fluid-dynamic models, the printing set-up was optimized to obtain scaffolds characterized by high printing fidelity and complex geometries, where the final mechanical stability was further enhanced by a chemical genipin crosslinking method.

Synthesis and characterization of multi-ionic block copolymers and blended membranes for chemical protective clothing applications

  • First Published: 04 January 2023
Synthesis and characterization of multi-ionic block copolymers and blended membranes for chemical protective clothing applications

Multi-ionic block copolymers with sulfonated amines and counter-ion substitution selectively allow the permeation of water, while inhibiting the transport of chemicals.

Simultaneously improving of thermal resistance and mechanical performances of cyclic olefin copolymers by incorporation of bulky adamantane side group

  • First Published: 03 January 2023
Simultaneously improving of thermal resistance and mechanical performances of cyclic olefin copolymers by incorporation of bulky adamantane side group

A series of cycloolefin copolymers bearing bulky adamantane side group were prepared and characterized. Benefited from the significant steric hindrance of adamantane, both the unsaturated polymers and hydrogenated polymers showed outstanding thermal resistance, even at low NBDAE incorporations. Besides, the obtained COCs also exhibited improved mechanical performance and excellent transparency.

Preparation and drug release performance of amphiphilic medical hot-melt pressure sensitive adhesives based on polystyrene-isoprene-styrene

  • First Published: 03 January 2023
Preparation and drug release performance of amphiphilic medical hot-melt pressure sensitive adhesives based on polystyrene-isoprene-styrene

Modification mechanism of amphiphilic HMPSAs. Because of their nonpolar structure, hot-melt pressure-sensitive adhesive (HMPSAs) with SIS as the base material have significant difficulties in hydrophilic drug release. SIS-based amphiphilic medical HMPSAs SIS/AEO-9/PEG was successfully prepared in this study using AEO-9 and PEG of varying molecular weights. It can achieve the co-release of lipophilic and hydrophilic drugs, which has a wide range of applications.

Novel antistatic glass fiber reinforced heat-resistant PA10T composites with excellent processing properties and thermal stability

  • First Published: 04 January 2023
Novel antistatic glass fiber reinforced heat-resistant PA10T composites with excellent processing properties and thermal stability

The PA10T/AGF antistatic composites composed of PA10T, antistatic agent, 30 wt.% glass fiber possess excellent antistatic properties, thermal characteristics, balanced toughness, and notched impact strength.

Interfacial adhesion of immiscible component polymers of isoprene rubber and α-olefin copolymer by chemical reaction using peroxide crosslinking agent

  • First Published: 05 January 2023
Interfacial adhesion of immiscible component polymers of isoprene rubber and α-olefin copolymer by chemical reaction using peroxide crosslinking agent

Confocal-Raman spectra revealed that a mixed layer having a distance about 358 nm was formed at the interface of immiscible component polymers of IR and αOC by chemical reaction using peroxide crosslinking agent. Owing to the existence of the mixed layer at the interface, the adhesion strength was large and the tensile stress of the IR was enhanced.

Immobilized Pd metal-complex on polymeric resin with high surface areas for recyclable catalyst: Effect of the immobilization method on nature of palladium species

  • First Published: 05 January 2023
Immobilized Pd metal-complex on polymeric resin with high surface areas for recyclable catalyst: Effect of the immobilization method on nature of palladium species

Two polymerization route was evaluated, to obtain a immobilized palladium coordination compounds, but only one, the “one-step” synthetic route, by polymerization of MCM is suitable to obtain the immobilized coordination compound.