Fabrication of Polymer Film with Extraordinary Conductive Anisotropy by Forming Parallel Conductive Vorticity-Aligned Stripes and Its Formation Mechanism
Corresponding Author
Jinrui Huang
Key Laboratory of Biomass Energy and Material, Jiangsu Province, Key and Open Laboratory on Forest Chemical Engineering, State Forestry Administration, National Engineering Laboratory for Biomass Chemical Utilization, Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing, 210042 Jiangsu Province, P. R. China
E-mail: [email protected], [email protected]Search for more papers by this authorJunbao Xu
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China
Search for more papers by this authorYuping Sheng
Analytical and Testing Center, Sichuan University of Science and Engineering, Zigong, 643000 P. R. China
Search for more papers by this authorCorresponding Author
Yutian Zhu
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China
E-mail: [email protected], [email protected]Search for more papers by this authorWei Jiang
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China
Search for more papers by this authorDonghua Xu
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China
Search for more papers by this authorQingxin Tang
Key Laboratory of UV Light Emitting Materials and Technology under Ministry of Education, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorXiaoan Nie
Key Laboratory of Biomass Energy and Material, Jiangsu Province, Key and Open Laboratory on Forest Chemical Engineering, State Forestry Administration, National Engineering Laboratory for Biomass Chemical Utilization, Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing, 210042 Jiangsu Province, P. R. China
Search for more papers by this authorCorresponding Author
Jinrui Huang
Key Laboratory of Biomass Energy and Material, Jiangsu Province, Key and Open Laboratory on Forest Chemical Engineering, State Forestry Administration, National Engineering Laboratory for Biomass Chemical Utilization, Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing, 210042 Jiangsu Province, P. R. China
E-mail: [email protected], [email protected]Search for more papers by this authorJunbao Xu
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China
Search for more papers by this authorYuping Sheng
Analytical and Testing Center, Sichuan University of Science and Engineering, Zigong, 643000 P. R. China
Search for more papers by this authorCorresponding Author
Yutian Zhu
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China
E-mail: [email protected], [email protected]Search for more papers by this authorWei Jiang
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China
Search for more papers by this authorDonghua Xu
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China
Search for more papers by this authorQingxin Tang
Key Laboratory of UV Light Emitting Materials and Technology under Ministry of Education, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorXiaoan Nie
Key Laboratory of Biomass Energy and Material, Jiangsu Province, Key and Open Laboratory on Forest Chemical Engineering, State Forestry Administration, National Engineering Laboratory for Biomass Chemical Utilization, Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing, 210042 Jiangsu Province, P. R. China
Search for more papers by this authorAbstract
In this work, anisotropic conductive film (ACF) is fabricated by shear-flow induced assembly. It is found that an appropriate content of carbonaceous filler is needed for forming well-ordered parallel vorticity-aligned stripes and the content depends on the category of the filler. Interestingly, the lowest aspect ratio carbon black (CB) with lowest electrical conductivity is the best candidate for fabricating ACF. The film with CB stripes shows excellent conductive anisotropy: the electrical resistivity in the direction parallel to the CB stripes is almost eight orders of magnitude lower than that in the perpendicular direction. The formation mechanism of the vorticity-aligned stripe is also investigated by the rheological measurement and the study of morphological evolution. It is found that the coalescence of dispersed phase or aggregates dominates the formation and growth of the stripe and negative value of the first normal stress difference drives the stripe to align along the vorticity direction.
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