Zn2[(S)-O3PCH2NHC4H7CO2]2: A Homochiral 3D Zinc Phosphonate with Helical Channels†
Xin Shi Dr.
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130012, China, Fax: (+86) 431-5168589
Search for more papers by this authorGuangshan Zhu Dr.
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130012, China, Fax: (+86) 431-5168589
Search for more papers by this authorShilun Qiu Prof.
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130012, China, Fax: (+86) 431-5168589
Search for more papers by this authorKunlin Huang Dr.
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130012, China, Fax: (+86) 431-5168589
Search for more papers by this authorJihong Yu Prof.
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130012, China, Fax: (+86) 431-5168589
Search for more papers by this authorRuren Xu Prof.
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130012, China, Fax: (+86) 431-5168589
Search for more papers by this authorXin Shi Dr.
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130012, China, Fax: (+86) 431-5168589
Search for more papers by this authorGuangshan Zhu Dr.
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130012, China, Fax: (+86) 431-5168589
Search for more papers by this authorShilun Qiu Prof.
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130012, China, Fax: (+86) 431-5168589
Search for more papers by this authorKunlin Huang Dr.
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130012, China, Fax: (+86) 431-5168589
Search for more papers by this authorJihong Yu Prof.
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130012, China, Fax: (+86) 431-5168589
Search for more papers by this authorRuren Xu Prof.
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130012, China, Fax: (+86) 431-5168589
Search for more papers by this authorWe are grateful for financial support from the State Basic Research Project (G2000077507) and the National Nature Science Foundation of China (Grant no. 29873017, 20101004 and 20371020). We thank Professor Guangdi Yang and Dr. Guanghua Li (Department of Chemistry, Jilin University) for their help in the analysis of the single-crystal structure.
Graphical Abstract
Drei Arten von Kanälen zeichnen die Struktur der Titelverbindung aus (siehe Bild): rechts- (R) und linksgängige (L) helicale sowie achirale Kanäle (A). Die katalytisch aktiven Gruppen des 1-Phosphonomethylprolin-Liganden ragen ins Innere der Kanäle, sodass das Material möglicherweise als „Heterogen-Organokatalysator“ dienen kann.
Supporting Information
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