Chemistry of the 5g Elements: Relativistic Calculations on Hexafluorides
Corresponding Author
Dr. Jean-Pierre Dognon
NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay, 91191 Gif-sur-Yvette, France
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Prof. Dr. Pekka Pyykkö
Department of Chemistry, University of Helsinki, P.O. Box 55, 00014 Helsinki, Finland
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Dr. Jean-Pierre Dognon
NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay, 91191 Gif-sur-Yvette, France
Search for more papers by this authorCorresponding Author
Prof. Dr. Pekka Pyykkö
Department of Chemistry, University of Helsinki, P.O. Box 55, 00014 Helsinki, Finland
Search for more papers by this authorAbstract
A Periodic System was proposed for the elements 1–172 by Pyykkö on the basis of atomic and ionic calculations. In it, the elements 121–138 were nominally assigned to a 5g row. We now perform molecular, relativistic four-component DFT calculations and find that the hexafluorides of the elements 125–129 indeed enjoy occupied 5g states.
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