Construction of Mesoporous Frameworks with Vanadoborate Clusters†
Hong Chen
Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden)
Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074 (P.R. China)
Search for more papers by this authorDr. Zheng-Bao Yu
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P.R. China)
Search for more papers by this authorDr. Zoltán Bacsik
Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden)
Search for more papers by this authorHuishuang Zhao
Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden)
Search for more papers by this authorDr. Qingxia Yao
Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden)
Search for more papers by this authorCorresponding Author
Prof. Junliang Sun
Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden)
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P.R. China)
Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden)Search for more papers by this authorHong Chen
Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden)
Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074 (P.R. China)
Search for more papers by this authorDr. Zheng-Bao Yu
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P.R. China)
Search for more papers by this authorDr. Zoltán Bacsik
Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden)
Search for more papers by this authorHuishuang Zhao
Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden)
Search for more papers by this authorDr. Qingxia Yao
Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden)
Search for more papers by this authorCorresponding Author
Prof. Junliang Sun
Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden)
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P.R. China)
Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden)Search for more papers by this authorThis project was supported by the Swedish Research Council (VR), the Swedish Governmental Agency for Innovation Systems (VINNOVA) through the Berzelii EXSELENT, and the National Basic Research Program of China (2013CB933402). H.C. thanks the China Scholarship Council.
Abstract
A new porous vanadoborate was synthesized by employing the scale chemistry theory with the vanadoborate cluster V10B28. The twofold interpenetrated lvt network was assembled with zinc-containing elliptical vanadoborate clusters and Zn polyhedra. The single lvt framework contains a three-dimensional 38×38×20 ring channel system with the pore size (24.7×12.7 Å) reaching the mesoscale, thus indicating the possibility of constructing 3D ordered mesopores with vanadoborate clusters. The porosity of the SUT-7 structure was confirmed by CO2 adsorption of the as-synthesized materials.
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References
- 1A. Corma, Chem. Rev. 1997, 97, 2373–2420.
- 2M. E. Davis, Nature 2002, 417, 813–821.
- 3A. K. Cheetham, G. Férey, T. Loiseau, Angew. Chem. 1999, 111, 3466–3492;
10.1002/(SICI)1521-3757(19991115)111:22<3466::AID-ANGE3466>3.0.CO;2-M Google ScholarAngew. Chem. Int. Ed. 1999, 38, 3268–3292.10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO;2-U CAS PubMed Web of Science® Google Scholar
- 4M. O’Keeffe, M. Eddaoudi, H. Li, T. Reineke, O. M. Yaghi, J. Solid State Chem. 2000, 152, 3–20.
- 5J. Jiang, J. L. Jorda, J. Yu, L. Baumes, E. Mugnaioli, M. J. Diaz-Cabanas, U. Kolb, A. Corma, Science 2011, 333, 1131–1134.
- 6X. Zou, T. Conradsson, M. Klingstedt, M. S. Dadachov, M. O’Keeffe, Nature 2005, 437, 716–719.
- 7X. Ren, Y. Li, Q. Pan, J. Yu, R. Xu, Y. Xu, V. Uni, J. Am. Chem. Soc. 2009, 131, 14128–14129.
- 8J. Sun, C. Bonneau, A. Cantín, A. Corma, M. J. Díaz-Cabañas, M. Moliner, D. Zhang, M. Li, X. Zou, Nature 2009, 458, 1154–1157.
- 9H.-Y. Lin, C.-Y. Chin, H.-L. Huang, W.-Y. Huang, M.-J. Sie, L.-H. Huang, Y.-H. Lee, C.-H. Lin, K.-H. Lii, X. Bu, et al., Science 2013, 339, 811–813.
- 10D. J. Tranchemontagne, Z. Ni, M. O’Keeffe, O. M. Yaghi, Angew. Chem. 2008, 120, 5214–5225;
10.1002/ange.200705008 Google ScholarAngew. Chem. Int. Ed. 2008, 47, 5136–5147.
- 11M. Eddaoudi, D. B. Moler, H. Li, B. Chen, T. M. Reineke, M. O’Keeffe, O. M. Yaghi, Acc. Chem. Res. 2001, 34, 319–330.
- 12H. Deng, S. Grunder, K. E. Cordova, C. Valente, H. Furukawa, M. Hmadeh, F. Gándara, A. C. Whalley, Z. Liu, S. Asahina, et al., Science 2012, 336, 1018–1023.
- 13G. Férey, Science 2001, 291, 994–995.
- 14A. Müller, E. Krickemeyer, S. K. Das, P. Kögerler, S. Sarkar, H. Bögge, M. Schmidtmann, S. Sarkar, Angew. Chem. 2000, 112, 1674–1676;
Angew. Chem. Int. Ed. 2000, 39, 1612–1614.
10.1002/(SICI)1521-3773(20000502)39:9<1612::AID-ANIE1612>3.0.CO;2-L CAS PubMed Web of Science® Google Scholar
- 15M. I. Khan, J. Solid State Chem. 2000, 152, 105–112.
- 16G. Férey, Science 1999, 283, 1125–1126.
- 17G. Férey, J. Solid State Chem. 2000, 152, 37–48.
- 18S. Huang, K. Christensen, M. V. Peskov, S. Yang, K. Li, X. Zou, J. Sun, Inorg. Chem. 2011, 50, 9921–9923.
- 19I. D. Williams, M. Wu, H. H. Sung, X. X. Zhang, J. Yu, Chem. Commun. 1998, 2463–2464.
- 20X. Liu, J. Zhou, L. An, R. Chen, F. Hu, Q. Tang, J. Solid State Chem. 2013, 201, 79–84.
- 21T. Yamase, M. Suzuki, K. Ohtaka, Dalton Trans. 1997, 44, 2463–2472.
- 22M. Wu, T. S.-C. Law, H. H.-Y. Sung, J. Cai, I. D. Williams, Chem. Commun. 2005, 1827–1829.
- 23J. T. Rijssenbeek, D. J. Rose, R. C. Haushalter, J. Zubieta, Angew. Chem. 1997, 109, 1049–1052;
10.1002/ange.19971090931 Google ScholarAngew. Chem. Int. Ed. Engl. 1997, 36, 1008–1010.
- 24P. Hermosilla-Ibáñez, P. E. Car, A. Vega, J. Costamagna, F. Caruso, J.-Y. Pivan, E. Le Fur, E. Spodine, D. Venegas-Yazigi, CrystEngComm 2012, 14, 5604–5612.
- 25J. Zhou, X. Liu, F. Hu, H. Zou, R. Li, X. Li, RSC Adv. 2012, 2, 10937–10940.
- 26Y.-Q. Sun, G.-M. Li, Y.-P. Chen, Dalton Trans. 2012, 41, 5774–5777.
- 27X. Liu, J. Zhou, H.-P. Xiao, C. Kong, H. Zou, Q. Tang, J. Li, New J. Chem. 2013, 37, 4077–4082.
- 28J. Zhou, X. Liu, R. Chen, X.-P. Xiao, F. Hu, H. Zou, Y. Zhou, C. Liu, L. Zhu, CrystEngComm. 2013, 15, 5057.
- 29H. Chen, Y. Deng, Z. Yu, H. Zhao, Q. Yao, X. Zou, J. Sun, Chem. Mater. 2013, 25, 5031–5036.
- 30V. A. Blatov, L. Carlucci, G. Ciani, D. M. Proserpio, CrystEngComm 2004, 6, 378–395.
- 31P. Yang, J. Wu, H. Zhou, B. Ye, Cryst. Growth Des. 2012, 12, 99–108.
- 32I. A. Baburin, V. A. Blatov, L. Carlucci, G. Ciani, D. M. Proserpio, Cryst. Growth Des. 2008, 8, 519–539.
- 33Z. Bacsik, R. Atluri, A. E. Garcia-Bennett, N. Hedin, Langmuir 2010, 26, 10013–10024.
- 34Z. Bacsik, N. Ahlsten, A. Ziadi, G. Zhao, A. E. Garcia-Bennett, B. Martín-Matute, N. Hedin, Langmuir 2011, 27, 11118–111128.
- 35Crysalis Sofware Syst. Version 171.35.19, Xcalibur CCD Syst. Oxford Diffr. Ltd., 2001.
- 36G. M. Sheldrick, Acta Crystallogr. Sect. A 2008, 64, 112–122.
- 37G. M. Sheldrick, Program for solution of crystal structures, University of Göttingen, 1997.
- 38A. L. Spek, J. Appl. Crystallogr. 2003, 36, 7–13.
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