Funktionelle Gemischtmetall-organische Gerüste mit Metalloliganden
Dr. Madhab C. Das
Department of Chemistry, University of Texas at San Antonio, San Antonio, Texas 78249-0698 (USA), Fax: (+1) 210-458-7428
Search for more papers by this authorDr. Shengchang Xiang
Department of Chemistry, University of Texas at San Antonio, San Antonio, Texas 78249-0698 (USA), Fax: (+1) 210-458-7428
Search for more papers by this authorDr. Zhangjing Zhang
Department of Chemistry, University of Texas at San Antonio, San Antonio, Texas 78249-0698 (USA), Fax: (+1) 210-458-7428
Search for more papers by this authorCorresponding Author
Prof. Dr. Banglin Chen
Department of Chemistry, University of Texas at San Antonio, San Antonio, Texas 78249-0698 (USA), Fax: (+1) 210-458-7428
Department of Chemistry, University of Texas at San Antonio, San Antonio, Texas 78249-0698 (USA), Fax: (+1) 210-458-7428Search for more papers by this authorDr. Madhab C. Das
Department of Chemistry, University of Texas at San Antonio, San Antonio, Texas 78249-0698 (USA), Fax: (+1) 210-458-7428
Search for more papers by this authorDr. Shengchang Xiang
Department of Chemistry, University of Texas at San Antonio, San Antonio, Texas 78249-0698 (USA), Fax: (+1) 210-458-7428
Search for more papers by this authorDr. Zhangjing Zhang
Department of Chemistry, University of Texas at San Antonio, San Antonio, Texas 78249-0698 (USA), Fax: (+1) 210-458-7428
Search for more papers by this authorCorresponding Author
Prof. Dr. Banglin Chen
Department of Chemistry, University of Texas at San Antonio, San Antonio, Texas 78249-0698 (USA), Fax: (+1) 210-458-7428
Department of Chemistry, University of Texas at San Antonio, San Antonio, Texas 78249-0698 (USA), Fax: (+1) 210-458-7428Search for more papers by this authorAbstract
Die Immobilisierung funktioneller Zentren innerhalb von Metall-organischen Gerüsten (MOFs) ist für ihre Fähigkeit zur Erkennung kleiner Moleküle und somit für ihre funktionellen Eigenschaften von großer Bedeutung. Das Metalloligandverfahren ermöglicht es uns, eine Vielzahl unterschiedlicher funktioneller Zentren wie offene, katalytisch aktive und photoaktive Metallzentren, chirale Porenumgebungen und Poren abstimmbarer Größe/Krümmung in Gemischtmetall-organischen Gerüsten (M′MOFs) zielgerichtet zu immobilisieren. In diesem Kurzaufsatz richten wir die Aufmerksamkeit auf einige wichtige funktionelle M′MOFs mit Metalloliganden für die Gasspeicherung und -trennung, die enantioselektive Trennung, die heterogene asymmetrische Katalyse und die Sensorik sowie als photoaktive, nanoskalige Materialien für die Wirkstoff-Freisetzung und biomedizinische Bildgebung.
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