Die Suche nach Katalysatoren für die Olefinpolymerisation hat Komplexe mit 1,1′-Ferrocendi(amido)-Chelatliganden in den Brennpunkt rücken lassen. Die Stabilisierung kationischer Titanzentren durch einen solchen Liganden kann zur Bildung einer dativen Fe→Ti-Heterodimetall-Bindung führen, wie sie im Kation von 1 vorliegt.

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Volume114, Issue6

March 15, 2002

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1,1′-Ferrocendi(amido)-Chelatliganden in Titan- und Zirconiumkomplexen

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1,1′-Ferrocendi(amido)-Chelatliganden in Titan- und Zirconiumkomplexen

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