In Situ Electrochemical Polymerization of Cathode Electrolyte Interphase Enabling High-Performance Lithium Metal Batteries
Shipeng Sun
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorJiangtao Yu
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorXinyu Ma
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorPengda Fang
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorMingchen Yang
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorJinhua Yang
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorMingzhu Wu
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorCorresponding Author
Yin Hu
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
E-mail: [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Feng Yan
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, China
E-mail: [email protected]; [email protected]
Search for more papers by this authorShipeng Sun
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorJiangtao Yu
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorXinyu Ma
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorPengda Fang
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorMingchen Yang
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorJinhua Yang
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorMingzhu Wu
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorCorresponding Author
Yin Hu
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
E-mail: [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Feng Yan
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, China
E-mail: [email protected]; [email protected]
Search for more papers by this authorAbstract
Lithium metal batteries (LMBs) with high-voltage nickel-rich cathodes show great potential as energy storage devices due to their exceptional capacity and power density. However, the detrimental parasitic side reactions at the cathode electrolyte interface result in rapid capacity decay. Herein, a polymerizable electrolyte additive, pyrrole-1-propionic acid (PA), which can be in situ electrochemically polymerized on the cathode surface and involved in forming cathode electrolyte interphase (CEI) film during cycling is proposed. The formed CEI film prevents the formation of microcracks in LiNi0.8Co0.1Mn0.1O2 (NCM811) secondary particles and mitigates parasitic reactions. Additionally, the COO− anions of PA promote the acceleration of Li+ transport from cathode particles and increase charging rates. The Li||NCM811 batteries with PA in the electrolyte exhibit a high capacity retention of 83.83% after 200 cycles at 4.3 V, and maintain 80.88% capacity after 150 cycles at 4.6 V. This work provides an effective strategy for enhancing interface stability of high-voltage nickel-rich cathodes by forming stable CEI film.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
| Filename | Description |
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| smll202403145-sup-0001-SuppMat.pdf1.3 MB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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