Volume 20, Issue 26 2310426
Review

Metal Phosphide Anodes in Sodium-Ion Batteries: Latest Applications and Progress

Longzhen Wang

Longzhen Wang

College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, 201620 P. R. China

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Qingmeng Li

Qingmeng Li

College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, 201620 P. R. China

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Zhiyuan Chen

Zhiyuan Chen

College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, 201620 P. R. China

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Yiting Wang

Yiting Wang

College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, 201620 P. R. China

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Yifei Li

Yifei Li

College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, 201620 P. R. China

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Jiali Chai

Jiali Chai

College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, 201620 P. R. China

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Ning Han

Ning Han

Department of Materials Engineering, KU Leuven, Leuven, 3001 Belgium

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Bohejin Tang

Corresponding Author

Bohejin Tang

College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, 201620 P. R. China

E-mail: [email protected]; [email protected]; [email protected]

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Yichuan Rui

Corresponding Author

Yichuan Rui

College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, 201620 P. R. China

E-mail: [email protected]; [email protected]; [email protected]

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Lei Jiang

Corresponding Author

Lei Jiang

Department of Chemical Engineering, KU Leuven, Celestijnenlaan 200F, Heverlee, B-3001 Belgium

E-mail: [email protected]; [email protected]; [email protected]

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First published: 17 January 2024
Citations: 34

Abstract

Sodium-ion batteries (SIBs), as the next-generation high-performance electrochemical energy storage devices, have attracted widespread attention due to their cost-effectiveness and wide geographical distribution of sodium. As a crucial component of the structure of SIBs, the anode material plays a crucial role in determining its electrochemical performance. Significantly, metal phosphide exhibits remarkable application prospects as an anode material for SIBs because of its low redox potential and high theoretical capacity. However, due to volume expansion limitations and other factors, the rate and cycling performance of metal phosphides have gradually declined. To address these challenges, various viable solutions have been explored. In this paper, the recent research progress of metal phosphide materials for SIBs is systematically reviewed, including the synthesis strategy of metal phosphide, the storage mechanism of sodium ions, and the application of metal phosphide in electrochemical aspects. In addition, future challenges and opportunities based on current developments are presented.

Conflict of Interest

The authors declare no conflict of interest.

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