In-Situ Fabrication of Sustainable-N-Doped-Carbon-Nanotube-Encapsulated CoNi Heterogenous Nanocomposites for High-Efficiency Electromagnetic Wave Absorption
Xue Zhang
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
Contribution: Investigation (lead), Methodology (lead), Writing - original draft (lead), Writing - review & editing (lead)
Search for more papers by this authorXuelei Tian
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
Contribution: Supervision (lead)
Search for more papers by this authorJing Qiao
School of Mechanical Engineering, Shandong University, Jinan, 250061 P. R. China
Contribution: Investigation (equal), Software (lead), Writing - review & editing (equal)
Search for more papers by this authorXinrui Fang
Jinan Institute of Special Structures of Aviation Industry of China (Jinan 637 Institute of Aviation Industry of China), Jinan, 250000 P. R. China
Contribution: Project administration (equal)
Search for more papers by this authorKaiye Liu
Jinan Institute of Special Structures of Aviation Industry of China (Jinan 637 Institute of Aviation Industry of China), Jinan, 250000 P. R. China
Contribution: Project administration (equal)
Search for more papers by this authorChang Liu
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
Contribution: Investigation (equal), Software (equal)
Search for more papers by this authorJingpeng Lin
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
Contribution: Investigation (equal), Validation (equal)
Search for more papers by this authorLutong Li
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
Contribution: Investigation (equal), Validation (equal)
Search for more papers by this authorWei Liu
State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100 P. R. China
Contribution: Funding acquisition (supporting), Resources (supporting)
Search for more papers by this authorCorresponding Author
Jiurong Liu
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
E-mail: [email protected]; [email protected]
Contribution: Conceptualization (lead), Funding acquisition (lead), Supervision (lead)
Search for more papers by this authorCorresponding Author
Zhihui Zeng
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
E-mail: [email protected]; [email protected]
Contribution: Conceptualization (lead), Funding acquisition (lead), Supervision (lead), Writing - review & editing (lead)
Search for more papers by this authorXue Zhang
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
Contribution: Investigation (lead), Methodology (lead), Writing - original draft (lead), Writing - review & editing (lead)
Search for more papers by this authorXuelei Tian
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
Contribution: Supervision (lead)
Search for more papers by this authorJing Qiao
School of Mechanical Engineering, Shandong University, Jinan, 250061 P. R. China
Contribution: Investigation (equal), Software (lead), Writing - review & editing (equal)
Search for more papers by this authorXinrui Fang
Jinan Institute of Special Structures of Aviation Industry of China (Jinan 637 Institute of Aviation Industry of China), Jinan, 250000 P. R. China
Contribution: Project administration (equal)
Search for more papers by this authorKaiye Liu
Jinan Institute of Special Structures of Aviation Industry of China (Jinan 637 Institute of Aviation Industry of China), Jinan, 250000 P. R. China
Contribution: Project administration (equal)
Search for more papers by this authorChang Liu
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
Contribution: Investigation (equal), Software (equal)
Search for more papers by this authorJingpeng Lin
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
Contribution: Investigation (equal), Validation (equal)
Search for more papers by this authorLutong Li
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
Contribution: Investigation (equal), Validation (equal)
Search for more papers by this authorWei Liu
State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100 P. R. China
Contribution: Funding acquisition (supporting), Resources (supporting)
Search for more papers by this authorCorresponding Author
Jiurong Liu
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
E-mail: [email protected]; [email protected]
Contribution: Conceptualization (lead), Funding acquisition (lead), Supervision (lead)
Search for more papers by this authorCorresponding Author
Zhihui Zeng
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061 P. R. China
E-mail: [email protected]; [email protected]
Contribution: Conceptualization (lead), Funding acquisition (lead), Supervision (lead), Writing - review & editing (lead)
Search for more papers by this authorAbstract
Developing carbon encapsulated magnetic composites with rational design of microstructure for achieving high-performance electromagnetic wave (EMW) absorption in a facile, sustainable, and energy-efficiency approach is highly demanded yet remains challenging. Here, a type of N-doped carbon nanotube (CNT) encapsulated CoNi alloy nanocomposites with diverse heterostructures are synthesized via the facile, sustainable autocatalytic pyrolysis of porous CoNi-layered double hydroxide/melamine. Specifically, the formation mechanism of the encapsulated structure and the effects of heterogenous microstructure and composition on the EMW absorption performance are ascertained. With the presence of melamine, CoNi alloy emerges its autocatalysis effect to generate N-doped CNTs, leading to unique heterostructure and high oxidation stability. The abundant heterogeneous interfaces induce strong interfacial polarization to EMWs and optimize impedance matching characteristic. Combined with the inherent high conductive and magnetic loss capabilities, the nanocomposites accomplish a high-efficiency EMW absorption performance even at a low filling ratio. The minimum reflection loss of −84.0 dB at the thickness of 3.2 mm and a maximum effective bandwidth of 4.3 GHz are obtained, comparable to the best EMW absorbers. Integrated with the facile, controllable, and sustainable preparation approach of the heterogenous nanocomposites, the work shows a great promise of the nanocarbon encapsulation protocol for achieving lightweight, high-performance EMW absorption materials.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
| Filename | Description |
|---|---|
| smll202302686-sup-0001-SuppMat.pdf1.7 MB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1X.-X. Wang, C. Wen-Qiang, C. Mao-Sheng, Y. Jie, Adv. Mater. 2020, 32, 2002112.
- 2Q. Li, Z. Zhang, L. Qi, Q. Liao, Z. Kang, Y. Zhang, Adv. Sci. 2019, 6, 1801057.
- 3W. Huang, Q. Qiu, X. Yang, S. Zuo, J. Bai, H. Zhang, K. Pei, R. Che, Nano-Micro Lett. 2022, 14, 96.
- 4Z. Wu, H. W. Cheng, C. Jin, B. Yang, C. Xu, K. Pei, H. Zhang, Z. Yang, R. Che, Adv. Mater. 2022, 34, 2107538.
- 5Z. Zhao, L. Zhang, H. Wu, Adv. Mater. 2022, 34, 2205376.
- 6Q. Song, F. Ye, L. Kong, Q. Shen, L. Han, L. Feng, G. Yu, Y. Pan, H. Li, Adv. Funct. Mater. 2020, 30, 2000475.
- 7D. W. Lin, Y. Zhou, K. Kobashi, G. H. Chen, D. N. Futaba, K. Hata, Adv. Funct. Mater. 2022, 33, 2211180.
- 8J. Cheng, H. Zhang, H. Wang, Z. Huang, H. Raza, C. Hou, G. Zheng, D. Zhang, Q. Zheng, R. Che, Adv. Funct. Mater. 2022, 32, 2201129.
- 9L. Liang, Q. Li, X. Yan, Y. Feng, Y. Wang, H. B. Zhang, X. Zhou, C. Liu, C. Shen, X. Xie, ACS Nano 2021, 15, 6622.
- 10J. Yang, J. Wang, H. Li, Z. Wu, Y. Xing, Y. Chen, L. Liu, Adv. Sci. 2022, 9, 2101988.
- 11L. Wu, S. Shi, G. Wang, P. Mou, X. Liu, J. Liu, L. Li, C. Du, Adv. Funct. Mater. 2022, 32, 2209898.
- 12X. Xu, S. Shi, Y. Tang, G. Wang, M. Zhou, G. Zhao, X. Zhou, S. Lin, F. Meng, Adv. Sci. 2021, 8, 2002658.
- 13X. C. Zhang, B. Li, J. Xu, X. Zhang, Y. A. Shi, C. L. Zhu, X. T. Zhang, Y. J. Chen, Adv. Funct. Mater. 2023, 33, 2210456.
- 14X. Huan, H. Wang, W. Deng, J. Yan, K. Xu, H. Geng, X. Guo, X. Jia, J. Zhou, X. Yang, Small 2022, 18, 2105411.
- 15H. Sun, R. Che, X. You, Y. Jiang, Z. Yang, J. Deng, L. Qiu, H. Peng, Adv. Mater. 2014, 26, 8120.
- 16L. Wang, M. Huang, X. Yu, W. You, J. Zhang, X. Liu, M. Wang, R. Che, Nano-Micro Lett. 2020, 12, 150.
- 17W. Huang, J. Chen, W. Gao, L. Wang, P. Liu, Y. Zhang, Z. Yin, Y. Yang, Carbon 2022, 197, 129.
- 18X. Liu, Y. Duan, Y. Guo, H. Pang, Z. Li, X. Sun, T. Wang, Nano-Micro Lett. 2022, 14, 142.
- 19M. Qiao, J. Li, S. Li, D. Wei, X. Lei, W. Lei, J. Wei, Q. Zhang, M. Ma, J. Alloys Compd. 2022, 926, 166854.
- 20B. Yang, J. Fang, C. Xu, H. Cao, R. Zhang, B. Zhao, M. Huang, X. Wang, H. Lv, R. Che, Nano-Micro Lett. 2022, 14, 170.
- 21X. Yang, W. Gao, J. Chen, X. Lu, D. Yang, Y. Kang, Q. Liu, Y. Qing, W. Huang, Chin. J. Chem. 2023, 41, 64.
- 22W. Huang, W. Gao, S. Zuo, L. Zhang, K. Pei, P. Liu, R. Che, H. Zhang, J. Mater. Chem. A 2022, 10, 1290.
- 23L. Wang, X. Yu, X. Li, J. Zhang, M. Wang, R. Che, Chem. Eng. J. 2020, 383, 123099.
- 24Z. Man, P. Li, D. Zhou, Y. Wang, X. Liang, R. Zang, P. Li, Y. Zuo, Y. M. Lam, G. Wang, Nano Lett. 2020, 20, 3769.
- 25P. He, W. J. Ma, J. Xu, J. Wei, X. Y. Liu, P. Y. Zuo, Z. K. Cui, Q. X. Zhuang, Small 2023, 19, 2204649.
- 26B. Wen, H. Yang, Y. Lin, L. Ma, Y. Qiu, F. Hu, Y. Zheng, J. Mater. Chem. A 2021, 9, 3567.
- 27W. Huang, S. Wang, X. Yang, X. Zhang, Y. Zhang, K. Pei, R. Che, Carbon 2022, 195, 44.
- 28X. Huang, J. Wei, Y. Zhang, B. Qian, Q. Jia, J. Liu, X. Zhao, G. Shao, Nano-Micro Lett. 2022, 14, 107.
- 29X. Li, L. Wang, X. Li, J. Zhang, M. Wang, R. Che, Carbon 2021, 172, 15.
- 30A. C. Ferrari, J. Robertson, Phys. Rev. B 2000, 61, 14095.
- 31J. Qiao, X. Zhang, C. Liu, Z. Zeng, Y. Yang, L. Wu, F. Wang, Z. Wang, W. Liu, J. Liu, Carbon 2022, 191, 525.
- 32J. Qiao, X. Zhang, C. Liu, L. Lyu, Y. Yang, Z. Wang, L. Wu, W. Liu, F. Wang, J. Liu, Nano-Micro Lett. 2021, 13, 75.
- 33W. Liu, S. Tan, Z. Yang, G. Ji, ACS Appl. Mater. Interfaces 2018, 10, 31610.
- 34J. Qiao, X. Zhang, C. Liu, L. Lyu, Z. Wang, L. Wu, W. Liu, F. Wang, J. Liu, Composites, Part B 2020, 200, 108343.
- 35H. J. Yang, W. Q. Cao, D. Q. Zhang, T. J. Su, H. L. Shi, W. Z. Wang, J. Yuan, M. S. Cao, ACS Appl. Mater. Interfaces 2015, 7, 7073.
- 36M. Li, W. Zhu, X. Li, H. Xu, X. Fan, H. Wu, F. Ye, J. Xue, X. Li, L. Cheng, L. Zhang, Adv. Sci. 2022, 9, 2201118.
