Functionalized Naphthalene Diimides as Low-Cost Organic Cathodes for Potassium Batteries
Anastasiia D. Blokhina
Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Bolshoy Boulevard 30, bld. 1, Moscow, 121205 Russia
Search for more papers by this authorAlexey V. Kozlov
Department of Kinetics and Catalysis, Institute for Problems of Chemical Physics RAS, Acad. Semenov str. 1, Chernogolovka, 142432 Russia
Search for more papers by this authorIrina V. Klimovich
Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Bolshoy Boulevard 30, bld. 1, Moscow, 121205 Russia
Department of Kinetics and Catalysis, Institute for Problems of Chemical Physics RAS, Acad. Semenov str. 1, Chernogolovka, 142432 Russia
Search for more papers by this authorCorresponding Author
Pavel A. Troshin
Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Bolshoy Boulevard 30, bld. 1, Moscow, 121205 Russia
Department of Kinetics and Catalysis, Institute for Problems of Chemical Physics RAS, Acad. Semenov str. 1, Chernogolovka, 142432 Russia
Search for more papers by this authorAnastasiia D. Blokhina
Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Bolshoy Boulevard 30, bld. 1, Moscow, 121205 Russia
Search for more papers by this authorAlexey V. Kozlov
Department of Kinetics and Catalysis, Institute for Problems of Chemical Physics RAS, Acad. Semenov str. 1, Chernogolovka, 142432 Russia
Search for more papers by this authorIrina V. Klimovich
Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Bolshoy Boulevard 30, bld. 1, Moscow, 121205 Russia
Department of Kinetics and Catalysis, Institute for Problems of Chemical Physics RAS, Acad. Semenov str. 1, Chernogolovka, 142432 Russia
Search for more papers by this authorCorresponding Author
Pavel A. Troshin
Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Bolshoy Boulevard 30, bld. 1, Moscow, 121205 Russia
Department of Kinetics and Catalysis, Institute for Problems of Chemical Physics RAS, Acad. Semenov str. 1, Chernogolovka, 142432 Russia
Search for more papers by this authorAbstract
Herein, the synthesis and investigation of two naphthalene diimide derivatives with the ethylenesulfonic (NDI1) and methylenecarboxylic (NDI2) groups appended to diimide nitrogen atoms in the form of potassium salts are reported. Synthesized compounds are characterized by 1H NMR, 13C NMR, and elemental analysis. Electrochemical performance of the diimides is evaluated in half-cells with potassium anodes. Both materials show a decent specific capacity of 86–96 mAh g−1 at the first cycle at C/10 current rate in combination with average cell discharge potentials approaching 2.2 V. The obtained results suggest that synthesized materials can be considered as cheap electrode materials for potassium batteries designed for stationary energy storage applications.
Conflict of Interest
The authors declare no conflict of interest.
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