Volume 31, Issue 5 pp. 449-460
RESEARCH ARTICLE

Achievement of 25.54% power conversion efficiency by optimization of current losses at the front side of silicon heterojunction solar cells

Tianwei Tang

Tianwei Tang

Suzhou Maxwell Technologies Co., Ltd., Suzhou, Jiangsu, China

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Cao Yu

Corresponding Author

Cao Yu

Suzhou Maxwell Technologies Co., Ltd., Suzhou, Jiangsu, China

Correspondence

Cao Yu, Suzhou Maxwell Technologies Co., Ltd., No. 1801 Pangjin Road, Wujiang Economic Development Zone, Suzhou, Jiangsu 215200, China.

Email: [email protected]

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Chen-Wei Peng

Chen-Wei Peng

Suzhou Maxwell Technologies Co., Ltd., Suzhou, Jiangsu, China

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Gangqiang Dong

Gangqiang Dong

Suzhou Maxwell Technologies Co., Ltd., Suzhou, Jiangsu, China

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Chenran He

Chenran He

Suzhou Maxwell Technologies Co., Ltd., Suzhou, Jiangsu, China

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Xiaochao Ran

Xiaochao Ran

Suzhou Maxwell Technologies Co., Ltd., Suzhou, Jiangsu, China

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Hao Jiang

Hao Jiang

Suzhou Maxwell Technologies Co., Ltd., Suzhou, Jiangsu, China

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Vince Allen

Vince Allen

Sundrive Solar Pty., Ltd., Kirrawee, NSW, Australia

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Xinmin Cao

Xinmin Cao

Suzhou Maxwell Technologies Co., Ltd., Suzhou, Jiangsu, China

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Jian Zhou

Jian Zhou

Suzhou Maxwell Technologies Co., Ltd., Suzhou, Jiangsu, China

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First published: 30 October 2022
Citations: 8

Tianwei Tang and Cao Yu contributed equally.

Funding information: Australian Renewable Energy Agency (ARENA) as part of ARENA's Advancing Renewables Program; Carbon Emission Peak and Carbon Neutrality Special Fund of Jiangsu Province, Grant/Award Number: BA2022205

Abstract

Parasitic absorption in the front window layers of transparent conductive oxide (TCO) films and carrier selective collection layers and the optical shading losses from the metallic finger grid mainly limit the current generation in silicon heterojunction (SHJ) solar cells. In this work, we demonstrate an improved short-circuit current density (Jsc) of 40.24 mA/cm2 through a combination of novel window layers composed of transition metal doped indium oxide (IMO) and hydrogenated nanocrystalline silicon oxide (nc-SiOx:H) films and Cu plating for SHJ solar cells. By introducing water vapor during direct current (DC) magnetron sputtering deposition process, IMO films show a large optical band gap (Eg) of about 3.88 eV and high mobility up to 83.2 cm2/V·s, while maintaining a low carrier concentration, which leads to high transparency and low near-infrared (NIR) free carrier absorption (FCA). In addition to its high deposition rate and crystalline volume fraction, we found that nc-SiOx:H films deposited by very high frequency (VHF) excited plasma-enhanced chemical vapor deposition (PECVD) show an excellent surface passivation quality, which not only improves the open circuit voltage (Voc) of SHJ cells but also increases the Jsc through improved carrier selective collection. The quantified Jsc breakdown analysis was performed to identify the room for improvement, and it showed that the front shading loss (about 1.32 mA/cm2) is the largest portion. By combining the benefits of these window layer enhancements with the further use of fine line width and conductivity of Cu plating, SHJ solar cells, with a Jsc improvement of 0.57 mA/cm2 and a certified efficiency of 25.54%, were achieved on a total area of 274.5 cm2 using in-house pilot production line equipment.

DATA AVAILABILITY STATEMENT

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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