Clustering-Triggered Emission Mechanism of Sulfur Ester-Polyacrylamide Aqueous Solution
Xiaoping Lei
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, 310018 China
Search for more papers by this authorYuanchao Zhang
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, 310018 China
Search for more papers by this authorQingfeng Wu
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, 310018 China
Search for more papers by this authorXiangxi Zhang
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, 310018 China
Search for more papers by this authorCorresponding Author
Qing Zhou
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, 310018 China
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Departmentof Polymer Science and Engineering, Zhejiang University, Hangzhou, 310058 China
Zhejiang Sci-Tech University Shaoxing-Keqiao Research Institute, Zhejiang Provincial Innovation Center of Advanced Textile Technology, Building 7, Cross border E-commerce Park, Huashe Street, Keqiao District, Shaoxing, Zhejiang, 312030 China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Qi Li
Zhejiang Sci-Tech University Shaoxing-Keqiao Research Institute, Zhejiang Provincial Innovation Center of Advanced Textile Technology, Building 7, Cross border E-commerce Park, Huashe Street, Keqiao District, Shaoxing, Zhejiang, 312030 China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Lingmin Yi
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, 310018 China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorXiaoping Lei
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, 310018 China
Search for more papers by this authorYuanchao Zhang
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, 310018 China
Search for more papers by this authorQingfeng Wu
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, 310018 China
Search for more papers by this authorXiangxi Zhang
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, 310018 China
Search for more papers by this authorCorresponding Author
Qing Zhou
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, 310018 China
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Departmentof Polymer Science and Engineering, Zhejiang University, Hangzhou, 310058 China
Zhejiang Sci-Tech University Shaoxing-Keqiao Research Institute, Zhejiang Provincial Innovation Center of Advanced Textile Technology, Building 7, Cross border E-commerce Park, Huashe Street, Keqiao District, Shaoxing, Zhejiang, 312030 China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Qi Li
Zhejiang Sci-Tech University Shaoxing-Keqiao Research Institute, Zhejiang Provincial Innovation Center of Advanced Textile Technology, Building 7, Cross border E-commerce Park, Huashe Street, Keqiao District, Shaoxing, Zhejiang, 312030 China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Lingmin Yi
Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, 310018 China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorAbstract
Most nonconventional luminogens enjoy good water solubility and biocompatibility, showing unique application prospects in fields like biological imaging. Although clustering-triggered emission (CTE) mechanisms have been proposed to explain such emissions, it has not been thoroughly elucidated, which limits their development and application. Herein, the photoluminescence properties of polyacrylamide prepared by reversible addition-fragmentation chain transfer (RAFT) polymerization aqueous solution are utilized to further investigate the effects of changes in concentration, in order to elucidate the emission mechanism through transmission electron microscopy (TEM), small angle X-ray scattering (SAXS) and theoretical calculation. The results showed that the size distribution, morphology, and distance between the polymer clusters formed in the water solution are successfully correlated with the cluster emission centers. The emission mechanism of nonconventional luminogens solutions is more clearly and intuitively elucidated, which has a promoting effect on the emission and application of this field. It provides a strategy a strategy to clarify the CTE mechanism of nonconventional luminogens solution more clearly.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the supplementary material of this article.
Supporting Information
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| marc202400307-sup-0001-SuppMat.pdf558.6 KB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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