Research Article

Characterization and Properties of Polylactic Acid/Cottonseed Protein Bioplastics

Yanli Jiang

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

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Peng Yan,

Peng Yan

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

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Lingwei Mai,

Lingwei Mai

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

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Hai Liu,

Hai Liu

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

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Xiaobo Liu,

Xiaobo Liu

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

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Chufen Yang,

Chufen Yang

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory (Rongjiang Laboratory), Jieyang, 515200 China

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Jinping Peng,

Jinping Peng

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory (Rongjiang Laboratory), Jieyang, 515200 China

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Hangbo Yue,

Corresponding Author

Hangbo Yue

[email protected]

orcid.org/0000-0003-2557-1427

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory (Rongjiang Laboratory), Jieyang, 515200 China

E-mail: [email protected]

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Yanli Jiang,

Yanli Jiang

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

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Peng Yan,

Peng Yan

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

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Lingwei Mai,

Lingwei Mai

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

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Hai Liu,

Hai Liu

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

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Xiaobo Liu,

Xiaobo Liu

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

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Chufen Yang,

Chufen Yang

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory (Rongjiang Laboratory), Jieyang, 515200 China

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Jinping Peng,

Jinping Peng

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory (Rongjiang Laboratory), Jieyang, 515200 China

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Hangbo Yue,

Corresponding Author

Hangbo Yue

[email protected]

orcid.org/0000-0003-2557-1427

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006 China

Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory (Rongjiang Laboratory), Jieyang, 515200 China

E-mail: [email protected]

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First published: 13 August 2024

https://doi.org/10.1002/macp.202400191

Citations: 2

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Abstract

In this study, polylactic acid (PLA) is compounded with cottonseed protein concentrate (CPC) by melt blending under the compatibilization of maleic anhydride (MA), and then hot-pressed to prepare PLA/CPC composite bioplastics. The attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy showed that high temperature and compatibilizer induced the protein secondary structure to transition. CPC can be used as a heterogeneous PLA nucleating agent, effectively accelerating PLA crystallization, which is characterized by polarization optical microscopy (POM), synchrotron radiation wide-angle X-ray scattering (WAXS) and differential scanning calorimetry (DSC). The highest crystallinity of the PLA/CPC10 composite is 8.9% higher than that of neat PLA. The unfolding of the protein secondary structure is likely to promote an orderly arrangement of PLA crystals, showing strong binding forces between them. Moreover, the CPC/PLA interfacial compatibility is improved by the addition of a small amount of maleic anhydride. The increased crystallinity and interfacial compatibility contribute to the improved mechanical properties, water resistance, and thermal stability of the bioplastics. Environmentally friendly plastic handicrafts (e.g., commemorative emblems, flower pots, ornaments, etc.) can be fabricated using these biocomposites for future value-added applications.

Conflict of Interest

The authors declare no conflict of interest.

Open Research

Data Availability Statement

The data that support the findings of this study are available from the corresponding author upon reasonable request.

Supporting Information

References

1N. Laskar, U. Kumar, Environ. Technol. Innovat. 2019, 14, 100352.
10.1016/j.eti.2019.100352
Web of Science® Google Scholar
2W. Ali, H. Ali, S. Souissi, P. Zinck, Environ. Chem. Lett. 2023, 21, 1991.
10.1007/s10311-023-01601-6
CAS Web of Science® Google Scholar
3A. R. Othman, H. Abu Hasan, M. H. Muhamad, N. I. Ismail, S. R. S. Abdullah, Environ. Chem. Lett. 2021, 19, 3057.
10.1007/s10311-021-01197-9
CAS Web of Science® Google Scholar
4T. Mekonnen, P. Mussone, H. Khalil, D. Bressler, J. Mater. Chem. A 2013, 1, 13379.
10.1039/c3ta12555f
CAS Web of Science® Google Scholar
5W. Leal, A. L. Salvia, A. Bonoli, U. A. Saari, V. Voronova, M. Kloga, S. S. Kumbhar, K. Olszewski, D. M. De Quevedo, J. Barbir, Sci. Total Environ. 2021, 755, 142732.
10.1016/j.scitotenv.2020.142732
PubMed Google Scholar
6 Bioplastics Market Development Update 2023, European Bioplastics, Berlin, Germany 2023.
Google Scholar
7M. Karamanlioglu, R. Preziosi, G. D. Robson, Polym. Degrad. Stab. 2017, 137, 122.
10.1016/j.polymdegradstab.2017.01.009
CAS Web of Science® Google Scholar
8S. Nanda, B. R. Patra, R. Patel, J. Bakos, A. K. Dalai, Environ. Chem. Lett. 2022, 20, 379.
10.1007/s10311-021-01334-4
CAS PubMed Web of Science® Google Scholar
9R. Nandhini, B. Sivaprakash, N. Rajamohan, D. V. N. Vo, Environ. Chem. Lett. 2023, 21, 403.
10.1007/s10311-022-01505-x
CAS Web of Science® Google Scholar
10J. Kuang, J. H. Wang, Y. Bai, Y. C. Li, Eur. Polym. J. 2019, 121, 109286.
10.1016/j.eurpolymj.2019.109286
CAS Web of Science® Google Scholar
11M. Niaounakis, E. Kontou, S. Pispas, M. Kafetzi, D. Giaouzi, Polym. Eng. Sci. 2019, 59, E432.
10.1002/pen.25079
CAS Web of Science® Google Scholar
12Z. Q. Li, L. Liu, Y. Rao, L. C. Ran, T. Wu, R. Nie, D. Anna, Y. L. Li, Z. M. Che, Polym. Eng. Sci. 2019, 59, 2121.
10.1002/pen.25214
CAS Web of Science® Google Scholar
13T. Tabi, T. Ageyeva, J. G. Kovacs, Mater. Today Commun. 2022, 32, 103936.
10.1016/j.mtcomm.2022.103936
CAS Web of Science® Google Scholar
14X. H. Gong, L. Pan, C. Y. Tang, L. Chen, C. Q. Li, C. G. Wu, W. C. Law, X. T. Wang, C. P. Tsui, X. L. Xie, Compos. Part B-Eng. 2016, 91, 103.
10.1016/j.compositesb.2015.12.032
CAS Web of Science® Google Scholar
15P. Chen, K. S. Yu, Y. Q. Wang, W. B. Wang, H. F. Zhou, H. Q. Li, J. G. Mi, X. D. Wang, J. Polym. Environ. 2018, 26, 3718.
10.1007/s10924-018-1251-2
CAS Web of Science® Google Scholar
16A. P. Mathew, K. Oksman, M. Sain, J. Appl. Polym. Sci. 2005, 97, 2014.
10.1002/app.21779
CAS Web of Science® Google Scholar
17S. Barrau, C. Vanmansart, M. Moreau, A. Addad, G. Stoclet, J. M. Lefebvre, R. Seguela, Macromolecules 2011, 44, 6496.
10.1021/ma200842n
CAS Web of Science® Google Scholar
18X. Z. Zhang, J. X. Shi, J. Zhou, J. W. Nan, Polym. Bull. 2022, 79, 5481.
10.1007/s00289-021-03567-3
CAS Web of Science® Google Scholar
19M. Aouay, A. Magnin, J. L. Putaux, S. Boufi, Int. J. Biol. Macromol. 2022, 218, 588.
10.1016/j.ijbiomac.2022.07.069
CAS PubMed Google Scholar
20N. Wang, C. Zhang, Y. Weng, J. Appl. Polym. Sci. 2021, 138, 50199.
10.1002/app.50199
CAS Web of Science® Google Scholar
21L. J. Li, H. B. Yue, Q. Q. Wu, J. P. Fernandez-Blazquerz, P. S. Shuttleworth, J. H. Clark, J. W. Guo, Compos. Sci. Technol. 2022, 225, 109480.
10.1016/j.compscitech.2022.109480
Google Scholar
22Y. Chen, L. N. Zhang, L. B. Du, Ind. Eng. Chem. Res. 2003, 42, 6786.
10.1021/ie0301381
CAS Web of Science® Google Scholar
23W. J. Chen, J. Ding, X. M. Yan, W. Yan, M. He, G. Q. Yin, Polym.-Basel 2019, 11, 2096.
10.3390/polym11122096
CAS PubMed Web of Science® Google Scholar
24 Oilseeds: World Markets and Trade, United States Department of Agriculture, 2024869.
Google Scholar
25M. Kumar, M. Tomar, S. Punia, S. Grasso, F. Arrutia, J. Choudhary, S. Singh, P. Verma, A. Mahapatra, S. Patil, Radha, S. D., J. Potkule, S. Saxena, R. Amarowicz, Trends Food Sci. Tech. 2021, 111, 100.
10.1016/j.tifs.2021.02.058
CAS Google Scholar
26H. B. Yue, Y. D. Cui, P. S. Shuttleworth, J. H. Clark, Green Chem. 2012, 14, 2009.
10.1039/c2gc35509d
CAS Web of Science® Google Scholar
27G. E. A. Verginio, T. L. D. Montanheiro, L. S. Montagna, J. Marini, F. R. Passador, J. Appl. Polym. Sci. 2021, 138, 50087.
10.1002/app.50087
CAS Web of Science® Google Scholar
28T. L. D. Montanheiro, F. R. Passador, M. P. de Oliveira, N. Durán, A. P. Lemes, Mater. Res.-Ibero-Am. J. 2016, 19, 229.
10.1590/1980-5373-MR-2015-0496
CAS Google Scholar
29H. B. Yue, C. Xu, J. C. Yao, M. He, G. Q. Yin, Y. D. Cui, C. F. Yang, J. W. Guo, Cellulose 2022, 29, 5869.
10.1007/s10570-022-04611-9
CAS Web of Science® Google Scholar
30C. Mortalò, P. Russo, E. Miorin, V. Zin, E. Paradisi, C. Leonelli, Polymer 2023, 282, 126162.
10.1016/j.polymer.2023.126162
CAS Web of Science® Google Scholar
31S. Wasti, E. Triggs, R. Farag, M. Auad, S. Adhikari, D. Bajwa, M. Li, A. J. Ragauskas, Compos. Part B-Eng. 2021, 205, 108483.
10.1016/j.compositesb.2020.108483
CAS Web of Science® Google Scholar
32X. H. Ge, X. Y. Huang, L. P. Zhou, Y. Wang, Food Packag. Shelf 2022, 34, 100977.
10.1016/j.fpsl.2022.100977
CAS Google Scholar
33T. R. Arruda, P. C. Bernardes, A. R. F. E. Moraes, C. S. Marques, P. F. Pinheiro, T. V. de Oliveira, S. O. Ferreira, E. A. A. Naves, N. D. F. Soares, Int. J. Biol. Macromol. 2023, 228, 23.
10.1016/j.ijbiomac.2022.12.191
CAS PubMed Google Scholar
34N. Mohamad, M. M. Mazlan, I. S. M. A. Tawakkal, R. A. Talib, L. K. Kian, H. Fouad, M. Jawaid, Int. J. Biol. Macromol. 2020, 163, 1451.
10.1016/j.ijbiomac.2020.07.209
CAS PubMed Web of Science® Google Scholar
35E. F. Sucinda, M. S. A. Majid, M. J. M. Ridzuan, E. M. Cheng, H. A. Alshahrani, N. Mamat, Int. J. Biol. Macromol. 2021, 187, 43.
10.1016/j.ijbiomac.2021.07.069
CAS PubMed Web of Science® Google Scholar
36M. Carbonaro, A. Nucara, Amino Acids 2010, 38, 679.
10.1007/s00726-009-0274-3
CAS PubMed Web of Science® Google Scholar
37S. D. He, J. Shi, E. Walid, H. W. Zhang, Y. Ma, S. J. Xue, Food Chem. 2015, 166, 93.
10.1016/j.foodchem.2014.05.156
CAS PubMed Web of Science® Google Scholar
38Z. K. Wei, Z. M. Liu, X. W. Fu, Y. C. Wang, A. Q. Yuan, J. X. Lei, Eur. Polym. J. 2021, 157, 110647.
10.1016/j.eurpolymj.2021.110647
CAS Web of Science® Google Scholar
39A. Waisarikit, S. Ross, G. M. Ross, S. Mahasaranon, Polym.-Plast. Tech. Mat 2023, 62, 1684.
10.1080/25740881.2023.2228884
CAS Google Scholar
40J. Li, Y. X. Wang, J. Lin, Y. Liu, G. L. Wang, D. Quan, Y. J. Guan, G. Q. Zhao, S. C. Ji, J. Clean Prod. 2023, 425, 138952.
10.1016/j.jclepro.2023.138952
CAS Google Scholar
41Z. Y. Wei, S. N. Shao, M. L. Sui, P. Song, M. M. He, Q. Hu, X. F. Leng, Y. S. Wang, Y. Li, Eur. Polym. J. 2019, 118, 337.
10.1016/j.eurpolymj.2019.05.064
CAS Google Scholar
42K. Shi, G. S. Liu, H. Sun, B. Yang, Y. X. Weng, Polym.-Basel 2022, 14, 4305.
10.3390/polym14204305
CAS PubMed Web of Science® Google Scholar
43S. P. Qian, H. H. Zhang, W. C. Yao, K. C. Sheng, Comp. Part B-Eng. 2018, 133, 203.
10.1016/j.compositesb.2017.09.040
CAS Web of Science® Google Scholar
44H. H. Zhang, S. J. Wang, S. Y. Zhang, R. X. Ma, Y. M. Wang, W. Cao, C. T. Liu, C. Y. Shen, Polym. Test. 2017, 64, 12.
10.1016/j.polymertesting.2017.09.034
CAS Web of Science® Google Scholar
45H. L. Mao, P. J. Pan, G. R. Shan, Y. Z. Bao, J. Phys. Chem. B 2015, 119, 6471.
10.1021/acs.jpcb.5b03610
CAS PubMed Web of Science® Google Scholar
46C. C. Chen, J. Y. Chueh, H. Tseng, H. M. Huang, S. Y. Lee, Biomaterials 2003, 24, 1167.
10.1016/S0142-9612(02)00466-0
CAS PubMed Web of Science® Google Scholar
47P. Gong, Y. X. Zhao, K. Li, H. F. Tian, C. M. Li, J. Polym. Environ. 2022, 30, 562.
10.1007/s10924-021-02223-1
CAS Web of Science® Google Scholar
48Y. Baimark, W. Rungseesantivanon, N. Prakymoramas, Mater. Today Commun. 2022, 33, 104539.
10.1016/j.mtcomm.2022.104539
CAS Web of Science® Google Scholar
49H. W. Pan, J. J. Kong, Y. J. Chen, H. L. Zhang, L. S. Dong, Int. J. Biol. Macromol. 2019, 122, 848.
10.1016/j.ijbiomac.2018.10.178
CAS PubMed Google Scholar
50H. Kang, D. S. Kim, Polym. Comp. 2023, 44, 7727.
10.1002/pc.27658
CAS Web of Science® Google Scholar
51R. O. Okpuwhara, B. O. Oboirien, E. R. Sadiku, Polym. Eng. Sci. 2022, 62, 1571.
10.1002/pen.25945
CAS Web of Science® Google Scholar
52Y. T. Shieh, G. L. Liu, J. Polym. Sci. Pol. Phys. 2007, 45, 1870.
10.1002/polb.21184
CAS Web of Science® Google Scholar
53D. V. Cong, T. Hoang, N. V. Giang, N. T. Ha, T. D. Lam, M. Sumita, Mat. Sci. Eng. C-Mater. 2012, 32, 558.
10.1016/j.msec.2011.12.012
CAS Web of Science® Google Scholar
54M. Q. Wei, Q. B. Li, T. Jiang, H. Q. Ding, X. H. Wu, Y. F. Zhang, X. F. Wang, Mater. Today Commun. 2023, 34, 105278.
10.1016/j.mtcomm.2022.105278
CAS Google Scholar
55D. F. Zou, X. Zheng, Y. P. Ye, D. Yan, H. Xu, S. Si, X. G. Li, Int. J. Biol. Macromol. 2022, 216, 456.
10.1016/j.ijbiomac.2022.06.209
CAS PubMed Web of Science® Google Scholar
56L. He, F. Song, D. F. Li, X. Zhao, X. L. Wang, Y. Z. Wang, ACS Sustain. Chem. Eng. 2020, 8, 1573.
10.1021/acssuschemeng.9b06308
CAS Web of Science® Google Scholar
57H. B. Li, M. A. Huneault, Polymer 2007, 48, 6855.
10.1016/j.polymer.2007.09.020
CAS Web of Science® Google Scholar
58Y. M. Ma, Y. Jilili, T. F. Shao, W. J. Zhen, Int. J. Biol. Macromol. 2024, 254, 127676.
10.1016/j.ijbiomac.2023.127676
CAS PubMed Google Scholar
59S. S. Wang, L. Zhang, K. Semple, M. Zhang, W. B. Zhang, C. P. Dai, Polym.-Basel 2020, 12, 2217.
10.3390/polym12102217
CAS PubMed Google Scholar
60A. N. M. M. Rahman, X. P. Zhang, X. H. Qin, M. M. A. Sayeed, S. R. Islam, Polym. Comp. 2023, 44, 8819.
10.1002/pc.27740
CAS Google Scholar
61Z. F. Cheng, L. L. Lei, B. B. Zhao, Y. F. Zhu, T. Yu, W. D. Yang, Y. Li, Compos. Sci. Technol. 2023, 240, 110091.
10.1016/j.compscitech.2023.110091
CAS Google Scholar
62A. Marra, C. Silvestre, D. Duraccio, S. Cimmino, Int. J. Biol. Macromol. 2016, 88, 254.
10.1016/j.ijbiomac.2016.03.039
CAS PubMed Web of Science® Google Scholar
63X. Dai, Y. Cao, X. W. Shi, X. L. Wang, RSC Adv. 2016, 6, 71461.
10.1039/C6RA14190K
CAS Web of Science® Google Scholar
64A. Biswas, H. N. Cheng, G. Kuzniar, Z. Q. He, S. Kim, R. F. Furtado, C. R. Alves, B. K. Sharma, Polym.-Basel 2023, 15, 1425.
10.3390/polym15061425
CAS PubMed Google Scholar
65X. G. Li, Q. Yang, K. Zhang, L. S. Pan, Y. H. Feng, Y. F. Jia, N. Xu, J. Clean Prod. 2022, 375, 134097.
10.1016/j.jclepro.2022.134097
CAS Google Scholar
66A. González, C. I. A. Igarzabal, Food Hydrocoll. 2013, 33, 289.
10.1016/j.foodhyd.2013.03.010
CAS Web of Science® Google Scholar
67A. Todorovic, Y. Blössl, G. Oreski, K. Resch-Fauster, Comp. Part A-Appl. S 2022, 152, 106666.
10.1016/j.compositesa.2021.106666
CAS Google Scholar
68K. Li, C. M. Clarkson, L. Wang, Y. Liu, M. Lamm, Z. Q. Pang, Y. B. Zhou, J. Qian, M. Tajvidi, D. J. Gardner, H. Tekinalp, L. B. Hu, T. Li, A. J. Ragauskas, J. P. Youngblood, S. Ozcan, ACS Nano 2021, 15, 3646.
10.1021/acsnano.0c07613
CAS PubMed Web of Science® Google Scholar
69Y. F. Zuo, K. Chen, P. Li, X. Y. He, W. H. Li, Y. Q. Wu, Int. J. Biol. Macromol. 2020, 157, 177.
10.1016/j.ijbiomac.2020.04.205
CAS PubMed Web of Science® Google Scholar
70M. He, B. N. Zhang, Y. Dou, G. Q. Yin, Y. D. Cui, J. Appl. Polym. Sci. 2017, 134, 44680.
10.1002/app.44680
Web of Science® Google Scholar
71P. H. Sun, S. H. Wang, Z. Huang, L. Zhang, F. H. Dong, X. Xu, H. Liu, Green Chem. 2022, 24, 7519.
10.1039/D2GC02372E
CAS Web of Science® Google Scholar
72S. Guo, Z. Zhou, S. L. Yu, Z. B. Chen, H. X. Xiang, M. F. Zhu, Int. J. Biol. Macromol. 2023, 226, 1579.
10.1016/j.ijbiomac.2022.11.270
CAS PubMed Web of Science® Google Scholar
73L. Aliotta, P. Cinelli, M. B. Coltelli, M. C. Righetti, M. Gazzano, A. Lazzeri, Eur. Polym. J. 2017, 93, 822.
10.1016/j.eurpolymj.2017.04.041
CAS Web of Science® Google Scholar
74Z. Z. Gu, Y. Xu, Q. Q. Lu, C. J. Han, R. J. Liu, Z. P. Zhou, T. F. Hao, Y. J. Nie, Phys. Chem. Chem. Phys. 2019, 21, 6443.
10.1039/C8CP07839D
CAS PubMed Web of Science® Google Scholar

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Volume225, Issue20

October 2024

2400191

Characterization and Properties of Polylactic Acid/Cottonseed Protein Bioplastics

Abstract

Conflict of Interest

Open Research

Data Availability Statement

Supporting Information

References

Citing Literature

References

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Characterization and Properties of Polylactic Acid/Cottonseed Protein Bioplastics

Abstract

Conflict of Interest

Open Research

Data Availability Statement

Supporting Information

References

Citing Literature

References

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