Controls on the physical and chemical architecture of the subsurface critical zone are somewhat controversial, with multiple hypotheses proposed to account for variations in the depth of weathering between sites, and with landscape position at a site. In the Piedmont region of the Mid-Atlantic US weathering of crystalline bedrock has been observed to extend tens of meters below the surface and groundwater in a'bow-tie’ shape – i.e. weathering extends to lower elevations below ridges than below channels. The chemical and physical structure of a hillslope transect in the Maryland Piedmont was explored with a 45 m borehole in the ridge, as well as shallow bedrock boreholes at the toe of the slope and valley. Chemical weathering fronts were characterized using elemental abundances and mineralogical analysis. The ridge borehole did not extend deeper than the chemically and physically weathered rock. Surface and borehole geophysics and density measurements were used to characterize the weathered rock and saprolite. Na and Ca results suggest that plagioclase feldspar weathering is similar between samples collected from 45 m under the ridge and 2.2 m under the valley bottom. A narrow Fe oxidation garnet weathering front co-insides with the transition from weathered bedrock to saprolite, suggesting that this reaction may generate initial saprolite porosity. Muscovite weathering co-occurs with complete depletion of plagioclase a few meters above the Fe oxidation front. These nested weathering fronts in the saprolite appear to follow a subdued version of the surface topography. The location and shape of the nested saprolite weathering fronts may be controlled by the feedback between the transport of reactants and solutes and reaction-generated porosity, consistent with the conceptual “valve” hypothesis. Differing dominant control mechanisms on deep bedrock weathering and saprolite initiating reactions may explain the thickness and structure of the critical zone at our site.