Synthesis of Graft-Modified Polyolefin Compatibilizers for Compatibilizing Mixed Plastics
Yu Chen
Institute of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, Anhui, 230601 China
These authors contributed equally.
Search for more papers by this authorYuxin Ding
Institute of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, Anhui, 230601 China
These authors contributed equally.
Search for more papers by this authorPei Li
Institute of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, Anhui, 230601 China
Search for more papers by this authorWanlu Tian
Institute of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, Anhui, 230601 China
Search for more papers by this authorCorresponding Author
Yu Wang
CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui, 230026 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Fuzhou Wang
Institute of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, Anhui, 230601 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Chen Tan
Institute of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, Anhui, 230601 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorYu Chen
Institute of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, Anhui, 230601 China
These authors contributed equally.
Search for more papers by this authorYuxin Ding
Institute of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, Anhui, 230601 China
These authors contributed equally.
Search for more papers by this authorPei Li
Institute of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, Anhui, 230601 China
Search for more papers by this authorWanlu Tian
Institute of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, Anhui, 230601 China
Search for more papers by this authorCorresponding Author
Yu Wang
CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui, 230026 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Fuzhou Wang
Institute of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, Anhui, 230601 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Chen Tan
Institute of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, Anhui, 230601 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorComprehensive Summary
Recycling polyolefin and other plastic mixtures encounters significant obstacles due to the intricate nature and economic inefficiencies of physically separating vast streams of mixed waste. Incorporating compatibilizers emerges as a viable strategy to diminish interfacial energy and bolster compatibility, ultimately yielding homogeneous products. In this contribution, polar polyolefins featuring metal dynamic cross-linking networks were synthesized by tandem polymerizing ionic cluster type polar monomers and olefins. Subsequent treatment with HCl aqueous solution and esterification with polyester precursors yields high-performance grafted polar polyolefins for mixed polymer compatibilizing. For PP/PC melting blends, adding 5 wt% of graft-modified polyolefin results in tougher blends that surpass the performance of corresponding virgin iPP in elongation at break (εb). Polar polyolefins containing sodium carboxylate groups play a dual role in compatibilizing PET/HDPE blends, acting both as compatibilizers and nucleating agents. Moreover, this strategy enables the production of grafted polyolefins comprising ternary polymers, which can be employed in compatibilizing ternary blends.
Supporting Information
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Appendix S1: Supporting Information |
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