Volume 42, Issue 22 pp. 2751-2756
Concise Report

A General Electron Donor-Acceptor Photoactivation Using Oxime Esters Enabled Divergent Thioetherifications

Maojian Lu

Maojian Lu

College of Chemistry and Chemical Engineering, and Key (Guangdong-Hong Kong Joint) Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, Guangdong, 515063 China

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Liang-Liang Jiang

Liang-Liang Jiang

College of Chemistry and Chemical Engineering, and Key (Guangdong-Hong Kong Joint) Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, Guangdong, 515063 China

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Yue-Ming Xu

Yue-Ming Xu

College of Chemistry and Chemical Engineering, and Key (Guangdong-Hong Kong Joint) Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, Guangdong, 515063 China

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Sanliang Li

Sanliang Li

College of Chemistry and Chemical Engineering, and Key (Guangdong-Hong Kong Joint) Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, Guangdong, 515063 China

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Qing-Xiao Tong

Corresponding Author

Qing-Xiao Tong

College of Chemistry and Chemical Engineering, and Key (Guangdong-Hong Kong Joint) Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, Guangdong, 515063 China

E-mail: [email protected]; [email protected]Search for more papers by this author
Jian-Ji Zhong

Corresponding Author

Jian-Ji Zhong

College of Chemistry and Chemical Engineering, and Key (Guangdong-Hong Kong Joint) Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, Guangdong, 515063 China

Chemistry and Chemical Engineering Guangdong Laboratory, Shantou, Guangdong, 515063 China

E-mail: [email protected]; [email protected]Search for more papers by this author
First published: 12 July 2024
Citations: 10

Dedicated to the Special Issue of Emerging Investigators in 2024.

Abstract

Comprehensive Summary

The EDA complex-mediated reactions involving oxime esters have been few studied. Herein, an EDA complex formed by thiophenolate anion and oxime ester is reported for photoinduced divergent synthesis of thioethers, depending on different types of oxime esters. Operational simplicity, mild reaction conditions, and flexible options of leaving group demonstrate the generality and synthetic utility of this approach. Such an approach can also enable an interesting thiol-catalysis for the synthesis of phenanthridines.

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