Kinetic Modeling of the Palladium-Catalyzed Isomerizing Methoxycarbonylation of 1-Decene
Corresponding Author
Martin Gerlach
Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany
Correspondence: Martin Gerlach ([email protected]), Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany.Search for more papers by this authorSabine Kirschtowski
Max Planck Institute for Dynamics of Complex Technical Systems, Sandtorstraße 1, 39106 Magdeburg, Germany
Search for more papers by this authorAndreas Seidel-Morgenstern
Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany
Max Planck Institute for Dynamics of Complex Technical Systems, Sandtorstraße 1, 39106 Magdeburg, Germany
Search for more papers by this authorChristof Hamel
Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany
Anhalt University of Applied Sciences, Process Engineering, Bernburger Straße 55, 06354 Köthen, Germany
Search for more papers by this authorCorresponding Author
Martin Gerlach
Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany
Correspondence: Martin Gerlach ([email protected]), Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany.Search for more papers by this authorSabine Kirschtowski
Max Planck Institute for Dynamics of Complex Technical Systems, Sandtorstraße 1, 39106 Magdeburg, Germany
Search for more papers by this authorAndreas Seidel-Morgenstern
Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany
Max Planck Institute for Dynamics of Complex Technical Systems, Sandtorstraße 1, 39106 Magdeburg, Germany
Search for more papers by this authorChristof Hamel
Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany
Anhalt University of Applied Sciences, Process Engineering, Bernburger Straße 55, 06354 Köthen, Germany
Search for more papers by this authorAbstract
The experimental and model-based investigation of the palladium-catalyzed methoxycarbonylation of 1-decene using methanol and carbon monoxide is presented. The reaction was studied in a thermomorphic solvent system using the industrially applied ligand DTBPMB in order to describe the kinetics of the main and the most relevant side reactions. Based on a reaction analysis, kinetic models including main influencing variables were derived and successfully parametrized. Thus, inhibition effects of the substrate 1-decene as well as carbon monoxide on the isomerization and methoxycarbonylation rate could be identified.
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