Pesticides Adsorption by a Sustainable Porous Carbon: Modeling and River Water Decontamination
Juliana M. N. dos Santos
Research Group on Adsorptive and Catalytic Process Engineering (ENGEPAC), Federal University of Santa Maria, Av. Roraima, 1000-7, Santa Maria, Rio Grande do Sul, 97105-900 Brazil
Search for more papers by this authorFabíola B. Dalla Nora
Research Group on Adsorptive and Catalytic Process Engineering (ENGEPAC), Federal University of Santa Maria, Av. Roraima, 1000-7, Santa Maria, Rio Grande do Sul, 97105-900 Brazil
Search for more papers by this authorCristiano R. B. Rhoden
Laboratory of Nanostructured Magnetic Materials, LaMMaN, Franciscan University—UFN, Andradas, Santa Maria, Rio Grande do Sul, 97010-032 Brazil
Search for more papers by this authorFranciele da S. Bruckmann
Research Group on Adsorptive and Catalytic Process Engineering (ENGEPAC), Federal University of Santa Maria, Av. Roraima, 1000-7, Santa Maria, Rio Grande do Sul, 97105-900 Brazil
Search for more papers by this authorChristian Manera
Postgraduate Program in Engineering Processes and Technologies, University of Caxias do Sul (UCS), Francisco Getúlio Vargas, Caxias do Sul, Rio Grande do Sul, 95070-560 Brazil
Search for more papers by this authorMarcelo Godinho
Postgraduate Program in Engineering Processes and Technologies, University of Caxias do Sul (UCS), Francisco Getúlio Vargas, Caxias do Sul, Rio Grande do Sul, 95070-560 Brazil
Search for more papers by this authorMelissa G. A. Vieira
Chemical Engineering Department, State University of Campinas—UNICAMP, Zeferino Vaz University City—Barão Geraldo, Campinas, São Paulo, 13083-970 Brazil
Search for more papers by this authorLiliana P. Lozano
Universidad De La Costa, Calle 58 # 55-66, Barranquilla, Atlantico, 080002 Colombia
Search for more papers by this authorCorresponding Author
Luis F. O. Silva
Universidad De La Costa, Calle 58 # 55-66, Barranquilla, Atlantico, 080002 Colombia
E-mail: [email protected], [email protected]
Search for more papers by this authorSonaimuthu Mohandoss
School of Chemical Engineering, Yeungnam University, Daehak-Ro, Gyeongsan, 38541 Republic of Korea
Search for more papers by this authorNaushad Ahmad
Department of Chemistry, College of Science, King Saud University, King Abdullah Road Westward, Riyadh, 11451 Saudi Arabia
Search for more papers by this authorAna Carolina F. P. Fuhr
Research Group on Adsorptive and Catalytic Process Engineering (ENGEPAC), Federal University of Santa Maria, Av. Roraima, 1000-7, Santa Maria, Rio Grande do Sul, 97105-900 Brazil
Search for more papers by this authorCorresponding Author
Guilherme L. Dotto
Research Group on Adsorptive and Catalytic Process Engineering (ENGEPAC), Federal University of Santa Maria, Av. Roraima, 1000-7, Santa Maria, Rio Grande do Sul, 97105-900 Brazil
E-mail: [email protected], [email protected]
Search for more papers by this authorJuliana M. N. dos Santos
Research Group on Adsorptive and Catalytic Process Engineering (ENGEPAC), Federal University of Santa Maria, Av. Roraima, 1000-7, Santa Maria, Rio Grande do Sul, 97105-900 Brazil
Search for more papers by this authorFabíola B. Dalla Nora
Research Group on Adsorptive and Catalytic Process Engineering (ENGEPAC), Federal University of Santa Maria, Av. Roraima, 1000-7, Santa Maria, Rio Grande do Sul, 97105-900 Brazil
Search for more papers by this authorCristiano R. B. Rhoden
Laboratory of Nanostructured Magnetic Materials, LaMMaN, Franciscan University—UFN, Andradas, Santa Maria, Rio Grande do Sul, 97010-032 Brazil
Search for more papers by this authorFranciele da S. Bruckmann
Research Group on Adsorptive and Catalytic Process Engineering (ENGEPAC), Federal University of Santa Maria, Av. Roraima, 1000-7, Santa Maria, Rio Grande do Sul, 97105-900 Brazil
Search for more papers by this authorChristian Manera
Postgraduate Program in Engineering Processes and Technologies, University of Caxias do Sul (UCS), Francisco Getúlio Vargas, Caxias do Sul, Rio Grande do Sul, 95070-560 Brazil
Search for more papers by this authorMarcelo Godinho
Postgraduate Program in Engineering Processes and Technologies, University of Caxias do Sul (UCS), Francisco Getúlio Vargas, Caxias do Sul, Rio Grande do Sul, 95070-560 Brazil
Search for more papers by this authorMelissa G. A. Vieira
Chemical Engineering Department, State University of Campinas—UNICAMP, Zeferino Vaz University City—Barão Geraldo, Campinas, São Paulo, 13083-970 Brazil
Search for more papers by this authorLiliana P. Lozano
Universidad De La Costa, Calle 58 # 55-66, Barranquilla, Atlantico, 080002 Colombia
Search for more papers by this authorCorresponding Author
Luis F. O. Silva
Universidad De La Costa, Calle 58 # 55-66, Barranquilla, Atlantico, 080002 Colombia
E-mail: [email protected], [email protected]
Search for more papers by this authorSonaimuthu Mohandoss
School of Chemical Engineering, Yeungnam University, Daehak-Ro, Gyeongsan, 38541 Republic of Korea
Search for more papers by this authorNaushad Ahmad
Department of Chemistry, College of Science, King Saud University, King Abdullah Road Westward, Riyadh, 11451 Saudi Arabia
Search for more papers by this authorAna Carolina F. P. Fuhr
Research Group on Adsorptive and Catalytic Process Engineering (ENGEPAC), Federal University of Santa Maria, Av. Roraima, 1000-7, Santa Maria, Rio Grande do Sul, 97105-900 Brazil
Search for more papers by this authorCorresponding Author
Guilherme L. Dotto
Research Group on Adsorptive and Catalytic Process Engineering (ENGEPAC), Federal University of Santa Maria, Av. Roraima, 1000-7, Santa Maria, Rio Grande do Sul, 97105-900 Brazil
E-mail: [email protected], [email protected]
Search for more papers by this authorAbstract
A sustainable porous carbon (WSPC) was applied to remove atrazine and 2,4-d (2,4-dichlorophenoxyacetic acid) pesticides commonly used in cultivating grains and cereals. The 2,4-d and atrazine removals were favored at original pH values. The equilibrium occurred according to Brouers–Sotolongo's description. The thermodynamic studies supported the exothermic behavior. The adsorption data over time were represented by the pore-volume and surface diffusion model. Statistical mechanics revealed that the multilayer model showed the best fit for the adsorption isotherms. The steric parameters indicated that the adsorbed molecules are perpendicular to the WSPC surface. The number of adsorbed molecules decreased with increasing temperature for 2,4-d, whereas for atrazine, it remained constant. The adsorption energy indicates that the process is governed by physisorption. WSPC efficiently removed atrazine and 2,4-d from real river waters, reaching 98 % and 92 % removal percentages, respectively.
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References
- 1 Embrapa, “ Ministério da Agricultura aborda cenário de uso de agrotóxicos no Brasil na Reunião de Pesquisa de Soja,” 2019.
- 2C. P. C. Arias, Número, Tipo de Envases y Cantidad de Residuos Tóxicos de Plaguicidas Abandonados En Dos Agroecosistemas de Hortalizas, Unversidad Nacional De Trujillo, Trujillo 2010.
- 3Q. S. X. Lü, J. Integr. Agric. 2020, 19 (2), 590–599. DOI: https://doi.org/10.1016/S2095-3119(19)62864-9
- 4B. R. Sinambela, AGROTEK J. Ilm. Ilmu Pertan. 2024, 8 (2), 178–187. DOI: https://doi.org/10.33096/agrotek.v8i2.625
10.33096/agrotek.v8i2.625 Google Scholar
- 5 FAOSTAT, FAOSTAT—Compare Data, FAOSTAT, 2024. https://www.fao.org/faostat/en/#compare
- 6F. R. Campos, R. P. Romanini, M. E. N. Rodrigues, M. F. Moura, G. J. Vaz, Content From the Books of Embrapa's 500 Questions 500 Answers Collection (Coleção 500 Perguntas 500 Respostas) Treated to Be Used in Digital Solutions, 2022.
- 7S. Kumagai, Y. Noguchi, Y. Kurimoto, K. Takeda, Waste Manag 2007, 27 (4), 554–561. DOI: https://doi.org/10.1016/j.wasman.2006.04.006
- 8R. Pode, Renew Sustain. Energy Rev. 2016, 53, 1468–1485. DOI: https://doi.org/10.1016/j.rser.2015.09.051
- 9S. Steven, E. Restiawaty, Y. Bindar, Renew Sustain. Energy Rev. 2021, 149, 111329. DOI: https://doi.org/10.1016/j.rser.2021.111329
- 10Y. Zou, T. Yang, in Rice Bran Rice Bran Oil, Elsevier, Amsterdam 2019.
- 11U. Kalapathy, A. Proctor, J. Shultz, Bioresour. Technol. 2002, 85 (3), 285–289. DOI: https://doi.org/10.1016/S0960-8524(02)00116-5
- 12T.-H. Liou, S.-Y. Wang, Y.-T. Lin, S. Yang, Colloids Surfaces A Physicochem. Eng. Asp. 2022, 636, 128150. DOI: https://doi.org/10.1016/j.colsurfa.2021.128150
- 13A. Widyasanti, I. H. Utami, A. M. Kramadibrata, T. Herwanto, J. Appl. Agric. Sci. Technol. 2019, 3 (1), 15–28. DOI: https://doi.org/10.32530/jaast.v3i1.56
10.32530/jaast.v3i1.56 Google Scholar
- 14J. J. Romero-Hernandez, M. Paredes-Laverde, J. Silva-Agredo, D. F. Mercado, Y. Ávila-Torres, R. A. Torres-Palma, J. Clean. Prod. 2024, 434, 139935. DOI: https://doi.org/10.1016/j.jclepro.2023.139935
- 15V. Gargiulo, F. Di Natale, M. Alfe, J. Environ. Chem. Eng. 2024, 12 (5), 113497. DOI: https://doi.org/10.1016/j.jece.2024.113497
- 16X. You, R. Zhou, Y. Zhu, D. Bu, D. Cheng, J. Hazard. Mater. 2022, 430, 128445. DOI: https://doi.org/10.1016/j.jhazmat.2022.128445
- 17K. A. Phan, D. Phihusut, N. Tuntiwiwattanapun, J. Environ. Chem. Eng. 2022, 10 (3), 107575. DOI: https://doi.org/10.1016/j.jece.2022.107575
- 18R. Selvaraj, R. V. Iyer, G. Murugesan, L. C. Goveas, T. Varadavenkatesan, A. Samanth, R. Vinayagam, J. Water Process Eng. 2024, 66, 106027. DOI: https://doi.org/10.1016/j.jwpe.2024.106027
- 19A. Samanth, R. Selvaraj, G. Murugesan, T. Varadavenkatesan, R. Vinayagam, Chemosphere 2024, 361, 142513. DOI: https://doi.org/10.1016/j.chemosphere.2024.142513
- 20R. Vinayagam, V. Nagendran, L. C. Goveas, M. K. Narasimhan, T. Varadavenkatesan, A. Samanth, R. Selvaraj, Chemosphere 2024, 350, 141130. DOI: https://doi.org/10.1016/j.chemosphere.2024.141130
- 21J. O. Ighalo, A. G. Adeniyi, A. A. Adelodun, J. Ind. Eng. Chem. 2021, 93, 117–137. DOI: https://doi.org/10.1016/j.jiec.2020.10.011
- 22O. M. Yamashita, F. Zonta, R. A. F. Machado, Rev. Ciências Agro-Ambientais. 2008, 6, 39–45.
- 23G. Marchi, E. C. S. Marchi, T. G. Guimarães, in Doc. 227 2008. https://www.infoteca.cnptia.embrapa.br/bitstream/doc/571939/1/doc227.pdf
- 24E. A. A. M. R. Chidambaram, Ecol. Eng. 2016, 92, 97–105. DOI: https://doi.org/10.1016/j.ecoleng.2016.03.020
- 25K. Poonia, V. Hasija, P. Singh, A. A. Parwaz Khan, S. Thakur, V. K. Thakur, S. Mukherjee, T. Ahamad, S. M. Alshehri, P. Raizada, J. Clean. Prod. 2022, 367, 133087. DOI: https://doi.org/10.1016/j.jclepro.2022.133087
- 26M. Niksirat, R. Sadeghi, J. Esmaili, SN Appl. Sci. 2019, 1 (7), 782. DOI: https://doi.org/10.1007/s42452-019-0797-5
10.1007/s42452-019-0797-5 Google Scholar
- 27D. S. P. Franco, K. da Boit Martinello, J. Georgin, M. S. Netto, E. L. Foletto, L. F. O. Silva, G. S. dos Reis, G. L. Dotto, Chem. Eng. Res. Des. 2022, 182, 645–658. DOI: https://doi.org/10.1016/j.cherd.2022.04.037
- 28L. Sellaoui, G. L. Dotto, H. A. Pereira, Y. Vieira, G. S. dos Reis, M. L. S. Oliveira, L. F. O. Silva, M. R. Khan, S. Manoharadas, M. Godinho, L. A. Fantinel, C. Aguzzoli, R. K. S. Santos, Chem. Eng. J. 2023, 474, 145564. DOI: https://doi.org/10.1016/j.cej.2023.145564
- 29C. J. Geankoplis, Processos de Transporte y Operaciones Unitarias, 3rd ed., Compañía Editorial Continental 1998.
- 30S. James, E. E. Yaya, B. Singh Chandravanshi, F. Zewge, Bull. Chem. Soc. Ethiop. 2022, 37 (2), 251–263. DOI: https://doi.org/10.4314/bcse.v37i2.1
10.4314/bcse.v37i2.1 Google Scholar
- 31A. C. F. P. Fuhr, Y. Vieira, M. L. S. Oliveira, L. F. O. Silva, S. Manoharadas, A. Nawaz, G. L. Dotto, J. Mol. Liq. 2023, 390, 123107. DOI: https://doi.org/10.1016/j.molliq.2023.123107
- 32T.-H. Liou, S.-J. Wu, J. Hazard. Mater. 2009, 171 (1–3), 693–703. DOI: https://doi.org/10.1016/j.jhazmat.2009.06.056
- 33S. Azat, A. V. Korobeinyk, K. Moustakas, V. J. Inglezakis, J. Clean. Prod. 2019, 217, 352–359. DOI: https://doi.org/10.1016/j.jclepro.2019.01.142
- 34N. Bouchelkia, H. Tahraoui, K. Benazouz, A. Mameri, R. Boudraa, H. Moussa, N. Hamri, R. Merdoud, H. Belkacemi, A. Zoukel, A. Amrane, M. Kebir, L. Mouni, Chemom. Intell. Lab. Syst. 2025, 261, 105377. DOI: https://doi.org/10.1016/j.chemolab.2025.105377
- 35L. J. Kennedy, J. J. Vijaya, G. Sekaran, Ind. Eng. Chem. Res. 2004, 43 (8), 1832–1838. DOI: https://doi.org/10.1021/ie034093f
- 36M. Thommes, K. Kaneko, A. V. Neimark, J. P. Olivier, F. Rodriguez-Reinoso, J. Rouquerol, K. S. W. Sing, Pure Appl. Chem. 2015, 87 (9–10), 1051–1069. DOI: https://doi.org/10.1515/pac-2014-1117
- 37F. Rouquerol, J. Rouquerol, K. D. Sing, P. Llewellyn, G. Maurin, in Principles, Methodology and Applications, 2nd ed., Academic Press—Elsevier Ltd., Amsterdam 2014.
- 38Y. Chen, Y. Zhu, Z. Wang, Y. Li, L. Wang, L. Ding, X. Gao, Y. Ma, Y. Guo, Adv. Colloid Interface Sci. 2011, 163 (1), 39–52. DOI: https://doi.org/10.1016/j.cis.2011.01.006
- 39G. Palmisano, S. Al Jitan, C. Garlisi, in Heterogeneous Catalysis, Elsevier, Amsterdam 2022.
10.1016/B978-0-323-89845-4.00007-2 Google Scholar
- 40E. R. Raut, M. A. Bedmohata, A. R. Chaudhari, Mater. Today Proc 2022, 66, 1875–1884. DOI: https://doi.org/10.1016/j.matpr.2022.05.413
- 41H. Asadi, M. Ghorbani, M. Rezaei-Rashti, S. Abrishamkesh, E. Amirahmadi, C. Chengrong, M. Gorji, Rice Sci. 2021, 28 (4), 325–343. DOI: https://doi.org/10.1016/j.rsci.2021.05.004
- 42Z. Shamsollahi, A. Partovinia, J. Environ. Manage. 2019, 246, 314–323. DOI: https://doi.org/10.1016/j.jenvman.2019.05.145
- 43F. da Silva Bruckmann, C. M. Ledur, I. Zanella da Silva, G. L. Dotto, C. R. B. Rhoden, J. Mol. Liq. 2022, 353, 118837. DOI: https://doi.org/10.1016/j.molliq.2022.118837
10.1016/j.molliq.2022.118837 Google Scholar
- 44F. M. de Souza, O. A. A. dos Santos, M. G. A. Vieira, Environ. Sci. Pollut. Res. 2019, 26 (18), 18329–18342. DOI: https://doi.org/10.1007/s11356-019-05196-w
- 45F. K. Algethami, E. A. Abdelrahman, Y. G. Abou El-Reash, A. Shahat, Appl. Organomet. Chem. 2024, 38 (2). DOI: https://doi.org/10.1002/aoc.7334
- 46J. Goscianska, A. Olejnik, Adsorption 2019, 25 (3), 345–355. DOI: https://doi.org/10.1007/s10450-019-00015-7
- 47A. Mandal, N. Singh, T. J. Purakayastha, Sci. Total Environ. 2017, 577, 376–385. DOI: https://doi.org/10.1016/j.scitotenv.2016.10.204
- 48M. A. Al-Ghouti, D. A. Da'ana, J. Hazard. Mater. 2020, 393, 122383. DOI: https://doi.org/10.1016/j.jhazmat.2020.122383
- 49C. Buttersack, Colloids Surf A Physicochem. Eng. Asp. 2022, 650, 129489. DOI: https://doi.org/10.1016/j.colsurfa.2022.129489
- 50M. M. Majd, V. Kordzadeh-Kermani, V. Ghalandari, A. Askari, M. Sillanpää, Sci. Total Environ. 2022, 812, 151334. DOI: https://doi.org/10.1016/j.scitotenv.2021.151334
- 51T. Štimec, M. Hriberšek, J. Ravnik, S. Bašič, M. Zadravec, Anal. PAZU. 2022, 5 (1–2), 26–32. DOI: https://doi.org/10.18690/analipazu.5.1-2.26-32.2015
10.18690/analipazu.5.1-2.26-32.2015 Google Scholar
- 52D. Smith, C. H. Giles, T. H. MacEwant, S. N. Nakhwa, J. Chem. Soc. 1960, 14, 3973–3993. http://doi.org/10.1039/jr9600003973
- 53D. M. Ruthven, Principles of Adsorption and Adsorption Processes, 1st ed., John Wiley & Sons, Ltd 1984.
- 54P. R. Souza, G. L. Dotto, N. P. G. Salau, Chem. Eng. Res. Des. 2017, 122, 298–307. DOI: https://doi.org/10.1016/j.cherd.2017.04.021
- 55M. T. Q. S. Da Silva, W. Mazer, Contrib. A Las Ciencias Soc. 2023, 16 (9), 18281–18302. DOI: https://doi.org/10.55905/revconv.16n.9-264
10.55905/revconv.16n.9?264 Google Scholar
- 56A. Yazidi, L. Sellaoui, G. L. Dotto, A. Bonilla-Petriciolet, A. C. Fröhlich, A. B. Lamine, J. Mol. Liq. 2019, 283, 276–286. DOI: https://doi.org/10.1016/j.molliq.2019.03.101
- 57O. Amrhar, L. El Gana, M. Mobarak, Environ. Chem. Lett. 2021, 19 (6), 4519–4547. DOI: https://doi.org/10.1007/s10311-021-01279-8
- 58A. Samanth, R. Vinayagam, G. Murugesan, T. Varadavenkatesan, R. Selvaraj, A. Pugazhendhi, Chemosphere 2023, 336, 139143. DOI: https://doi.org/10.1016/j.chemosphere.2023.139143
- 59F. Dhaouadi, L. Sellaoui, S. Taamalli, F. Louis, A. El Bakali, M. Badawi, J. Georgin, D. S. P. Franco, L. F. O. Silva, A. Bonilla-Petriciolet, S. Rtimi, Chem. Eng. J. 2022, 445, 136773. DOI: https://doi.org/10.1016/j.cej.2022.136773
- 60K. Sen, N. K. Mondal, J. Ind. Eng. Chem. 2024, 136, 150–166. DOI: https://doi.org/10.1016/j.jiec.2024.02.003
- 61M. Atrous, L. Sellaoui, M. Bouzid, E. C. Lima, P. S. Thue, A. Bonilla-Petriciolet, A. B. Lamine, J. Mol. Liq. 2019, 294, 111610. DOI: https://doi.org/10.1016/j.molliq.2019.111610
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