Fluid-Solid Adsorption in Batch and Continuous Processing: A Review and Insights into Modeling
Vincenzo Russo
University of Naples “Federico II”, Chemical Sciences Department, Via Cintia, 4, 80126 Naples, Italy
Search for more papers by this authorMarco Trifuoggi
University of Naples “Federico II”, Chemical Sciences Department, Via Cintia, 4, 80126 Naples, Italy
Search for more papers by this authorMartino Di Serio
University of Naples “Federico II”, Chemical Sciences Department, Via Cintia, 4, 80126 Naples, Italy
Search for more papers by this authorCorresponding Author
Riccardo Tesser
University of Naples “Federico II”, Chemical Sciences Department, Via Cintia, 4, 80126 Naples, Italy
Correspondence: Riccardo Tesser ([email protected]), University of Naples “Federico II”, Chemical Sciences Department, Via Cintia, 4, 80126 Naples, Italy.Search for more papers by this authorVincenzo Russo
University of Naples “Federico II”, Chemical Sciences Department, Via Cintia, 4, 80126 Naples, Italy
Search for more papers by this authorMarco Trifuoggi
University of Naples “Federico II”, Chemical Sciences Department, Via Cintia, 4, 80126 Naples, Italy
Search for more papers by this authorMartino Di Serio
University of Naples “Federico II”, Chemical Sciences Department, Via Cintia, 4, 80126 Naples, Italy
Search for more papers by this authorCorresponding Author
Riccardo Tesser
University of Naples “Federico II”, Chemical Sciences Department, Via Cintia, 4, 80126 Naples, Italy
Correspondence: Riccardo Tesser ([email protected]), University of Naples “Federico II”, Chemical Sciences Department, Via Cintia, 4, 80126 Naples, Italy.Search for more papers by this authorAbstract
Adsorption is a highly versatile separation technique that can be used both for product separation and waste purification, involving selective interaction of one or more compounds from the liquid phase on a solid called adsorbent. In literature, several models have been proposed to describe both the kinetics and the equilibrium data of different systems. These models are relevant for fluid-solid adsorption and fluid-solid reactions. Kinetic models can be classified in either pseudo-kinetic or diffusive models. Most of them cannot be applied directly in simulating the behavior of continuous columns, while others are applicable only in a narrow range of experimental conditions. The performances of a general continuous adsorption model have been tested by performing a dedicated parametric investigation with the aim to give an overview of how the parameters affect the continuous operation.
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