Transforming Pharmaceutical Synthesis with Sein-E-B Nanocomposite Photocatalyst through 1,4-NAD(P)H Cofactor Regeneration and C-N Bond Activation
Ravindra K. Shukla
Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P., 273010 India
Search for more papers by this authorCorresponding Author
Rajesh K. Yadav
Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P., 273010 India
Search for more papers by this authorVitthal L. Gole
Department of Chemical Engineering, Madan Mohan Malaviya University of Technology, Gorakhpur, 273010 U.P., India
Search for more papers by this authorRajat Singhal
Centre for Sustainable Technologies, Indian Institute of Science, Gulmohar Marg, Mathikere, Bengaluru, 560012 India
Search for more papers by this authorRehana Shahin
Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P., 273010 India
Search for more papers by this authorShaifali Mishra
Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P., 273010 India
Search for more papers by this authorSatyam Singh
Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P., 273010 India
Search for more papers by this authorKanchan Sharma
Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P., 273010 India
Search for more papers by this authorCorresponding Author
Jin-Ook Baeg
Artificial Photosynthesis Research group, Korea Research Institute of Chemical Technology, Yuseong-gu, Daejeon, 34114 Republic of Korea
Search for more papers by this authorGamal A. El-Hiti
Department of Optometry, College of Applied, Medical Sciences, King Saud University, Riyadh, 11433 Saudi Arabia
Search for more papers by this authorKrishna Kumar Yadav
Faculty of Science and Technology, Madhyanchal Professional University, Ratibad, Bhopal, 462044 India
Environmental and Atmospheric Sciences Research Group, Scientific Research Center, Al-Ayen University, Thi-Qar, Nasiriyah, 64001 Iraq
Search for more papers by this authorCorresponding Author
Navneet Kumar Gupta
Centre for Sustainable Technologies, Indian Institute of Science, Gulmohar Marg, Mathikere, Bengaluru, 560012 India
Search for more papers by this authorRavindra K. Shukla
Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P., 273010 India
Search for more papers by this authorCorresponding Author
Rajesh K. Yadav
Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P., 273010 India
Search for more papers by this authorVitthal L. Gole
Department of Chemical Engineering, Madan Mohan Malaviya University of Technology, Gorakhpur, 273010 U.P., India
Search for more papers by this authorRajat Singhal
Centre for Sustainable Technologies, Indian Institute of Science, Gulmohar Marg, Mathikere, Bengaluru, 560012 India
Search for more papers by this authorRehana Shahin
Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P., 273010 India
Search for more papers by this authorShaifali Mishra
Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P., 273010 India
Search for more papers by this authorSatyam Singh
Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P., 273010 India
Search for more papers by this authorKanchan Sharma
Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P., 273010 India
Search for more papers by this authorCorresponding Author
Jin-Ook Baeg
Artificial Photosynthesis Research group, Korea Research Institute of Chemical Technology, Yuseong-gu, Daejeon, 34114 Republic of Korea
Search for more papers by this authorGamal A. El-Hiti
Department of Optometry, College of Applied, Medical Sciences, King Saud University, Riyadh, 11433 Saudi Arabia
Search for more papers by this authorKrishna Kumar Yadav
Faculty of Science and Technology, Madhyanchal Professional University, Ratibad, Bhopal, 462044 India
Environmental and Atmospheric Sciences Research Group, Scientific Research Center, Al-Ayen University, Thi-Qar, Nasiriyah, 64001 Iraq
Search for more papers by this authorCorresponding Author
Navneet Kumar Gupta
Centre for Sustainable Technologies, Indian Institute of Science, Gulmohar Marg, Mathikere, Bengaluru, 560012 India
Search for more papers by this authorAbstract
The need for sunlight chemical renewal and contemporary organic transformation has fostered the advancement of environmentally friendly photocatalytic techniques. For the first time, we report on the novel crafting of a bright future with selenium-infused Eosin-B (Sein-E-B) nanocomposite photocatalysts in this work. The Sein-E-B nanocomposite materials were created using a hydrothermal process for solar chemical regeneration and organic transformation under visible light. The synthesized samples were subjected to UV-DRS-visible spectroscopy, FT-IR, SEM, EDX, EIS and XRD analysis. The energy band gap of the Sein-E-B nanocomposite photocatalyst was measured using UV-DRS, and the result was around 2.06 eV. to investigate the generated Sein-E-B catalytic activity as a nanocomposite for 1,4-NADH/NADPH re-formation and C−N bond activation. This novel photocatalyst offers a promising alternative for the regeneration of solar chemicals and C−N bond creation between pyrrole and aryl halides.
Graphical Abstract
Conflict of interests
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
Filename | Description |
---|---|
cbdv202400329-sup-0001-misc_information.pdf219.9 KB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1M. Chakraborty, A. K. Panda, Spectrochim. Acta - A: Mol. Biomol. Spectrosc. 2011, 81, 458–465.
- 2S. J. He, X. Y. Du, Q. Wang, J. Xu, Adv. Mater. Res. 2013, 827, 3–7.
10.4028/www.scientific.net/AMR.827.3 Google Scholar
- 3H. Rahman, Int. J. Pharm. Pharm. Sci. 2017, 9, 1.
10.22159/ijpps.2017v9i12.21220 Google Scholar
- 4P. Singh, S. Chaubey, C. Singh, S. Singh, R. K. Yadav, A. P. Singh, P. D. Subhash, D. Tiwari, React. Chem. Eng. 2023, 8, 1072–1082.
- 5H. K. Singh, A. Kamal, S. Kumari, D. Kumar, S. K. Maury, V. Srivastava, S. Singh, ACS Omega 2020, 5 (46), 29854–29863.
- 6S Soni, P. Pali, M. A. Ansari, M. S. Singh, J. Org. Chem. 2020, 85 (15), 10098–10109.
- 7S. Rossi, F. Herbrik, S. Resta, A. Puglisi, Molecules 2022, 27, 5096.
- 8P. Fita, M. Fedoseeva, E. Vauthey, J. Phys. Chem. A 2011, 115 (12), 2465–2470.
- 9V. Pascanu, G. G. Miera, A. K. Inge, B. M. Matute, J. Am. Chem. Soc. 2019, 141 (18), 7223–7234.
- 10S. Jana, M. Uchman, Prog. Polym. Sci. 2020, 106, 101252.
- 11J. B. Fankam, G. W. Ejuh, F. T. Nya, J. M. B. Ndjaka, Opt. Quantum Electron. 2020, 52, 292.
- 12J. A. Khan, M. Sayed, N. S. Shah, S. Khan, Y. Zhang, G. Boczkaj, H. M. Khan, D. D. Dionysiou, Appl. Catal. B 2020, 265, 118557.
- 13S. C. Yan, Z. S. Li, Z. G. Zou, Langmuir 2010, 26, 3894–3901.
- 14J. Li, B. Shen, Z. Hong, B. Lin, B. Gao, Y. A. Chen, Chem. Commun. 2012, 48, 12017–12019.
- 15G. Dong, K. Zhao, L. Zhang, Chem. Commun. 2012, 48, 6178–6180.
- 16Z. Lin, X. Wang, Angew. Chem. Int. Ed. 2013, 52, 1735–1738.
- 17J. A. Johnson, M.-L. Saboungi, P. Thiyagarajan, R. Csencsits, D. Meisel, J. Phys. Chem. B 1999, 103, 59–63.
- 18M. P. Kalamuei, M. M. Kamazani, M. S. Niasari, S. H. Mashkani, Ultrason. Sonochem. 2015, 23, 246–256.
- 19S. Cao, J. J. Yu, Phys. Chem. Lett. 2014, 5, 2101–2107.
- 20S. Cao, J. Low, J. Yu, M. Jaroniec, Adv. Mater. 2015, 27, 2150–2176.
- 21J. Wen, J. Xie, X. Chen, X. Li, Appl. Surf. Sci. 2017, 391, 72–123.
- 22E. Y. Tsui, K. H. Hartstein, D. R. Gamelin, J. Am. Chem. Soc. 2016, 138, 11105–11108.
- 23H. J. Reich, R. Hondal, ACS Chem. Biol. 2016, 11, 821–841.
- 24E. M. Rockafellow, J. M. Haywood, T. Witte, R. S. Houk, W. S. Jenks, Langmuir 2010, 26, 19052–19059.
- 25S. Singh, R. K. Yadav, T. W. Kim, C. Singh, P. Singh, S. Chaubey, A. P. Singh, J.-O. Baeg, S. K. Gupta, D. Tiwary, ACS Energy Fuels 2022, 36 (15), 8402–8412.
- 26M. Zhu, C. Zhai, L. Qiu, C. Lu, A. S. Paton, Y Du, M. C. Goh, ACS Sustainable Chem. Eng. 2015, 3 (12), 3123–3129.
- 27A. Kumar, R. K. Yadav, N.-J. Park, J.-O. Baeg, ACS Appl. Nano Mater. 2018, 1 (1), 47–54.
- 28E. J. Bastian, R. B. Martin, J. Phys. Chem. 1973, 77, 1129–1133.
- 29H. Q. Jiang, H. Endo, H. Natori, M. Nagai, K. Kobayashi, J. Eur. Ceram. Soc. 2008, 28, 2955–2962.
- 30C. A. Wang, Z. K. Zhang, T. Yue, Y. L. Sun, L. Wang, W. D. Wang, Y. Zhang, C. Liu, W. Wang, Chem. A Eur. J. 2012, 18, 6718–6723.
- 31C. A. Wang, Y. F. Han, Y. W. Li, K. Nie, X. L. Cheng, J. P. Zhang, RSC Adv. 2016, 6, 34866–34871.
- 32C. A. Wang, Y. W. Li, X. M. Hou, Y. F. Han, K. Nie, J. P. Zhang, ChemistrySelect 2016, 1, 1371–1376.
- 33S. G. Bolton, M. D. Pluth, Chem. Sci. 2020, 11, 11777–11784.
- 34B. Wang, J. Zhang, Z. Xia, M. Fan, C. Lv, G. Tian, X. Li, Nano Res. 2018, 11, 2460–2469.
- 35P. Bhatia, S. Pandey, R. Prakash, T. P. Nagaraja, J. Biol. Act. Prod. Nat. 2014, 4, 354–364.
- 36G. Huang, Y Lin, L. Zhang, Z. Yan, Y. Wang, Y. Liu, Nature 2019, 9, 19651.
- 37N. Bisht, P. Phalswal, P. K. Khanna, Mater. Adv. 2022, 3, 1415–1431.
- 38R. K. Yadav, J.-O. Baeg, A. Kumar, K-j. Kong, G. H. Oha, N.-J. Park, J. Mater. Chem. 2014, 2, 5068–5076.
- 39Y. Han, G. Wu, H. Li, M. Wang, H. Chen, Nanotechnology 2010, 21, 185708.
- 40T. Yoshida, K. Terada, D. Schlettwein, T. Oekermann, T. Sugiura, H. Minoura, Adv. Mater. 2000, 12, 1214.
- 41C. B. Park, S. H. Lee, S. Kale, S. M. Lee, J. O. Baeg, Chem. Commun. 2008, 42, 5423–5425.
- 42R. K. Yadav, A. Kumar, N.-J. Park, D. Yadav, J. Y. Kim, J.-O. Baeg, Sustain. Energy Fuels 2019, 3, 3324–3328.
- 43H. Stambulyana, T. G. Minehan, Org. Biomol. Chem. 2016, 14, 8728–8731.
- 44S. H. Barange, P. R. Bhagat, ChemistrySelect 2022, 7, e202201177.
- 45M. S. Oderinde, N. H. Jones, A. Juneau, M. Frenette, B. Aquila, S. Tentarelli, D. W. Robbins, J. W. Johannes, Angew. Chem. Int. Ed. 2016, 55, 1–6.
10.1002/anie.201510990 Google Scholar
- 46S. U. Raut, S. A. Deshmukh, S. H. Barange, P. R. Bhagat, Catal. Today 2023, 408, 81–91.
- 47A. Wimmer, B. König, Beilstein J. Org. Chem. 2018, 14, 54–83.
- 48M. N. Lavagnino, T. Liang, D. W. C. MacMillan, Proc. Natl. Acad. Sci. USA 2020, 117 (35), 21058–21064.
- 49J. Barber, B. Andersson, Nature 1994, 370, 31–34.
- 50S. Chaubey, R. K. Yadav, S. K. Tripathi, B. C. Yadav, S. N. Singh, T. W. Kim, Photochem. Photobiol. 2022, 98, 150–159.
- 51R. K. Yadav, J. O. Baeg, G. H. Oh, N. J. Park, K. J. Kong, J. Kim, D. W. Hwang, S. K. Biswas, J. Am. Chem. Soc. 2012, 134, 11455–11461.