Volume 142, Issue 23 e56990
RESEARCH ARTICLE

Enhance the Durable Antistatic Properties of Aqueous Dispersion XNBR Films of Light Color With Grafting Hydrophilic Sodium Polyacrylate

Xin Shan

Xin Shan

Key Laboratory of Specially Functional Polymeric Materials and Related Technology (Ministry of Education), School of Chemical Engineering, East China University of Science and Technology, Shanghai, China

Contribution: Data curation (lead), ​Investigation (lead), Methodology (lead), Writing - original draft (lead)

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Luo Luo

Luo Luo

Key Laboratory of Specially Functional Polymeric Materials and Related Technology (Ministry of Education), School of Chemical Engineering, East China University of Science and Technology, Shanghai, China

Contribution: Formal analysis (equal), Supervision (equal), Writing - review & editing (equal)

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Qunfang Lin

Qunfang Lin

School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, China

Contribution: Supervision (equal)

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Yang Yang

Yang Yang

Shandong Haoyue New Material Co. LTD, Shanghai, China

Contribution: Supervision (equal)

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Meiqin Yao

Meiqin Yao

Shandong Haoyue New Material Co. LTD, Shanghai, China

Contribution: Supervision (supporting)

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Huihang Ma

Corresponding Author

Huihang Ma

Key Laboratory of Specially Functional Polymeric Materials and Related Technology (Ministry of Education), School of Chemical Engineering, East China University of Science and Technology, Shanghai, China

Correspondence:

Huihang Ma ([email protected])

Xiaodong Zhou ([email protected])

Contribution: Supervision (lead), Writing - review & editing (lead)

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Xiaodong Zhou

Corresponding Author

Xiaodong Zhou

Key Laboratory of Specially Functional Polymeric Materials and Related Technology (Ministry of Education), School of Chemical Engineering, East China University of Science and Technology, Shanghai, China

Correspondence:

Huihang Ma ([email protected])

Xiaodong Zhou ([email protected])

Contribution: Conceptualization (lead), Funding acquisition (lead), Project administration (lead), Resources (lead), Supervision (lead)

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First published: 24 March 2025

Funding: This work was supported by Fundamental Research Funds for the Central Universities (no. JKD01241701).

X. Zhou and H. Ma contributed equally to this paper as co-corresponding authors.

ABSTRACT

A hydrophilic polyelectrolyte ion channel grafted polymer film based on carboxyl nitrile butadiene rubber latex (XNBRL) was prepared to enhance electrical conductivity and durability. In this research, XNBR was grafted with sodium acrylate (PAAS-g-XNBR), and cetyltrimethylammonium bromide (CTAB) was used to adsorb the monomer around the XNBR particles to form a new negative charge layer. The prepared PAAS-g-XNBR membrane section formed a continuous polyelectrolyte distribution, which prevented the formation of pores. Because the polyelectrolyte is strongly bound to the substrate by grafting chemical bonds, the ionic antistatic properties of the prepared film are durable and washable. Furthermore, the mechanical properties and antistatic properties of the film are balanced by the appropriate monomer content, and the appropriate vulcanization temperature also controls the appropriate moisture and crosslinking degree of the film. The results show that at 50% humidity, the optimal latex film achieves excellent conductive and antistatic properties (107 Ω) and good tensile strength (4.19 MPa), which present good application prospects in the field of thick protective touchscreen gloves with adjustable color.

Conflicts of Interest

The authors declare no conflicts of interest.

Data Availability Statement

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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