Rheological and mechanical properties, heat resistance and hydrolytic degradation of poly(butylene succinate-co-adipate)/stereocomplex polylactide blends
Chengkai Liu
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, 266510 China
Contribution: Conceptualization (lead), Investigation (lead), Methodology (lead), Writing - original draft (lead)
Search for more papers by this authorZhengyi Han
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Laboratory of Advanced Materials, Fudan University, Shanghai, 200438 China
Contribution: Investigation (supporting), Methodology (supporting)
Search for more papers by this authorXiangyu Yan
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Contribution: Investigation (supporting), Methodology (supporting)
Search for more papers by this authorJinshuo Yu
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Contribution: Formal analysis (supporting), Methodology (supporting)
Search for more papers by this authorQiao Zhang
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Contribution: Investigation (supporting)
Search for more papers by this authorDongmei Wang
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, 266510 China
Contribution: Writing - review & editing (supporting)
Search for more papers by this authorCorresponding Author
Yan Zhao
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Correspondence
Yan Zhao, Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.
Email: [email protected]
Contribution: Conceptualization (supporting), Investigation (supporting), Methodology (supporting), Resources (lead), Writing - review & editing (lead)
Search for more papers by this authorHuiliang Zhang
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Contribution: Resources (supporting), Writing - review & editing (supporting)
Search for more papers by this authorChengkai Liu
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, 266510 China
Contribution: Conceptualization (lead), Investigation (lead), Methodology (lead), Writing - original draft (lead)
Search for more papers by this authorZhengyi Han
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Laboratory of Advanced Materials, Fudan University, Shanghai, 200438 China
Contribution: Investigation (supporting), Methodology (supporting)
Search for more papers by this authorXiangyu Yan
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Contribution: Investigation (supporting), Methodology (supporting)
Search for more papers by this authorJinshuo Yu
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Contribution: Formal analysis (supporting), Methodology (supporting)
Search for more papers by this authorQiao Zhang
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Contribution: Investigation (supporting)
Search for more papers by this authorDongmei Wang
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, 266510 China
Contribution: Writing - review & editing (supporting)
Search for more papers by this authorCorresponding Author
Yan Zhao
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Correspondence
Yan Zhao, Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.
Email: [email protected]
Contribution: Conceptualization (supporting), Investigation (supporting), Methodology (supporting), Resources (lead), Writing - review & editing (lead)
Search for more papers by this authorHuiliang Zhang
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Contribution: Resources (supporting), Writing - review & editing (supporting)
Search for more papers by this authorAbstract
In this study, equimolar amounts of poly(l-lactic acid) (PLLA) and poly(d-lactide acid) (PDLA) were melt-blended with PBSA, to obtain a novel and environmentally friendly PBSA/sc-PLA blend, through in situ formation of stereo-complex poly(lactic acid) (sc-PLA). Differential scanning calorimetry and wide-angle X-ray diffractometry confirmed the formation of sc-PLA in PBSA matrix. The sc-PLA was uniformly dispersed in PBSA matrix. Up to 20 wt% sc-PLA concentration, the PBSA/sc-PLA blends showed solid-like flow behavior in the low-frequency region. Moreover, sc-PLA could reinforce the PBSA matrix. The Young's modulus, yield strength, and storage modulus of PBSA/sc-PLA blend increased with increase in sc-PLA content. In addition, the heat deflection temperatures of PBSA/sc-PLA blends increased on incorporation of sc-PLA, thus enhancing the heat resistance. Compared with neat PBSA, the hydrolytic degradation of PBSA/sc-PLA blends was improved. This work provides an effective strategy to obtain high performance PBSA materials and expand the application scope of PBSA.
CONFLICT OF INTEREST STATEMENT
The authors declare no conflict of interest.
Open Research
DATA AVAILABILITY STATEMENT
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
| Filename | Description |
|---|---|
| app53884-sup-0001-Supinfo.docxWord 2007 document , 1.2 MB | DATA S1: Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
REFERENCES
- 1A. L. Brooks, S. Wang, J. R. Jambeck, Sci. Adv. 2018, 4, 1.
- 2R. Geyer, J. R. Jambeck, K. L. Law, Sci. Adv. 2017, 3, 1.
- 3L. Yu, K. Dean, L. Li, Prog. Polym. Sci. 2006, 31, 576.
- 4G. Scott, Polym. Degrad. Stabil. 2000, 68, 1.
- 5A. Mohanty, M. Misra, G. Hinrchsen, Macromol. Mater. Eng. 2000, 276, 1.
- 6R. A. Cross, B. Kalra, Science 2002, 297, 803.
- 7I. Tadahisa, Angew. Chem. Int. Edit. 2015, 54, 3210.
- 8R. A. Pérez-Camargo, B. Fernández-d'Arlas, D. Cavallo, T. Debuissy, E. Pollet, L. Avérous, A. J. Müller, Macromolecules 2017, 50, 597.
- 9M. S. Nikolic, J. Djonlagic, Polym. Degrad. Stabil. 2001, 74, 263.
- 10V. Tserki, P. Matzinos, E. Pavlidou, D. Vachliotis, C. Panayiotou, Polym. Degrad. Stabil. 2006, 91, 367.
- 11S. Coiai, M. L. Di Lorenzo, P. Cinelli, M. C. Righetti, E. Passaglia, Polymer 2021, 13, 2489.
- 12Z. G. Qi, H. M. Ye, J. Xu, J. N. Chen, B. H. Guo, Colloids Surf. A 2013, 421, 109.
- 13S. Y. Zhu, Y. Y. Zhao, Z. B. Qiu, J. Appl. Polym. Sci. 2012, 124, 4268.
- 14T. Malwela, S. S. Ray, Polymer 2011, 52, 1297.
- 15J. A. Simao, C. F. Bellani, M. C. Branciforti, J. Appl. Polym. Sci. 2017, 134, 44493.
- 16C. S. Wu, Polym. Bull. 2018, 75, 5197.
- 17Z. B. Qiu, C. Z. Yan, J. M. Lu, W. T. Yang, Macromolecules 2007, 40, 5047.
- 18F. Yang, Z. B. Qiu, W. T. Yang, Polymer 2009, 50, 2328.
- 19T. Dadouche, M. Yousfi, C. Samuel, M. F. Lacrampe, J. Soulestin, Polym. Eng. Sci. 2021, 61, 1324.
- 20F. Yang, Z. B. Qiu, Thermochim. Acta 2011, 523, 200.
- 21G. Jiang, H. T. Wang, L. Yu, H. L. Li, Polym. Eng. Sci. 2022, 62, 1166.
- 22L. Maubane, S. S. Ray, K. Jalama, Carbohydr. Polym. 2017, 155, 89.
- 23M. C. Righetti, P. Cinelli, L. Aliotta, E. Bianchi, F. Tricoli, M. Seggiani, A. Lazzeri, Polym. Int. 2022, 71, 47.
- 24D. Garlotta, J. Polym. Environ. 2001, 9, 63.
- 25L. T. Lim, R. Auras, M. Rubino, Prog. Polym. Sci. 2008, 33, 820.
- 26R. E. Drumright, P. R. Gruber, D. E. Henton, Adv. Mater. 1841, 2000, 12.
- 27Y. Zhao, B. H. Zhao, B. L. Wei, Y. X. Wei, J. R. Yao, H. L. Zhang, X. Chen, Z. Z. Shao, Int. J. Biol. Macromol. 2020, 165, 460.
- 28V. Ojijo, S. S. Ray, R. Sadiku, ACS Appl. Mater. Interfaces 2012, 4, 6690.
- 29D. Lascano, L. Quiles-Carrillo, R. Balart, T. Boronat, N. Montanes, Materials 2019, 12, 622.
- 30V. Ojijo, S. S. Ray, R. Sadiku, ACS Appl. Mater. Interfaces 2013, 5, 4266.
- 31B. Palai, S. Mohanty, S. K. Nayak, Polym. Test. 2020, 83, 106130.
- 32P. Suwanamornlert, N. Kerddonfag, A. Sane, W. Chinsirikul, W. B. Zhou, V. Chonhenchob, Food Packag. Shelf Life 2020, 25, 100515.
- 33S. A. Pradeep, H. Kharbas, L. S. Turng, A. Avalos, J. G. Lawrence, S. Pilla, Polymer 2017, 9, 22.
- 34T. M. Ovitt, G. W. Coates, J. Am. Chem. Soc. 1999, 121, 4072.
- 35H. Tsuji, Y. Ikada, Polymer 1999, 40, 6699.
- 36S. Saeidlou, M. A. Huneault, H. B. Li, C. B. Park, Prog. Polym. Sci. 2012, 37, 1657.
- 37Y. Ikada, K. Jamshidi, H. Tsuji, S. H. Hyon, Macromolecules 1987, 20, 904.
- 38H. Tsuji, Macromol. Biosci. 2005, 5, 569.
- 39B. G. Wu, Q. T. Zeng, D. Y. Niu, W. J. Yang, W. F. Dong, M. Q. Chen, P. M. Ma, Macromolecules 2019, 52, 1092.
- 40C. X. Sun, Y. Zheng, S. S. Xu, L. L. Ni, X. Li, G. R. Shan, Y. Z. Bao, P. J. Pan, ACS Macro Lett. 2021, 10, 1023.
- 41H. W. Zhao, H. Liu, Y. Q. Liu, Y. Yang, RSC Adv. 2020, 10, 10482.
- 42Y. Li, Y. C. Yu, C. Y. Han, X. H. Wang, D. X. Huang, Chinese J. Polym. Sci. 2020, 38, 1267.
- 43P. J. Pan, Y. Inoue, Prog. Polym. Sci. 2009, 34, 605.
- 44N. V. Pogodina, V. P. Lavrenko, S. Srinivas, H. H. Winter, Polymer 2001, 42, 9031.
- 45Y. Zhao, B. L. Wei, M. Wu, H. L. Zhang, J. R. Yao, X. Chen, Z. Z. Shao, Int. J. Biol. Macromol. 2020, 155, 1468.
- 46L. Deng, C. Xu, X. H. Wang, Z. G. Wang, ACS Sustain. Chem. Eng. 2018, 6, 480.
- 47J. Duan, Y. N. Xie, J. H. Yang, T. Huang, N. Zhang, Y. Wang, J. H. Zhang, Polym. Test. 2016, 56, 220.
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