Volume 139, Issue 41 e52993

RESEARCH ARTICLE

Development of nanostructured green divalent manganese-coordinated polyurea

Laxmi,

Laxmi

Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi, India

Government College, Faridabad, India

Contribution: Conceptualization (lead), Writing - original draft (lead)

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Adnan Shahzaib,

Adnan Shahzaib

Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi, India

Contribution: Data curation (supporting), Software (supporting), Writing - original draft (supporting), Writing - review & editing (supporting)

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Manawwer Alam,

Manawwer Alam

Department of Chemistry, College of Science, King Saud University, Riyadh, Saudi Arabia

Contribution: Funding acquisition (supporting), Visualization (supporting)

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Anujit Ghosal,

Anujit Ghosal

Richardson Centre for Food Technology and Research, Department of Food & Human Nutritional Sciences, The University of Manitoba, Winnipeg, Canada

Contribution: Software (supporting), Visualization (supporting)

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Fahmina Zafar,

Corresponding Author

Fahmina Zafar

[email protected]

orcid.org/0000-0001-5454-3981

Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi, India

Correspondence

Nahid Nishat, Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025, India.

Email: [email protected]; Fahmina Zafar, Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025, India.

Email: [email protected]

Contribution: Supervision (supporting), Validation (supporting), Visualization (supporting)

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Nahid Nishat,

Corresponding Author

Nahid Nishat

[email protected]

orcid.org/0000-0003-4807-0051

Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi, India

Correspondence

Nahid Nishat, Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025, India.

Email: [email protected]; Fahmina Zafar, Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025, India.

Email: [email protected]

Contribution: Supervision (lead)

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Laxmi,

Laxmi

Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi, India

Government College, Faridabad, India

Contribution: Conceptualization (lead), Writing - original draft (lead)

Search for more papers by this author

Adnan Shahzaib,

Adnan Shahzaib

Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi, India

Contribution: Data curation (supporting), Software (supporting), Writing - original draft (supporting), Writing - review & editing (supporting)

Search for more papers by this author

Manawwer Alam,

Manawwer Alam

Department of Chemistry, College of Science, King Saud University, Riyadh, Saudi Arabia

Contribution: Funding acquisition (supporting), Visualization (supporting)

Search for more papers by this author

Anujit Ghosal,

Anujit Ghosal

Richardson Centre for Food Technology and Research, Department of Food & Human Nutritional Sciences, The University of Manitoba, Winnipeg, Canada

Contribution: Software (supporting), Visualization (supporting)

Search for more papers by this author

Fahmina Zafar,

Corresponding Author

Fahmina Zafar

[email protected]

orcid.org/0000-0001-5454-3981

Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi, India

Correspondence

Nahid Nishat, Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025, India.

Email: [email protected]; Fahmina Zafar, Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025, India.

Email: [email protected]

Contribution: Supervision (supporting), Validation (supporting), Visualization (supporting)

Search for more papers by this author

Nahid Nishat,

Corresponding Author

Nahid Nishat

[email protected]

orcid.org/0000-0003-4807-0051

Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi, India

Correspondence

Nahid Nishat, Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025, India.

Email: [email protected]; Fahmina Zafar, Inorganic Materials Research Lab, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025, India.

Email: [email protected]

Contribution: Supervision (lead)

Search for more papers by this author

First published: 08 August 2022

https://doi.org/10.1002/app.52993

Citations: 3

Funding information: King Saud University, Grant/Award Number: RSP-2021/113

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Abstract

The work presented here reports the greener synthesis of polyurea (GPUa) via in-situ solvent-free precipitation polymerization of toluene diisocyanate (TDI) (used as monomer) and water. The divalent manganese [Mn(II)] ions were incorporated into GPUa to form Mn(II)-GPUa to enhance its applicability. The structure of GPUa and Mn(II)-GPUa was validated by Fourier-transform infrared and proton nuclear magnetic resonance spectral techniques. The morphology along with the elemental analysis of GPUa and Mn(II)-GPUa was assessed by X-ray diffraction analysis and field emission scanning electron microscopy along with energy-dispersive X-ray spectroscopy. Thermal degradation behavior and stability of GPUa and Mn(II)-GPUa were investigated by thermo-gravimetric, differential thermal, differential scanning calorimetry, and integral procedure decomposition temperature analysis. Furthermore, the batch adsorption method was used to examine the adsorption behavior of Mn(II)-GPUa. The study's results indicated that Mn(II)-GPUa might be used as an eco-friendly, thermally stable material and adsorbent, making it suitable as an effective dye adsorbent for wastewater treatment. The current work is aligned with Green chemistry principles (Principles 1, 2, 3, 4, 5, 6, 8, and 12).

CONFLICT OF INTEREST

The authors have no competing interest to declare.

Open Research

DATA AVAILABILITY STATEMENT

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Volume139, Issue41

November 5, 2022

e52993

Development of nanostructured green divalent manganese-coordinated polyurea

Abstract

CONFLICT OF INTEREST

Open Research

DATA AVAILABILITY STATEMENT

REFERENCES

Citing Literature

References

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Development of nanostructured green divalent manganese-coordinated polyurea

Abstract

CONFLICT OF INTEREST

Open Research

DATA AVAILABILITY STATEMENT

REFERENCES

Citing Literature

References

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