Volume 120, Issue 1 pp. 56-61

Synthesis and curing properties of a novel curing agent based on N-(4-hydroxyphenyl) maleimide and dicyclopentadiene moieties

Jia Liu,

Jia Liu

College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China

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Xiao-Liang Zeng,

Xiao-Liang Zeng

College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China

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Xu-Yong Zhang,

Xu-Yong Zhang

College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China

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Xin-Nian Xia,

Corresponding Author

Xin-Nian Xia

[email protected]

College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China

College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China===Search for more papers by this author

Jia Liu,

Jia Liu

College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China

Search for more papers by this author

Xiao-Liang Zeng,

Xiao-Liang Zeng

College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China

Search for more papers by this author

Xu-Yong Zhang,

Xu-Yong Zhang

College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China

Search for more papers by this author

Xin-Nian Xia,

Corresponding Author

Xin-Nian Xia

[email protected]

College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China

College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China===Search for more papers by this author

First published: 11 October 2010

https://doi.org/10.1002/app.32850

Citations: 7

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Abstract

A new type of epoxy resin curing agent, containing pendant phenol functions, was synthesized by the free-radical copolymerization of N-(4-hydroxyphenyl) maleimide with dicyclopentadiene (DCPD) monomer in the presence of a radical initiator. The chemical structure was characterized with Fourier transform infrared spectroscopy and nuclear magnetic resonance. The molecular weight of the new curing agent was determined by gel permeation chromatography. The activity and activation energy of this new curing agent with o-cresol formaldehyde novolac epoxy (CNE) was investigated with a nonisothermal differential scanning calorimetry technique at different heating rates. The thermal properties of the cured polymers were evaluated with thermogravimetric analysis, and the results exhibit good thermal stability. In addition, this new curing agent with CNE showed low moisture absorption because of the hydrophobic nature of the DCPD structure. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011

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Volume120, Issue1

5 April 2011

Pages 56-61

Synthesis and curing properties of a novel curing agent based on N-(4-hydroxyphenyl) maleimide and dicyclopentadiene moieties

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Synthesis and curing properties of a novel curing agent based on N-(4-hydroxyphenyl) maleimide and dicyclopentadiene moieties

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