A PCP Pincer Ligand for Coordination Polymers with Versatile Chemical Reactivity: Selective Activation of CO2 Gas over CO Gas in the Solid State
Junpeng He
Department of Chemistry, The University of Texas at Austin, NHB 6.336, 100 E. 24th St. Stop A1590, Austin, TX, 78712 USA
Search for more papers by this authorNolan W. Waggoner
Department of Chemistry, The University of Texas at Austin, NHB 6.336, 100 E. 24th St. Stop A1590, Austin, TX, 78712 USA
Search for more papers by this authorSamuel G. Dunning
Department of Chemistry, The University of Texas at Austin, NHB 6.336, 100 E. 24th St. Stop A1590, Austin, TX, 78712 USA
Search for more papers by this authorDr. Alexander Steiner
Department of Chemistry, University of Liverpool, Crown St., Liverpool, L69 7ZD UK
Search for more papers by this authorDr. Vincent M. Lynch
Department of Chemistry, The University of Texas at Austin, NHB 6.336, 100 E. 24th St. Stop A1590, Austin, TX, 78712 USA
Search for more papers by this authorCorresponding Author
Prof. Simon M. Humphrey
Department of Chemistry, The University of Texas at Austin, NHB 6.336, 100 E. 24th St. Stop A1590, Austin, TX, 78712 USA
Search for more papers by this authorJunpeng He
Department of Chemistry, The University of Texas at Austin, NHB 6.336, 100 E. 24th St. Stop A1590, Austin, TX, 78712 USA
Search for more papers by this authorNolan W. Waggoner
Department of Chemistry, The University of Texas at Austin, NHB 6.336, 100 E. 24th St. Stop A1590, Austin, TX, 78712 USA
Search for more papers by this authorSamuel G. Dunning
Department of Chemistry, The University of Texas at Austin, NHB 6.336, 100 E. 24th St. Stop A1590, Austin, TX, 78712 USA
Search for more papers by this authorDr. Alexander Steiner
Department of Chemistry, University of Liverpool, Crown St., Liverpool, L69 7ZD UK
Search for more papers by this authorDr. Vincent M. Lynch
Department of Chemistry, The University of Texas at Austin, NHB 6.336, 100 E. 24th St. Stop A1590, Austin, TX, 78712 USA
Search for more papers by this authorCorresponding Author
Prof. Simon M. Humphrey
Department of Chemistry, The University of Texas at Austin, NHB 6.336, 100 E. 24th St. Stop A1590, Austin, TX, 78712 USA
Search for more papers by this authorGraphical Abstract
Poly-PCP-pincers: A new synthetic strategy for the formation of crystalline, porous versions of PCP-pincer complexes is presented. These complexes can selectively activate gas molecules, such as CO2 over CO, in the solid state. PCP=Porous Coordination Polymer
Abstract
A tetra(carboxylated) PCP pincer ligand has been synthesized as a building block for porous coordination polymers (PCPs). The air- and moisture-stable PCP metalloligands are rigid tetratopic linkers that are geometrically akin to ligands used in the synthesis of robust metal–organic frameworks (MOFs). Here, the design principle is demonstrated by cyclometalation with PdIICl and subsequent use of the metalloligand to prepare a crystalline 3D MOF by direct reaction with CoII ions and structural resolution by single crystal X-ray diffraction. The Pd−Cl groups inside the pores are accessible to post-synthetic modifications that facilitate chemical reactions previously unobserved in MOFs: a Pd−CH3 activated material undergoes rapid insertion of CO2 gas to give Pd−OC(O)CH3 at 1 atm and 298 K. However, since the material is highly selective for the adsorption of CO2 over CO, a Pd−N3 modified version resists CO insertion under the same conditions.
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