Communication
Friedel–Crafts Arylation for the Formation of C
C
Bonds: A Route to Unsymmetrical and Functionalized Polycyclic Aromatic Hydrocarbons from Aryl Triazenes†
Jun Zhou,
Weijun Yang,
Binjie Wang,
Prof. Dr. Hongjun Ren,
Jun Zhou
Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027 (P. R. China)
Search for more papers by this authorWeijun Yang
Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027 (P. R. China)
Search for more papers by this authorBinjie Wang
Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Hongjun Ren
Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027 (P. R. China)
Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018 (P. R. China)
Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027 (P. R. China)Search for more papers by this authorJun Zhou,
Weijun Yang,
Binjie Wang,
Prof. Dr. Hongjun Ren,
Jun Zhou
Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027 (P. R. China)
Search for more papers by this authorWeijun Yang
Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027 (P. R. China)
Search for more papers by this authorBinjie Wang
Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Hongjun Ren
Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027 (P. R. China)
Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018 (P. R. China)
Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027 (P. R. China)Search for more papers by this author†
We are grateful for financial support from the National Nature Science Foundation of China (21272003) as well as a Scholarship Award for Excellent Doctoral Student granted by the Ministry of Education (2011).
Graphical Abstract
Rings, rings, rings: A Friedel–Crafts intramolecular arylation for the synthesis of polycyclic aromatic hydrocarbons from aryl triazenes has been achieved. Polycyclic aromatic compounds consisting of five-, six-, and seven-membered rings can be prepared using this method.
Supporting Information
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