Perovskite B-Site Compositional Control of [110]p Polar Displacement Coupling in an Ambient-Pressure-Stable Bismuth-based Ferroelectric†
Michelle R. Dolgos
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)
Search for more papers by this authorUmut Adem
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)
Search for more papers by this authorAlicia Manjon-Sanz
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)
Search for more papers by this authorXinming Wan
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)
Search for more papers by this authorTim P. Comyn
Institute for Materials Research, University of Leeds, Leeds, LS2 9JT (UK)
Search for more papers by this authorTimothy Stevenson
Institute for Materials Research, University of Leeds, Leeds, LS2 9JT (UK)
Search for more papers by this authorJames Bennett
Institute for Materials Research, University of Leeds, Leeds, LS2 9JT (UK)
Search for more papers by this authorAndrew J. Bell
Institute for Materials Research, University of Leeds, Leeds, LS2 9JT (UK)
Search for more papers by this authorT. Thao Tran
University of Houston, Department of Chemistry, Houston, TX 77204 (USA)
Search for more papers by this authorP. Shiv Halasyamani
University of Houston, Department of Chemistry, Houston, TX 77204 (USA)
Search for more papers by this authorCorresponding Author
John B. Claridge
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)Search for more papers by this authorCorresponding Author
Matthew J. Rosseinsky
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)Search for more papers by this authorMichelle R. Dolgos
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)
Search for more papers by this authorUmut Adem
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)
Search for more papers by this authorAlicia Manjon-Sanz
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)
Search for more papers by this authorXinming Wan
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)
Search for more papers by this authorTim P. Comyn
Institute for Materials Research, University of Leeds, Leeds, LS2 9JT (UK)
Search for more papers by this authorTimothy Stevenson
Institute for Materials Research, University of Leeds, Leeds, LS2 9JT (UK)
Search for more papers by this authorJames Bennett
Institute for Materials Research, University of Leeds, Leeds, LS2 9JT (UK)
Search for more papers by this authorAndrew J. Bell
Institute for Materials Research, University of Leeds, Leeds, LS2 9JT (UK)
Search for more papers by this authorT. Thao Tran
University of Houston, Department of Chemistry, Houston, TX 77204 (USA)
Search for more papers by this authorP. Shiv Halasyamani
University of Houston, Department of Chemistry, Houston, TX 77204 (USA)
Search for more papers by this authorCorresponding Author
John B. Claridge
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)Search for more papers by this authorCorresponding Author
Matthew J. Rosseinsky
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK)Search for more papers by this authorThis work is funded by the European Research Council (M.D. is supported by ERC Grant agreement 227987 RLUCIM), the EPSRC (U.A. is supported by EP/H000925) and the Northwest Development Agency through the Knowledge Centre for Materials Chemistry. A.M.S. is supported by the European Union by the SOPRANO project (Grant No. PITN-GA-2008-214040). We thank ESRF (ID31) and ISIS (HRPD, GEM) for diffraction instrument access, and Prof. A. Fitch (ESRF) and Dr. K. S. Knight (ISIS) for their input into this work. P.S.H. and T.T.T. thank the Welch Foundation (Grant E-1457) for support.
Graphical Abstract
Off the axis: A new lead-free bismuth based perovskite has been formed at ambient pressure in the polar Pmc21 structure. Measurements give evidence for ferroelectricity and piezoelectricity. The material is significant due to a rotation of the polarization direction off the [111]p axis, making it important to the design of materials with a morphotropic phase boundary.
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