A Twin-Axial Hetero[7]rotaxane†
Zhi-Jun Zhang
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (P.R. China)
Search for more papers by this authorProf. Dr. Heng-Yi Zhang
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (P.R. China)
Search for more papers by this authorHui Wang
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (P.R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Yu Liu
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (P.R. China)
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (P.R. China)Search for more papers by this authorZhi-Jun Zhang
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (P.R. China)
Search for more papers by this authorProf. Dr. Heng-Yi Zhang
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (P.R. China)
Search for more papers by this authorHui Wang
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (P.R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Yu Liu
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (P.R. China)
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (P.R. China)Search for more papers by this authorWe thank the 973 Program (2011CB932500), and the NNSFC (Nos. 20932004 and 20972077) for financial support.
Graphical Abstract
Two in one: Two pseudorotaxanes can be combined to form a twin-axial hetero[7]rotaxane (see picture) by using the copper-catalyzed alkyne–azide “click” reaction. The synthetic route, in which twin-axial and single-axial rotaxanes are formed, combines self-assembly and the formation of covalent bonds to ensure the correct positioning of the two types of rings in the final product.
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Citing Literature
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