DNA-Programmed Glaser–Eglinton Reactions for the Synthesis of Conjugated Molecular Wires†
Jens B. Ravnsbæk
Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
Search for more papers by this authorMikkel F. Jacobsen
Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
Search for more papers by this authorChristian B. Rosen
Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
Search for more papers by this authorNiels V. Voigt
Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
Search for more papers by this authorCorresponding Author
Prof. Kurt V. Gothelf
Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)Search for more papers by this authorJens B. Ravnsbæk
Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
Search for more papers by this authorMikkel F. Jacobsen
Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
Search for more papers by this authorChristian B. Rosen
Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
Search for more papers by this authorNiels V. Voigt
Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
Search for more papers by this authorCorresponding Author
Prof. Kurt V. Gothelf
Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)Search for more papers by this authorThe work was supported by the Danish National Research Foundation.
Graphical Abstract
Wire self-assembly: Short oligo(phenylene ethynylene) modules (black structures, see picture) are assembled by attached DNA strands, which also direct the formation of 1,3-diyne linkages between the modules by the Cu-mediated Glaser–Eglinton reaction to selectively form dimer, trimer, and tetramer conjugated wires of up to 8 nm in length.
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