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Plasma-Assisted Dissociation of Organometallic Vapors for Continuous, Gas-Phase Preparation of Multimetallic Nanoparticles^†

Pin Ann Lin

Department of Chemical Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7217 (USA)

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Prof. R. Mohan Sankaran,

Corresponding Author

Prof. R. Mohan Sankaran

[email protected]

Department of Chemical Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7217 (USA)

Department of Chemical Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7217 (USA)Search for more papers by this author

Pin Ann Lin,

Pin Ann Lin

Department of Chemical Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7217 (USA)

Search for more papers by this author

Prof. R. Mohan Sankaran,

Corresponding Author

Prof. R. Mohan Sankaran

[email protected]

Department of Chemical Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7217 (USA)

Department of Chemical Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7217 (USA)Search for more papers by this author

First published: 22 September 2011

https://doi.org/10.1002/anie.201101881

Citations: 38

^†

We acknowledge funding from the NSF CAREER Award Program (CBET-0746821). R.M.S. also thanks the AFOSR Young Investigator Program and the Camille Dreyfus Teacher-Scholar Awards Program for their support.

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Graphical Abstract

Vapor-sized: In a plasma-based route to multimetallic nanoparticles (NPs), vapor mixtures of organometallic compounds are dissociated in an atmospheric-pressure microplasma (see picture). The size and composition of the particles is controlled by the relative vapor concentrations of the precursors.

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References

1J. L. Lyon, D. A. Fleming, M. B. Stone, P. Schiffer, M. E. Williams, Nano Lett. 2004, 4, 719–723.
10.1021/nl035253f
CAS Web of Science® Google Scholar
2X. Gao, L. Yu, R. I. MacCuspie, H. Matsui, Adv. Mater. 2005, 17, 426–429.
10.1002/adma.200400898
CAS Web of Science® Google Scholar
3C. Wang, D. Vliet, K. L. More, N. J. Zaluzec, S. Peng, S. Sun, H. Daimon, G. Wang, J. Greeley, J. Pearson, A. P. Paulikas, G. Karapetrov, D. Strmcnik, N. M. Markovic, V. R. Stamenkovic, Nano Lett. 2011, 11, 919–926.
10.1021/nl102369k
CAS PubMed Web of Science® Google Scholar
4J. Y. Park, Y. Zhang, M. Grass, T. Zhang, G. A. Somorjai, Nano Lett. 2008, 8, 673–677.
10.1021/nl073195i
CAS PubMed Web of Science® Google Scholar
5W.-H. Chiang, R. M. Sankaran, Adv. Mater. 2008, 20, 4857–4861.
10.1002/adma.200801006
CAS Web of Science® Google Scholar
6G. Frens et al., Nature Phys. Sci. 1973, 241, 20–22.
10.1038/physci241020a0
CAS Web of Science® Google Scholar
7I. Srnová-Šloufová, B. Vlčková, Z. Bastl, T. L. Hasslett, Langmuir 2004, 20, 3407–3415.
10.1021/la0302605
CAS PubMed Web of Science® Google Scholar
8F. Tao, M. E. Grass, Y. W. Zhang, D. R. Butcher, J. R. Renzas, Z. Liu, J. Y. Chung, B. S. Mun, M. Salmeron, G. A. Somorjai, Science 2008, 322, 932–934.
10.1126/science.1164170
CAS PubMed Web of Science® Google Scholar
9Z. Liu, C. Yu, I. A. Rusakova, D. Huang, P. Strasser, Top. Catal. 2008, 49, 241–250.
10.1007/s11244-008-9083-2
CAS Web of Science® Google Scholar
10H. K. Kammler, L. Mädler, S. E. Pratsinis, Chem. Eng. Technol. 2001, 24, 583–596.
10.1002/1521-4125(200106)24:6<583::AID-CEAT583>3.0.CO;2-H
CAS Web of Science® Google Scholar
11M. Ullmann, S. K. Friedlander, A. Schmidt-Ott, J. Nanopart. Res. 2002, 4, 499–509.
10.1023/A:1022840924336
CAS Web of Science® Google Scholar
12S. Eliezer, N. Eliaz, E. Grossman, D. Fisher, I. Gouzman, Z. Henis, S. Pecker, Y. Horovitz, M. Fraenkel, S. Maman, Y. Lereah, Phys. Rev. B 2004, 69, 144119.
10.1103/PhysRevB.69.144119
CAS Web of Science® Google Scholar
13D. Wang, Y. Li, Adv. Mater. 2011, 23, 1044–1060.
10.1002/adma.201003695
CAS PubMed Web of Science® Google Scholar
14H. Lillich, J. Wolfrum, V. Zumbach, L. E. Aleandri, D. J. Jones, J. Rozihre, P. Albers, K. Seibold, A. Freund, J. Phys. Chem. 1995, 99, 12413–12421.
10.1021/j100033a009
CAS Web of Science® Google Scholar
15R. Strobel, J-D. Grunwaldt, A. Camenzind, S. E. Pratsinis, A. Baiker, Catal. Lett. 2005, 104, 9–16.
10.1007/s10562-005-7429-y
CAS Web of Science® Google Scholar
16S. Senkan, M. Kahn, S. Duan, A. Ly, C. Leidhom, Catal. Today 2006, 117, 291–296.
10.1016/j.cattod.2006.05.051
CAS Web of Science® Google Scholar
17G. J. M. Dormans, J. Cryst. Growth 1991, 108, 806–816.
10.1016/0022-0248(91)90261-3
CAS Web of Science® Google Scholar
18J. Pelletier, R. Pantel, J. C. Oberlin, Y. Pauleau, P. Gouy-pailler, J. Appl. Phys. 1991, 70, 3862–3866.
10.1063/1.349192
CAS Web of Science® Google Scholar
19J. B. Edel, R. Fortt, J. C. deMello, A. J. deMello, Chem. Commun. 2002, 1136–1137.
10.1039/b202998g
CAS PubMed Web of Science® Google Scholar
20K. H. Brian, K. F. Jensen, M. G. Bawendi, Angew. Chem. 2005, 117, 5583–5587;
10.1002/ange.200500792
Google Scholar
Angew. Chem. Int. Ed. 2005, 44, 5447–5451.
10.1002/anie.200500792
CAS PubMed Web of Science® Google Scholar
21J. P. Borra, J. Phys. D 2006, 39, R 19–R54.
10.1088/0022-3727/39/2/R01
CAS Web of Science® Google Scholar
22A. Bapat, C. R. Perrey, S. A. Campbell, C. B. Carter, U. Kortshagen, J. Appl. Phys. 2003, 94, 1969–1974.
10.1063/1.1586957
CAS Web of Science® Google Scholar
23U. Kortshagen, U. Bhandarkar, Phys. Rev. E 1999, 60, 887.
10.1103/PhysRevE.60.887
CAS PubMed Web of Science® Google Scholar
24R. M. Sankaran, K. P. Giapis, J. Appl. Phys. 2002, 92, 2406.
10.1063/1.1497719
CAS Web of Science® Google Scholar
25D. Mariotti, R. M. Sankaran, J. Phys. D 2010, 43, 323001.
10.1088/0022-3727/43/32/323001
CAS Web of Science® Google Scholar
26J. H. Seinfeld, S. N. Pandis, Atmospheric Chemistry and Physics, Wiley, New York, NY, 1998.
Google Scholar
27N. E. Motl, E. Ewusi-Annan, I. T. Sines, L. Jensen, R. E. Schaak, J. Phys. Chem. C 2010, 114, 19263–19269.
10.1021/jp107637j
CAS Web of Science® Google Scholar

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Volume50, Issue46

November 11, 2011

Pages 10953-10956

Plasma-Assisted Dissociation of Organometallic Vapors for Continuous, Gas-Phase Preparation of Multimetallic Nanoparticles^†

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Plasma-Assisted Dissociation of Organometallic Vapors for Continuous, Gas-Phase Preparation of Multimetallic Nanoparticles†

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Plasma-Assisted Dissociation of Organometallic Vapors for Continuous, Gas-Phase Preparation of Multimetallic Nanoparticles^†