A Water-Based Synthesis of Octahedral, Decahedral, and Icosahedral Pd Nanocrystals†
Byungkwon Lim Dr.
Department of Chemistry, University of Washington, Seattle, Washington 98195, USA
Search for more papers by this authorYujie Xiong Dr.
Department of Chemistry, University of Washington, Seattle, Washington 98195, USA
Search for more papers by this authorYounan Xia Prof.
Department of Chemistry, University of Washington, Seattle, Washington 98195, USA
Search for more papers by this authorByungkwon Lim Dr.
Department of Chemistry, University of Washington, Seattle, Washington 98195, USA
Search for more papers by this authorYujie Xiong Dr.
Department of Chemistry, University of Washington, Seattle, Washington 98195, USA
Search for more papers by this authorYounan Xia Prof.
Department of Chemistry, University of Washington, Seattle, Washington 98195, USA
Search for more papers by this authorThis work was supported in part by grants from the ACS (PRF-44353-AC10) and the NSF (DMR-0451788), and a subcontract from GEMSEC, an MRSEC program on the UW campus sponsored by NSF. Y.X. is a Camille Dreyfus Teacher Scholar (2002–2007). B.L. was partially supported by the Postdoctoral Fellowship Program of the Korea Research Foundation (KRF).
Graphical Abstract
Shapes from water: Pd nanocrystals with controllable shapes are synthesized by reducing a Pd salt with citric acid in aqueous solution. Citric acid favors the formation of octahedra, icosahedra, or decahedra (see picture) owing to its strong binding to the {111} facets of Pd. Shape control of these nanocrystals is readily accomplished by adjusting the amounts of Na2PdCl4 precursor and citric acid added to the reaction mixture.
Supporting Information
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