Sol–Gel Reaction Using DNA as a Template: An Attempt Toward Transcription of DNA into Inorganic Materials
Munenori Numata Dr.
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 812–8581, Japan, Fax: (+81) 92-642-3611
Search for more papers by this authorKazunori Sugiyasu
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 812–8581, Japan, Fax: (+81) 92-642-3611
Search for more papers by this authorTeruaki Hasegawa Dr.
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 812–8581, Japan, Fax: (+81) 92-642-3611
Search for more papers by this authorSeiji Shinkai Prof.
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 812–8581, Japan, Fax: (+81) 92-642-3611
Search for more papers by this authorMunenori Numata Dr.
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 812–8581, Japan, Fax: (+81) 92-642-3611
Search for more papers by this authorKazunori Sugiyasu
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 812–8581, Japan, Fax: (+81) 92-642-3611
Search for more papers by this authorTeruaki Hasegawa Dr.
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 812–8581, Japan, Fax: (+81) 92-642-3611
Search for more papers by this authorSeiji Shinkai Prof.
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 812–8581, Japan, Fax: (+81) 92-642-3611
Search for more papers by this authorGraphical Abstract
The topologically different structures in plasmid DNA can be successfully transcribed into silica structures by using the DNA as a template for sol–gel polycondensation of tetraethoxysilane after treatment by two cation-exchange steps (see scheme). These findings imply that the different ordered silica structures can be created from the same template through its higher-order conformational changes.
Supporting Information
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