Expanding and Shrinking Porous Modulation Based on Pillared-Layer Coordination Polymers Showing Selective Guest Adsorption†
Tapas Kumar Maji Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorKazuhiro Uemura
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorHo-Chol Chang Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorRyotaro Matsuda
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorSusumu Kitagawa Prof. Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorTapas Kumar Maji Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorKazuhiro Uemura
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorHo-Chol Chang Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorRyotaro Matsuda
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorSusumu Kitagawa Prof. Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorThis work was supported by Core Research for Evolutional Science and Technology (CREST), and by the Japan Science and Technology Corporation (JST). Dr. T. K. Maji is grateful to JSPS for postdoctoral fellowship.
Graphical Abstract
Rationally designed and synthesized, two novel pillar-layered 3D microporous frameworks {[Cd(pzdc)(azpy)]⋅2 H2O}n (1, left) and {[Cd(pzdc)(bpee)]⋅1.5 H2O}n (2, right) have high thermal stability and highly selective adsorption properties. Removal of guest water molecules results in the expansion of 1 but the contraction of 2.
Supporting Information
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