Fluorination from Surface to Bulk Stabilizing High Nickel Cathode Materials with Outstanding Electrochemical Performance
Jieyu Yang
Jiangsu Key Laboratory of Materials and Technologies for Energy Storage, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu, 210016 China
These authors contributed equally to this work.
Search for more papers by this authorGuihong Mao
Jiangsu Key Laboratory of Materials and Technologies for Energy Storage, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu, 210016 China
These authors contributed equally to this work.
Search for more papers by this authorTengyu Yao
Jiangsu Key Laboratory of Materials and Technologies for Energy Storage, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu, 210016 China
Search for more papers by this authorCorresponding Author
Prof. Laifa Shen
Jiangsu Key Laboratory of Materials and Technologies for Energy Storage, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu, 210016 China
Search for more papers by this authorCorresponding Author
Prof. Yan Yu
Hefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorJieyu Yang
Jiangsu Key Laboratory of Materials and Technologies for Energy Storage, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu, 210016 China
These authors contributed equally to this work.
Search for more papers by this authorGuihong Mao
Jiangsu Key Laboratory of Materials and Technologies for Energy Storage, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu, 210016 China
These authors contributed equally to this work.
Search for more papers by this authorTengyu Yao
Jiangsu Key Laboratory of Materials and Technologies for Energy Storage, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu, 210016 China
Search for more papers by this authorCorresponding Author
Prof. Laifa Shen
Jiangsu Key Laboratory of Materials and Technologies for Energy Storage, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu, 210016 China
Search for more papers by this authorCorresponding Author
Prof. Yan Yu
Hefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorAbstract
High nickel layered oxides provide high energy densities as cathodes for next-generation batteries. However, critical issues such as capacity fading and voltage decay, which derive from labile surface reactivity and phase transition, especially under high-rate high-voltage conditions, prevent their commercialization. Here we propose a fluorination strategy to simultaneously introduce F atoms into oxygen layer and create a F aggregated interface. Substitution F for O stabilizes the layered ionic framework as the F ions can anchor the internal transition metal ions through strong TM−F bonding interaction, alleviating anisotropic lattice strain accumulation and release during the cycle, and promoting the Li+ dynamics diffusion. Meanwhile, the fluorinated interface induces the formation of a thin and stable CEI, ameliorating the detrimental issues like oxygen vacancy formation, the HF attacks and metal dissolution. The resultant fluorinated cathode delivers a high reversible capacity of 192.9 mAh g−1 at 10 C within the voltage range of 2.7–4.5 V. This fluorination strategy approach provides design concepts for the advanced cathodes that can meet the demands of high-rate and high-voltage applications in next-generation batteries.
Conflict of Interests
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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