Generating Strong Circularly Polarized Luminescence from Self-assembled Films of Chiral Selenium Nanoparticles and Upconversion Nanoparticles
Hui Zhangsun
State Key Laboratory of Food Science and Technology, International Joint Research Laboratory for Biointerface and Biodetection, School of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu, 214122 P.R. China
Search for more papers by this authorProf. Liguang Xu
State Key Laboratory of Food Science and Technology, International Joint Research Laboratory for Biointerface and Biodetection, School of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu, 214122 P.R. China
Search for more papers by this authorCorresponding Author
Dr. Aihua Qu
State Key Laboratory of Food Science and Technology, International Joint Research Laboratory for Biointerface and Biodetection, School of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu, 214122 P.R. China
Search for more papers by this authorProf. Chuanlai Xu
State Key Laboratory of Food Science and Technology, International Joint Research Laboratory for Biointerface and Biodetection, School of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu, 214122 P.R. China
Search for more papers by this authorCorresponding Author
Prof. Hua Kuang
State Key Laboratory of Food Science and Technology, International Joint Research Laboratory for Biointerface and Biodetection, School of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu, 214122 P.R. China
Search for more papers by this authorCorresponding Author
Dr. Changlong Hao
State Key Laboratory of Food Science and Technology, International Joint Research Laboratory for Biointerface and Biodetection, School of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu, 214122 P.R. China
Search for more papers by this authorHui Zhangsun
State Key Laboratory of Food Science and Technology, International Joint Research Laboratory for Biointerface and Biodetection, School of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu, 214122 P.R. China
Search for more papers by this authorProf. Liguang Xu
State Key Laboratory of Food Science and Technology, International Joint Research Laboratory for Biointerface and Biodetection, School of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu, 214122 P.R. China
Search for more papers by this authorCorresponding Author
Dr. Aihua Qu
State Key Laboratory of Food Science and Technology, International Joint Research Laboratory for Biointerface and Biodetection, School of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu, 214122 P.R. China
Search for more papers by this authorProf. Chuanlai Xu
State Key Laboratory of Food Science and Technology, International Joint Research Laboratory for Biointerface and Biodetection, School of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu, 214122 P.R. China
Search for more papers by this authorCorresponding Author
Prof. Hua Kuang
State Key Laboratory of Food Science and Technology, International Joint Research Laboratory for Biointerface and Biodetection, School of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu, 214122 P.R. China
Search for more papers by this authorCorresponding Author
Dr. Changlong Hao
State Key Laboratory of Food Science and Technology, International Joint Research Laboratory for Biointerface and Biodetection, School of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu, 214122 P.R. China
Search for more papers by this authorAbstract
Circularly polarized luminescence (CPL) has garnered significant research attention. Achieving a high luminescence dissymmetry factor (glum) is a key challenge in this field. Herein, we reported, for the first time, the fabrication of a chiral assembled film consisting of chiral D-/L-Selenium nanoparticles (D-/L-Se NPs) and DSPE-PEG-NH2 modified upconversion nanoparticles (DPNUCNPs) with remarkable CPL properties that were generated by the interfacial self-assembly technique. The chiral Se/DPNUCNPs films, consisting of three layers (3L) of D-/L-Se films and 3L DPNUCNPs films, exhibited the highest circular dichroism (CD) response and the strongest CPL signals. Under laser excitation at 980 nm, the 3L D-/L-Se/3L DPNUCNPs assembled films displayed symmetric CPL signals between 400 and 600 nm, with a maximum |glum| value of 0.68. The interaction between DPNUCNPs and Se NPs involves energy transfer and chirality transfer, along with the formation of spin-polarized excitons, thereby resulting in CPL activity. Furthermore, the chiral Se/DPNUCNPs films were patterned for anti-counterfeit and encryption applications. Our study provides a novel guide for fabricating chiral nanomaterials with strong CPL response.
Conflict of Interests
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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