Charging Metal-Organic Framework Membranes by Incorporating Crown Ethers to Capture Cations for Ion Sieving
Dr. Jiang Li
Department of Anesthesiology and Perioperative medicine, Shanghai Key Laboratory of Anesthesiology and Brain Functional Modulation, Shanghai Fourth People's Hospital, School of Medicine, Tongji University, Shanghai, 200434 P. R. China
School of Materials Science and Engineering, School of Water and Environment, Chang'an University, Xian, 710062 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorYayun Shi
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan, 030024 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorChenyang Qi
School of Materials Science and Engineering, Tongji University, Shanghai, 201804 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorBowen Zhang
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorProf. Xiwen Xing
Department of Biotechnology, College of Life Science and Technology, Jinan University, Guangzhou, 510632 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Yuliang Li
School of Materials Science and Engineering, School of Water and Environment, Chang'an University, Xian, 710062 P. R. China
Search for more papers by this authorTongdan Chen
School of Materials Science and Engineering, School of Water and Environment, Chang'an University, Xian, 710062 P. R. China
Search for more papers by this authorXingnuo Mao
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorProf. Zhijun Zuo
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan, 030024 P. R. China
Search for more papers by this authorDr. Xiaoli Zhao
School of Materials Science and Engineering, Tongji University, Shanghai, 201804 P. R. China
Search for more papers by this authorProf. Zhenghui Pan
School of Materials Science and Engineering, Tongji University, Shanghai, 201804 P. R. China
Search for more papers by this authorProf. Libo Li
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan, 030024 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Xiaowei Yang
Department of Anesthesiology and Perioperative medicine, Shanghai Key Laboratory of Anesthesiology and Brain Functional Modulation, Shanghai Fourth People's Hospital, School of Medicine, Tongji University, Shanghai, 200434 P. R. China
School of Materials Science and Engineering, Tongji University, Shanghai, 201804 P. R. China
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Cheng Li
Department of Anesthesiology and Perioperative medicine, Shanghai Key Laboratory of Anesthesiology and Brain Functional Modulation, Shanghai Fourth People's Hospital, School of Medicine, Tongji University, Shanghai, 200434 P. R. China
Search for more papers by this authorDr. Jiang Li
Department of Anesthesiology and Perioperative medicine, Shanghai Key Laboratory of Anesthesiology and Brain Functional Modulation, Shanghai Fourth People's Hospital, School of Medicine, Tongji University, Shanghai, 200434 P. R. China
School of Materials Science and Engineering, School of Water and Environment, Chang'an University, Xian, 710062 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorYayun Shi
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan, 030024 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorChenyang Qi
School of Materials Science and Engineering, Tongji University, Shanghai, 201804 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorBowen Zhang
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorProf. Xiwen Xing
Department of Biotechnology, College of Life Science and Technology, Jinan University, Guangzhou, 510632 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Yuliang Li
School of Materials Science and Engineering, School of Water and Environment, Chang'an University, Xian, 710062 P. R. China
Search for more papers by this authorTongdan Chen
School of Materials Science and Engineering, School of Water and Environment, Chang'an University, Xian, 710062 P. R. China
Search for more papers by this authorXingnuo Mao
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorProf. Zhijun Zuo
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan, 030024 P. R. China
Search for more papers by this authorDr. Xiaoli Zhao
School of Materials Science and Engineering, Tongji University, Shanghai, 201804 P. R. China
Search for more papers by this authorProf. Zhenghui Pan
School of Materials Science and Engineering, Tongji University, Shanghai, 201804 P. R. China
Search for more papers by this authorProf. Libo Li
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan, 030024 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Xiaowei Yang
Department of Anesthesiology and Perioperative medicine, Shanghai Key Laboratory of Anesthesiology and Brain Functional Modulation, Shanghai Fourth People's Hospital, School of Medicine, Tongji University, Shanghai, 200434 P. R. China
School of Materials Science and Engineering, Tongji University, Shanghai, 201804 P. R. China
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Cheng Li
Department of Anesthesiology and Perioperative medicine, Shanghai Key Laboratory of Anesthesiology and Brain Functional Modulation, Shanghai Fourth People's Hospital, School of Medicine, Tongji University, Shanghai, 200434 P. R. China
Search for more papers by this authorAbstract
Protein channels on the biofilm conditionally manipulate ion transport via regulating the distribution of charge residues, making analogous processes on artificial membranes a hot spot and challenge. Here, we employ metal–organic frameworks (MOFs) membrane with charge-adjustable subnano-channel to selectively govern ion transport. Various valent ions are binded with crown ethers embedded in the MOF cavity, which act as charged guest to regulate the channels’ charge state from the negativity to positivity. Compared with the negatively charged channel, the positive counterpart obviously enhances Li+/Mg2+ selectivity, which benefit from the reinforcement of the electrostatic repulsion between ions and the channel. Meanwhile, theoretical calculations reveal that Mg2+ transport through the more positively charged channel needed to overcome higher entrance energy barrier than that of Li+. This work provides a subtle strategy for ion-selective transport upon regulating the charge state of insulating membrane, which paves the way for the application like seawater desalination and lithium extraction from salt lakes.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the supplementary material of this article.
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