Real-Time In Situ Volatile Organic Compound Sensing by a Dual-Emissive Polynuclear Ln-MOF with Pronounced LnIII Luminescence Response
Jing-Jing Pang
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorCorresponding Author
Dr. Zhao-Quan Yao
School of Chemistry and Chemical Engineering, TKL of Organic Solar Cells and Photochemical Conversion, Tianjin University of Technology, Tianjin, 300384 China
Search for more papers by this authorKuo Zhang
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorDr. Quan-Wen Li
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorZi-Xuan Fu
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorRan Zheng
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorProf. Dr. Wei Li
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Jian Xu
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorProf. Dr. Xian-He Bu
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin, 300071 China
Search for more papers by this authorJing-Jing Pang
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorCorresponding Author
Dr. Zhao-Quan Yao
School of Chemistry and Chemical Engineering, TKL of Organic Solar Cells and Photochemical Conversion, Tianjin University of Technology, Tianjin, 300384 China
Search for more papers by this authorKuo Zhang
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorDr. Quan-Wen Li
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorZi-Xuan Fu
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorRan Zheng
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorProf. Dr. Wei Li
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Jian Xu
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
Search for more papers by this authorProf. Dr. Xian-He Bu
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin, 300350 China
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin, 300071 China
Search for more papers by this authorAbstract
Lanthanide metal–organic frameworks (Ln-MOFs) are promising for luminescence detection of volatile organic compound (VOC) vapors, but usually suffer from the silent or quenched Ln3+ emission. Herein, we report a new dual-emissive Eu-MOF composed of the coordinatively unsaturated Eu9 clusters that afford abundant open metal sites to form a confined “binding pocket” to facilitate the preconcentration and recognition of VOCs. Single-crystal structural analyses reveal that specific analytes can replace the OH oscillators in the first coordination sphere of Eu3+ and form a unique hydrogen-bonding second-sphere adduct tying adjacent Eu9 clusters together to minimize their nonradiative vibrational decay. With the promoted Eu3+ luminescence, the MOF realizes real-time in situ visual sensing of THF vapor (<1 s) and shows a quantitative ratiometric response to the vapor pressure with a limit of detection down to 17.33 Pa. Also, it represents a top-performing ratiometric luminescent thermometer.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the Supporting Information of this article.
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| ange202217456-sup-0001-misc_information.pdf3.5 MB | Supporting Information |
| ange202217456-sup-0001-SI_Movie_S1.mp42.3 MB | Supporting Information |
| ange202217456-sup-0001-SI_NKU-200-Eu-1,3-dioxane.cif519.1 KB | Supporting Information |
| ange202217456-sup-0001-SI_NKU-200-Eu-1,4-dioxane.cif713.8 KB | Supporting Information |
| ange202217456-sup-0001-SI_NKU-200-Eu-100K.cif785.4 KB | Supporting Information |
| ange202217456-sup-0001-SI_NKU-200-Eu-298K.cif1.1 MB | Supporting Information |
| ange202217456-sup-0001-SI_NKU-200-Eu-THF-10_min.cif780.7 KB | Supporting Information |
| ange202217456-sup-0001-SI_NKU-200-Eu-THF-30_min.cif770.7 KB | Supporting Information |
| ange202217456-sup-0001-SI_NKU-200-Eu-THF.cif698.2 KB | Supporting Information |
| ange202217456-sup-0001-SI_NKU-200-Eu-THP.cif559.2 KB | Supporting Information |
| ange202217456-sup-0001-SI_NKU-200-Gd.cif2 MB | Supporting Information |
| ange202217456-sup-0001-SI_NKU-200-Tb.cif1.2 MB | Supporting Information |
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