Individual (f,tA)- and (f,tC)-Fullerene-Based Nickel(II) Glycinates: Protected Chiral Amino Acids Directly Linked to a Chiral π-Electron System
Dr. Oleg A. Levitskiy
Chemistry Department, Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow, Russia
Search for more papers by this authorDr. Yuri K. Grishin
Chemistry Department, Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow, Russia
Search for more papers by this authorDr. Olesya O. Semivrazhskaya
Chemistry Department, Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow, Russia
Search for more papers by this authorDr. Asmik A. Ambartsumyan
Nesmeyanov Institute of Organoelement Compounds RAS, Vavilov str., 28, Moscow, Russia
Search for more papers by this authorDr. Konstantin A. Kochetkov
Nesmeyanov Institute of Organoelement Compounds RAS, Vavilov str., 28, Moscow, Russia
Search for more papers by this authorCorresponding Author
Prof. Dr. Tatiana V. Magdesieva
Chemistry Department, Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow, Russia
Search for more papers by this authorDr. Oleg A. Levitskiy
Chemistry Department, Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow, Russia
Search for more papers by this authorDr. Yuri K. Grishin
Chemistry Department, Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow, Russia
Search for more papers by this authorDr. Olesya O. Semivrazhskaya
Chemistry Department, Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow, Russia
Search for more papers by this authorDr. Asmik A. Ambartsumyan
Nesmeyanov Institute of Organoelement Compounds RAS, Vavilov str., 28, Moscow, Russia
Search for more papers by this authorDr. Konstantin A. Kochetkov
Nesmeyanov Institute of Organoelement Compounds RAS, Vavilov str., 28, Moscow, Russia
Search for more papers by this authorCorresponding Author
Prof. Dr. Tatiana V. Magdesieva
Chemistry Department, Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow, Russia
Search for more papers by this authorAbstract
Stereoselective electrosynthesis of the first individual (f,tA)- and (f,tC)-1,4-fullerene derivatives with a non-inherently chiral functionalization pattern is described, as well as the first example of an optically pure protected primary amino acid directly linked to the fullerene through only the chiral α-amino-acid carbon atom. An application of an auxiliary chiral nickel-Schiff base moiety as derivatizing agent allowed separation of (f,tA)- and (f,tC)-1,4-fullerene derivatives using an achiral stationary phase, a separation which has never been done before.
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