A Solvent-Free Hot-Pressing Method for Preparing Metal–Organic-Framework Coatings
Yifa Chen
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
These authors contributed equally to this work.
Search for more papers by this authorSiqing Li
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
These authors contributed equally to this work.
Search for more papers by this authorXiaokun Pei
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
These authors contributed equally to this work.
Search for more papers by this authorDr. Junwen Zhou
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorProf. Dr. Xiao Feng
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorShenghan Zhang
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorYuanyuan Cheng
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorHaiwei Li
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorRuodan Han
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorCorresponding Author
Prof. Dr. Bo Wang
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorYifa Chen
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
These authors contributed equally to this work.
Search for more papers by this authorSiqing Li
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
These authors contributed equally to this work.
Search for more papers by this authorXiaokun Pei
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
These authors contributed equally to this work.
Search for more papers by this authorDr. Junwen Zhou
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorProf. Dr. Xiao Feng
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorShenghan Zhang
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorYuanyuan Cheng
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorHaiwei Li
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorRuodan Han
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorCorresponding Author
Prof. Dr. Bo Wang
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081 P.R. China
Search for more papers by this authorAbstract
Metal–organic frameworks (MOFs), with their well-defined pores and rich structural diversity and functionality, have drawn a great deal of attention from across the scientific community. However, industrial applications are hampered by their intrinsic fragility and poor processability. Stable and resilient MOF devices with tunable flexibility are highly desirable. Herein, we present a solvent- and binder-free approach for producing stable MOF coatings by a unique hot-pressing (HoP) method, in which temperature and pressure are applied simultaneously to facilitate the rapid growth of MOF nanocrystals onto desired substrates. This strategy was proven to be applicable to carboxylate-based, imidazolate-based, and mixed-metal MOFs. We further successfully obtained superhydrophobic and “Janus” MOF films through layer-by-layer pressing. This HoP method can be scaled up in the form of roll-to-roll production and may push MOFs into unexplored industrial applications.
Supporting Information
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
| Filename | Description |
|---|---|
| ange201511063-sup-0001-misc_information.pdf2.6 MB | Supplementary |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1
- 1aH. Li, M. Eddaoudi, M. O'Keeffe, O. M. Yaghi, Nature 1999, 402, 276–279;
- 1bR. Kitaura, S. Kitagawa, Y. Kubota, T. C. Kobayashi, K. Kindo, Y. Mita, A. Matsuo, M. Kobayashi, H. C. Chang, T. C. Ozawa, M. Suzuki, M. Sakata, M. Takata, Science 2002, 298, 2358–2361;
- 1cG. Férey, C. Mellot-Draznieks, C. Serre, F. Millange, J. Dutour, S. Surblé, I. Margiolaki, Science 2005, 309, 2040–2042;
- 1dS. S. Y. Chui, S. M. F. Lo, J. P. H. Charmant, A. G. Orpen, I. D. Williams, Science 1999, 283, 1148–1150.
- 2
- 2aJ. R. Li, R. J. Kuppler, H. C. Zhou, Chem. Soc. Rev. 2009, 38, 1477–1504;
- 2bS. L. Qiu, M. Xue, G. S. Zhu, Chem. Soc. Rev. 2014, 43, 6116–6140;
- 2cJ. Lee, O. K. Farha, J. Roberts, K. A. Scheidt, S. T. Nguyen, J. T. Hupp, Chem. Soc. Rev. 2009, 38, 1450–1459;
- 2dB. L. Chen, S. C. Xiang, G. D. Qian, Acc. Chem. Res. 2010, 43, 1115–1124;
- 2eN. J. Hinks, A. C. McKinlay, B. Xiao, P. S. Wheatley, R. E. Morris, Microporous Mesoporous Mater. 2010, 129, 330–334.
- 3A. U. Czaja, N. Trukhan, U. Müller, Chem. Soc. Rev. 2009, 38, 1284–1293.
- 4
- 4aD. Zacher, O. Shekhah, C. Wöll, R. A. Fischer, Chem. Soc. Rev. 2009, 38, 1418–1429;
- 4bD. Bradshaw, A. Garai, J. Huo, Chem. Soc. Rev. 2012, 41, 2344–2381;
- 4cA. A. Talin, A. Centrone, A. C. Ford, M. E. Foster, V. Stavila, P. Haney, R. A. Kinney, V. Szalai, F. El Gabaly, H. P. Yoon, F. Léonard, M. D. Allendorf, Science 2014, 343, 66–69.
- 5
- 5aA. Huang, W. Dou, J. Caro, J. Am. Chem. Soc. 2010, 132, 15562–15564;
- 5bS. Hermes, F. Schröder, R. Chelmowski, C. Wöll, R. A. Fischer, J. Am. Chem. Soc. 2005, 127, 13744–13745;
- 5cG. Lu, O. K. Farha, W. N. Zhang, F. W. Huo, J. T. Hupp, Adv. Mater. 2012, 24, 3970–3974;
- 5dH. Bux, F. Y. Liang, Y. S. Li, J. Cravillon, M. Wiebcke, J. Caro, J. Am. Chem. Soc. 2009, 131, 16000–16001;
- 5eR. Ostermann, J. Cravillon, C. Weidmann, M. Wiebcke, B. M. Smarsly, Chem. Commun. 2011, 47, 442–444;
- 5fM. Y. Li, M. Dincă, Chem. Sci. 2014, 5, 107–111;
- 5gA. J. Brown, N. A. Brunelli, K. Eum, F. Rashidi, J. R. Johnson, W. J. Koros, C. W. Jones, S. Nair, Science 2014, 345, 72–75;
- 5hR. Zhang, S. Ji, N. Wang, L. Wang, G. Zhang, J.-R. Li, Angew. Chem. Int. Ed. 2014, 53, 9775–9779; Angew. Chem. 2014, 126, 9933–9937;
- 5iY. Sun, R. Zhang, C. Zhao, N. Wang, Y. Xie, J.-R. Li, RSC Adv. 2014, 4, 33007–33012.
- 6
- 6aP. Falcaro, R. Ricco, C. M. Doherty, K. Liang, A. J. Hill, M. J. Styles, Chem. Soc. Rev. 2014, 43, 5513–5560;
- 6bJ.-L. Zhuang, D. Ceglarek, S. Pethuraj, A. Terfort, Adv. Funct. Mater. 2011, 21, 1442–1447;
- 6cJ.-L. Zhuang, D. Ar, X.-J. Yu, J.-X. Liu, A. Terfort, Adv. Mater. 2013, 25, 4631–4635;
- 6dC. Dimitrakakis, B. Marmiroli, H. Amenitsch, L. Malfatti, P. Innocenzi, G. Grenci, L. Vaccari, A. J. Hill, B. P. Ladewig, M. R. Hill, P. Falcaro, Chem. Commun. 2012, 48, 7483–7485;
- 6eO. Shekhah, H. Wang, S. Kowarik, F. Schreiber, M. Paulus, M. Tolan, C. Sternemann, F. Evers, D. Zacher, R. A. Fischer, C. Wöll, J. Am. Chem. Soc. 2007, 129, 15118–15119;
- 6fY. N. Wu, F. T. Li, H. M. Liu, W. Zhu, M. M. Teng, Y. Jiang, W. N. Li, D. Xu, D. H. He, P. Hannam, G. T. Li, J. Mater. Chem. 2012, 22, 16971–16978.
- 7
- 7aO. Shekhah, J. Liu, R. A. Fischer, C. Wöll, Chem. Soc. Rev. 2011, 40, 1081–1160;
- 7bJ.-L. Zhuang, A. Terfort, C. Wöll, Coord. Chem. Rev. 2016, 307, 391–424.
- 8
- 8aV. Finsy, L. Ma, L. Alaerts, D. E. De Vos, G. V. Baron, J. F. M. Denayer, Microporous Mesoporous Mater. 2009, 120, 221–227;
- 8bY. Y. Zhang, X. Feng, H. W. Li, Y. F. Chen, J. S. Zhao, S. Wang, L. Wang, B. Wang, Angew. Chem. Int. Ed. 2015, 54, 4259–4263; Angew. Chem. 2015, 127, 4333–4337.
- 9H. Furukawa, N. Ko, Y. B. Go, N. Aratani, S. B. Choi, E. Choi, A. O. Yazaydin, R. Q. Snurr, M. O'Keeffe, J. Kim, O. M. Yaghi, Science 2010, 329, 424–428.
- 10R. Li, X. Q. Ren, H. W. Ma, X. Feng, Z. G. Lin, X. G. Li, C. W. Hu, B. Wang, J. Mater. Chem. A 2014, 2, 5724–5729.
- 11
- 11aS. L. James, C. J. Adams, C. Bolm, D. Braga, P. Collier, T. FriŠčić, F. Grepioni, K. D. M. Harris, G. Hyett, W. Jones, A. Krebs, J. Mack, L. Maini, A. G. Orpen, I. P. Parkin, W. C. Shearouse, J. W. Steed, D. C. Waddell, Chem. Soc. Rev. 2012, 41, 413–447;
- 11bP. J. Beldon, L. Fábián, R. S. Stein, A. Thirumurugan, A. K. Cheetham, T. FriŠčić, Angew. Chem. Int. Ed. 2010, 49, 9640–9643; Angew. Chem. 2010, 122, 9834–9837;
- 11cJ. B. Lin, R. B. Lin, X. N. Cheng, J. P. Zhang, X. M. Chen, Chem. Commun. 2011, 47, 9185–9187.
- 12A. J. Brown, J. R. Johnson, M. E. Lydon, W. J. Koros, C. W. Jones, S. Nair, Angew. Chem. Int. Ed. 2012, 51, 10615–10618; Angew. Chem. 2012, 124, 10767–10770.
- 13
- 13aQ. Z. Liu, Z. Zhou, M. Xia, Y. F. Tao, K. Liu, D. Wang, RSC Adv. 2014, 4, 40788–40793;
- 13bY. Lu, S. Sathasivam, J. L. Song, C. R. Crick, C. J. Carmalt, I. P. Parkin, Science 2015, 347, 1132–1135;
- 13cK. Zuber, D. Evans, P. Murphy, ACS Appl. Mater. Interfaces 2014, 6, 507–512.
- 14
- 14aM. C. Biesinger, L. W. M. Lau, A. R. Gerson, R. S. C. Smart, Appl. Surf. Sci. 2010, 257, 887–898;
- 14bM. C. McCarthy, V. Varela-Guerrero, G. V. Barnett, H. K. Jeong, Langmuir 2010, 26, 14636–14641.
- 15
- 15aJ. Genzer, K. Efimenko, Science 2000, 290, 2130–2133;
- 15bJ. V. I. Timonen, M. Latikka, L. Leibler, R. H. A. Ras, O. Ikkala, Science 2013, 341, 253–257;
- 15cW. Zhang, Y. Hu, J. Ge, H.-L. Jiang, S.-H. Yu, J. Am. Chem. Soc. 2014, 136, 16978–16981.
- 16
- 16aM. P. Jian, B. Liu, G. S. Zhang, R. P. Liu, X. W. Zhang, Colloids Surf. A 2015, 465, 67–76;
- 16bY. N. Wu, M. M. Zhou, B. R. Zhang, B. Z. Wu, J. Li, J. L. Qiao, X. H. Guan, F. T. Li, Nanoscale 2014, 6, 1105–1112.
- 17X. Feng, X. S. Ding, D. L. Jiang, Chem. Soc. Rev. 2012, 41, 6010–6022.
- 18Y. H. Xu, S. B. Jin, H. Xu, A. Nagai, D. L. Jiang, Chem. Soc. Rev. 2013, 42, 8012–8031.
- 19A. G. Slater, A. I. Cooper, Science 2015, 348, 988.
Citing Literature
This is the
German version
of Angewandte Chemie.
Note for articles published since 1962:
Do not cite this version alone.
Take me to the International Edition version with citable page numbers, DOI, and citation export.
We apologize for the inconvenience.
