Facile Self-Assembly of Metallo-Supramolecular Ring-in-Ring and Spiderweb Structures Using Multivalent Terpyridine Ligands†
Jun-Hao Fu
Department of Chemistry, National Taiwan University, No.1, Sec. 4, Roosevelt Rd., Taipei, 10617 (Taiwan)
Search for more papers by this authorYin-Hsuan Lee
Department of Chemistry, National Taiwan University, No.1, Sec. 4, Roosevelt Rd., Taipei, 10617 (Taiwan)
Search for more papers by this authorYun-Jui He
Department of Chemistry, National Taiwan University, No.1, Sec. 4, Roosevelt Rd., Taipei, 10617 (Taiwan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Yi-Tsu Chan
Department of Chemistry, National Taiwan University, No.1, Sec. 4, Roosevelt Rd., Taipei, 10617 (Taiwan)
Department of Chemistry, National Taiwan University, No.1, Sec. 4, Roosevelt Rd., Taipei, 10617 (Taiwan)Search for more papers by this authorJun-Hao Fu
Department of Chemistry, National Taiwan University, No.1, Sec. 4, Roosevelt Rd., Taipei, 10617 (Taiwan)
Search for more papers by this authorYin-Hsuan Lee
Department of Chemistry, National Taiwan University, No.1, Sec. 4, Roosevelt Rd., Taipei, 10617 (Taiwan)
Search for more papers by this authorYun-Jui He
Department of Chemistry, National Taiwan University, No.1, Sec. 4, Roosevelt Rd., Taipei, 10617 (Taiwan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Yi-Tsu Chan
Department of Chemistry, National Taiwan University, No.1, Sec. 4, Roosevelt Rd., Taipei, 10617 (Taiwan)
Department of Chemistry, National Taiwan University, No.1, Sec. 4, Roosevelt Rd., Taipei, 10617 (Taiwan)Search for more papers by this authorThis research was supported by the Ministry of Science and Technology of Taiwan (NSC101-2113M-002-020-MY2 and MOST103-2113M-002-003-MY2). We gratefully thank Prof. Hao Ming Chen for TEM measurements.
Abstract
A series of metallo-supramolecular ring-in-ring structures was generated by assembling CdII ions and the multivalent terpyridine ligands (L1-3) composed of one 60°-bent and two 120°-bent bis(terpyridine)s with varying alkyl linker lengths. The mechanistic study for the self-assembly process excluded an entropically templated pathway and showed that the intramolecularly complexed species is the key intermediate leading to ring-in-ring formation. The next-generation superstructure, a spiderweb, was produced in quantitative yield using the elongated decakis(terpyridine) ligand (L5).
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