A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity†
Dr. Feng Wang
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorJerrik Mielby
Department of Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)
Search for more papers by this authorDr. Felix Herrmann Richter
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorDr. Guanghui Wang
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorDr. Gonzalo Prieto
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorDr. Takeshi Kasama
Center for Electron Nanoscopy, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)
Search for more papers by this authorDr. Claudia Weidenthaler
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorHans-Josef Bongard
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorProf. Dr. Søren Kegnæs
Department of Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)
Search for more papers by this authorProf. Dr. Alois Fürstner
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Ferdi Schüth
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorDr. Feng Wang
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorJerrik Mielby
Department of Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)
Search for more papers by this authorDr. Felix Herrmann Richter
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorDr. Guanghui Wang
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorDr. Gonzalo Prieto
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorDr. Takeshi Kasama
Center for Electron Nanoscopy, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)
Search for more papers by this authorDr. Claudia Weidenthaler
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorHans-Josef Bongard
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorProf. Dr. Søren Kegnæs
Department of Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)
Search for more papers by this authorProf. Dr. Alois Fürstner
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Ferdi Schüth
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorThis work was conducted in the framework of the ERC Advanced Grant project “POLYCAT”. In addition, it was funded by the Cluster of Excellence RESOLV. F.W. and G.P. are grateful to the Alexander von Humboldt Stiftung for financial support. The A. P. Møller and Chastine Mc-Kinney Møller Foundation are gratefully acknowledged for their contribution toward the establishment of the Center for Electron Nanoscopy in the Technical University of Denmark.
Abstract
We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.
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