Volume 125, Issue 44 pp. 11813-11816
Zuschrift

Disentanglement of Donation and Back-Donation Effects on Experimental Observables: A Case Study of Gold–Ethyne Complexes

Giovanni Bistoni

Giovanni Bistoni

Istituto di Scienze e Tecnologie Molecolari del CNR (CNR-ISTM), Via Elce di Sotto 8, 06123 Perugia (Italy)

Dipartimento di Chimica, Biologia e Biotecnologie, Università di Perugia (Italy)

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Dr. Leonardo Belpassi

Corresponding Author

Dr. Leonardo Belpassi

Istituto di Scienze e Tecnologie Molecolari del CNR (CNR-ISTM), Via Elce di Sotto 8, 06123 Perugia (Italy)

Istituto di Scienze e Tecnologie Molecolari del CNR (CNR-ISTM), Via Elce di Sotto 8, 06123 Perugia (Italy)Search for more papers by this author
Prof. Francesco Tarantelli

Corresponding Author

Prof. Francesco Tarantelli

Istituto di Scienze e Tecnologie Molecolari del CNR (CNR-ISTM), Via Elce di Sotto 8, 06123 Perugia (Italy)

Dipartimento di Chimica, Biologia e Biotecnologie, Università di Perugia (Italy)

Istituto di Scienze e Tecnologie Molecolari del CNR (CNR-ISTM), Via Elce di Sotto 8, 06123 Perugia (Italy)Search for more papers by this author
First published: 05 September 2013
Citations: 12

We acknowledge financial support from MIUR Italy through the “FIRB-Futuro in ricerca” (RBFR1022UQ) programme and thank D. Zuccaccia (Udine, Italy) for insightful discussions.

Graphical Abstract

Die Analyse von Ladungsverschiebungen in Gold-Ethin-Komplexen zeigt die Existenz quantitativer Zusammenhänge zwischen messbaren Eigenschaften und den Bestandteilen chemischer Bindungen im Dewar-Chatt-Duncanson-Modell. Durch passende Experimente können diese Bestandteile voneinander separiert und somit entscheidende Erkenntnisse über die Natur von Koordinationsbindungen gewonnen werden.

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