Tightening of the Nanobelt upon Multielectron Reduction†
Dr. Alexander V. Zabula
Department of Chemistry, University at Albany, State University of New York, Albany, NY 12222 (USA)
New address: Department of Chemistry, University of Wisconsin, Madison, WI 53706 (USA)
Search for more papers by this authorDr. Alexander S. Filatov
Department of Chemistry, University at Albany, State University of New York, Albany, NY 12222 (USA)
Search for more papers by this authorDr. Jianlong Xia
Department of Chemistry, Boston University, Boston, MA 02215 (USA)
Search for more papers by this authorCorresponding Author
Prof. Ramesh Jasti
Department of Chemistry, Boston University, Boston, MA 02215 (USA)
Ramesh Jasti, Department of Chemistry, Boston University, Boston, MA 02215 (USA)
Marina A. Petrukhina, Department of Chemistry, University at Albany, State University of New York, Albany, NY 12222 (USA)
Search for more papers by this authorCorresponding Author
Prof. Marina A. Petrukhina
Department of Chemistry, University at Albany, State University of New York, Albany, NY 12222 (USA)
Ramesh Jasti, Department of Chemistry, Boston University, Boston, MA 02215 (USA)
Marina A. Petrukhina, Department of Chemistry, University at Albany, State University of New York, Albany, NY 12222 (USA)
Search for more papers by this authorDr. Alexander V. Zabula
Department of Chemistry, University at Albany, State University of New York, Albany, NY 12222 (USA)
New address: Department of Chemistry, University of Wisconsin, Madison, WI 53706 (USA)
Search for more papers by this authorDr. Alexander S. Filatov
Department of Chemistry, University at Albany, State University of New York, Albany, NY 12222 (USA)
Search for more papers by this authorDr. Jianlong Xia
Department of Chemistry, Boston University, Boston, MA 02215 (USA)
Search for more papers by this authorCorresponding Author
Prof. Ramesh Jasti
Department of Chemistry, Boston University, Boston, MA 02215 (USA)
Ramesh Jasti, Department of Chemistry, Boston University, Boston, MA 02215 (USA)
Marina A. Petrukhina, Department of Chemistry, University at Albany, State University of New York, Albany, NY 12222 (USA)
Search for more papers by this authorCorresponding Author
Prof. Marina A. Petrukhina
Department of Chemistry, University at Albany, State University of New York, Albany, NY 12222 (USA)
Ramesh Jasti, Department of Chemistry, Boston University, Boston, MA 02215 (USA)
Marina A. Petrukhina, Department of Chemistry, University at Albany, State University of New York, Albany, NY 12222 (USA)
Search for more papers by this authorFinancial support of this research by the National Science Foundation (CHE-1212441) is gratefully acknowledged by M.A.P. We thank the University at Albany for supporting the X-ray Center. R.J. also thanks Boston University for generous start-up funds.
Graphical Abstract
Den Gürtel enger schnallen: Die strukturelle Charakterisierung des mehrfach geladenen Fragments einer „Sessel“-Nanoröhre, das durch Reduktion des neutralen Moleküls mit Kalium gebildet wurde, offenbart eine bemerkenswerte elliptische Stauchung des Kohlenstoffrings (siehe Bild). Die entstandenen Tetraanionen bilden ein supramolekulares Aggregat mit Kaliumkationen, das solvatisierte Gastmoleküle aufnehmen kann.
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