Volume 125, Issue 29 pp. 7608-7611

Zuschrift

Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium–Sulfur Batteries^†

Dr. Zhan Lin,

Dr. Zhan Lin

Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6124 (USA)

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Dr. Zengcai Liu,

Dr. Zengcai Liu

Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6493 (USA)

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Dr. Wujun Fu,

Dr. Wujun Fu

Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6493 (USA)

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Dr. Nancy J. Dudney,

Dr. Nancy J. Dudney

Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6124 (USA)

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Dr. Chengdu Liang,

Corresponding Author

Dr. Chengdu Liang

[email protected]

Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6493 (USA)

Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6493 (USA)Search for more papers by this author

Dr. Zhan Lin,

Dr. Zhan Lin

Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6124 (USA)

Search for more papers by this author

Dr. Zengcai Liu,

Dr. Zengcai Liu

Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6493 (USA)

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Dr. Wujun Fu,

Dr. Wujun Fu

Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6493 (USA)

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Dr. Nancy J. Dudney,

Dr. Nancy J. Dudney

Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6124 (USA)

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Dr. Chengdu Liang,

Corresponding Author

Dr. Chengdu Liang

[email protected]

Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6493 (USA)

Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6493 (USA)Search for more papers by this author

First published: 04 June 2013

https://doi.org/10.1002/ange.201300680

Citations: 69

^†

This research was sponsored by U.S. Department of Energy (DOE)/Energy Efficiency and Renewable Energy (EERE) through Vehicle Technologies Office. The investigation of the ionic conductivity of these new compounds was supported by the Division of Materials Science and Engineering, Office of Basic Energy Sciences, U.S. Department of Energy (DOE). The synthesis and characterization was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Division of Scientific User Facilities, U.S. DOE.

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Graphical Abstract

Schwefelreiche Lithiumpolysulfidophosphate (LPSPs) ergeben langlebige und effiziente Lithium-Schwefel-Batterien. Die Ionenleitfähigkeiten von LPSPs (3.0×10⁻⁵ S cm⁻¹ bei 25 °C) sind um 8 Größenordnungen höher als von Li₂S, was entsprechenden Batterien eine ausgezeichnete Zyklenleistung verleiht. Die Tatsache, dass die Batterien eine vollständige Feststoffkonfiguration aufweisen, lässt außerdem einen sicheren Betrieb mit Lithiummetall-Anoden erhoffen.

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Volume125, Issue29

July 15, 2013

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Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium–Sulfur Batteries^†

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Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium–Sulfur Batteries†

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Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium–Sulfur Batteries^†