Oriented CoSAPO-5 Membranes by Microwave-Enhanced Growth on TiO2-Coated Porous Alumina†
Jared A. Stoeger
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455 (USA)
These authors contributed equally to this work.
Search for more papers by this authorMiguel Palomino
Instituto de Tecnologia Quimica (CSIC-UPV), Universidad Politecnica de Valencia, Avda de los Naranjos s/n 46022 Valencia (Spain)
These authors contributed equally to this work.
Search for more papers by this authorKumar Varoon Agrawal
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455 (USA)
Search for more papers by this authorXueyi Zhang
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455 (USA)
Search for more papers by this authorGeorgios N. Karanikolos
Institute of Physical Chemistry, Demokritos National Research Center, Athens 153 10 (Greece)
Search for more papers by this authorSusana Valencia
Instituto de Tecnologia Quimica (CSIC-UPV), Universidad Politecnica de Valencia, Avda de los Naranjos s/n 46022 Valencia (Spain)
Search for more papers by this authorProf. Avelino Corma
Instituto de Tecnologia Quimica (CSIC-UPV), Universidad Politecnica de Valencia, Avda de los Naranjos s/n 46022 Valencia (Spain)
Search for more papers by this authorCorresponding Author
Prof. Michael Tsapatsis
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455 (USA)
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455 (USA)Search for more papers by this authorJared A. Stoeger
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455 (USA)
These authors contributed equally to this work.
Search for more papers by this authorMiguel Palomino
Instituto de Tecnologia Quimica (CSIC-UPV), Universidad Politecnica de Valencia, Avda de los Naranjos s/n 46022 Valencia (Spain)
These authors contributed equally to this work.
Search for more papers by this authorKumar Varoon Agrawal
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455 (USA)
Search for more papers by this authorXueyi Zhang
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455 (USA)
Search for more papers by this authorGeorgios N. Karanikolos
Institute of Physical Chemistry, Demokritos National Research Center, Athens 153 10 (Greece)
Search for more papers by this authorSusana Valencia
Instituto de Tecnologia Quimica (CSIC-UPV), Universidad Politecnica de Valencia, Avda de los Naranjos s/n 46022 Valencia (Spain)
Search for more papers by this authorProf. Avelino Corma
Instituto de Tecnologia Quimica (CSIC-UPV), Universidad Politecnica de Valencia, Avda de los Naranjos s/n 46022 Valencia (Spain)
Search for more papers by this authorCorresponding Author
Prof. Michael Tsapatsis
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455 (USA)
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455 (USA)Search for more papers by this authorWe thank Dr. Christopher Lew for assistance with diffuse reflectance UV/Vis experiments. Support from the NSF (grant NSF-NIRT CMMI 0707610) and the Petroleum Institute of Abu Dhabi through the ADMIRE partnership (Abu Dhabi–Minnesota Institute for Research Excellence) is appreciated. M.P. acknowledges CSIC for a JAE doctoral fellowship, A.C. would like to thank CONSOLIDER Ingenio 2010-MULTICAT, and G.N.K. acknowledges a European Marie Curie International Reintegration Grant (FP7, grant agreement no. 210947). Portions of this work were carried out in the Nanofabrication Center, part of the National Nanotechnology Infrastructure Network (NNIN) which receives support from the NSF, and in the Characterization Facility on the campus of the University of Minnesota-Twin Cities which receives partial support from the NSF through the MRSEC program.
Graphical Abstract
Plättchen aus der Mikrowelle: Eine einfache Methode zur Herstellung von c-orientierten Cobalt-substituierten Silicoaluminophosphat-5(CoSAPO-5)-Membranen auf porösen Al2O3-Trägern wurde entwickelt. Die mikrowellenaktivierte Züchtung auf einer TiO2-Deckschicht ergab eine ausgerichtete Schicht von CoSAPO-5-Kristallen, die durch sekundäres mikrowellenverstärktes Hydrothermalwachstum in eine defektfreie Membran überführt wurde.
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